CAS 106-24-1 MFCD00002917-(E)-3,7-Dimethylocta-2,6-dien-1-ol 香叶醇 TAO{mole}

(E)-3,7-Dimethylocta-2,6-dien-1-ol 香叶醇

CAS 106-24-1 MFCD00002917

化学结构图

SMILES: CC(C)=CCC/C(C)=C/CO

化学属性

Mol. Formula	C10H18O
Mol. Weight	154.25
Density	0.879
Refractive index	1.4730 to 1.4790
Vapor Density	5.31 (vs air)
Boiling Point	229.499 °C at 760 mmHg
Flash Point	112°C(lit.)
TSCA	Yes
Melting Point	-15 °C
Vapor Pressure	~0.2 mmHg ( 20 °C)
Solubility	难溶
Appearance	无色油状液体。熔点约-15℃，沸点230℃，114-115℃（1.6kPa），相对密度0.8894（20/4℃），折光率1.4766，闪点76℃。溶于乙醇，乙醚，丙二醇，矿物油和动物油，不溶于水和甘油。香叶醇的几何异构体称橙花醇。橙花醇沸点为224-225℃（99kPa），相对密度为0.8756（20/4℃）。香叶醇和橙花醇在铜催化剂存在下加热，可重排成香茅醛，香茅醛可还原成香茅醇。

别名和识别编码

Chemical Name	(E)-3,7-Dimethylocta-2,6-dien-1-ol
MDL Number	MFCD00002917
CAS Number	106-24-1
EC Number	203-377-1
Beilstein Registry Number	1,457
Synonym	Geraniol {LY} Geraniol Guaniol LEMONOL Lemonol {} {LY} Geraniol {} {} {LY} Geraniol {} {} {} {LY} Geraniol {} {} {} {} {LY} Geraniol {} {} {} {} {} {LY} Geraniol {} {} {} {} {} {} {LY} Geraniol {} {} {} {} {} {} {} {LY} Geraniol {} {} {} {} {} {} {} {} {LY} Geraniol {} {} {} {} {} {} {} {} {} {LY} Geraniol {} {} {} {} {} {} {} {} {} {} {LY} Geraniol {} {} {} {} {} {} {} {} {} {} {} {LY} Geraniol {} {} {} {} {} {} {} {} {} {} {} {} {LY} Geraniol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Geraniol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Geraniol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Geraniol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Geraniol {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID	637566
Merck Number	4403
Reaxys-RN	1722456
Chemical Name Translation	香叶醇
Wiswesser Line Notation	Q2UY1&3UY1&1 -T
LabNetwork Molecule ID	LN00242420
InChI	InChI=1S/C10H18O/c1-9(2)5-4-6-10(3)7-8-11/h5,7,11H,4,6,8H2,1-3H3/b10-7+
Canonical SMILES	C/C(C)=C\CC/C(C)=C/CO

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

产品应用

Geraniol was used in field evaluation of synthetic herbivore-induced plant volatiles as attractants to beneficial insects.It was used to evaluate the tumor-suppressive potency of isoprenoids in vitro and in vivo.

安全信息

Signal word Danger

GHS Symbol

WGK Germany1

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
R36 Irritating to eyes 刺激眼睛
R41 Risk of serious damage to eyes 有严重损伤眼睛的危险

Precautionary statements

P304+P340+P312
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P501 Dispose of contents/container to..… 处理内容物/容器.....
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P403+P233
P273 Avoid release to the environment. 避免释放到环境中。
P405 Store locked up. 上锁保管。
P305+P351+P338+P337+P313
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H317 May cause an allergic skin reaction 可能导致皮肤过敏
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激
H318 Causes serious eye damage 严重伤害眼睛
H303 May be harmfully swallowed 吞食可能有害

Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSRG5830000

Hazard Codes Xi

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1090 mg/kg
TOXIC EFFECTS :
   Peripheral Nerve and Sensation - spastic paralysis with or without sensory
   change
REFERENCE :
   SIZSAR Sapporo Igaku Zasshi.  Sapporo Medical Journal.  (Sapporo Igaku
   Daigaku, Nishi-17-chome, Minami-1-jo, Chuo-ku, Sapporo 060, Japan)  V.3-
   1952-  Volume(issue)/page/year: 3,73,1952

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 50 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NYKZAU Nippon Yakurigaku Zasshi.  Japanese Journal of Pharmacology. (Nippon
   Yakuri Gakkai, c/o Kyoto Daigaku Igakubu Yakurigaku Kyoshitsu, Konoe-cho,
   Yoshida, Sakyo-ku, Kyoto 606, Japan) V.40-    1944- Volume(issue)/page/year:
   58,394,1962

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intramuscular
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 4 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JSICAZ Journal of Scientific and Industrial Research, Section C: Biological
   Sciences.  (New Delhi, India)  V.14-21, 1955-62.  For publisher information,
   see IJEBA6.  Volume(issue)/page/year: 21,342,1962

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3600 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - coma
   Skin and Appendages - hair
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher informat

其他信息

用途三:GB 2760—96规定为允许使用的食用香料。主要用以配制苹果、桃、杏、李、草莓、柠檬、姜、肉桂、肉豆蔻和蜂蜜等香精。
蒸气压:~0.2 mm Hg ( 20 °C)
{
Acros Organics:香叶醇/3,7-二甲基-3，7-辛二烯-1
下游产品:柠檬醛 --> 香茅醇 --> 香茅醛 --> 橙花醇 --> 3,7-二甲基-7-辛烯醇 --> 乙酸香叶酯 --> 丁酸叶醇酯 --> 甲酸香叶酯 --> 乙酰乙酸犍牛儿酯 --> 3，7-二甲基-1-辛醇 --> (E)-3,7-二甲基-2,6-辛二烯-1-醇苯甲酸酯
参考质量标准:FCC，1996 醇总含量(以C10H18O计) ≥88.0% 折射率(n D 20 ) 1.469～1.478 相对密度(d 25 25 ) 0.870～0.885 醇中溶解度 1ml溶于3mL，70%乙醇，稀
FEMA:2507
图谱信息:香叶醇(106-24-1)红外图谱(IR2) 香叶醇(106-24-1)Raman光谱香叶醇(106-24-1)核磁图( 13 CNMR) 香叶醇(106-24-1)红外图谱(IR1) 香叶醇(106-24-1)核磁图( 1 HNMR) 香叶醇(106-24-1)质谱(MS)
Hazard Note:Irritant
TCI Shanghai:香叶醇 Geraniol,>;96.0%(GC)(106-24-1)
用途四:香叶醇为玫瑰系香精的主剂，又是各种花香香精中不可缺少的调香原料，也可看作增甜剂，还可用于配制食品，香皂，日用化妆品香精。从天然精油中制取的产品，配制食品，日用化妆香精用时，含香叶醇大于90%，配制香皂香精用时，含香叶醇大于80%。工业品香叶醇和橙花醇是制造香草醇，香草醛、柠檬醛、羟基香草醛、紫罗兰酮和维生素A的原料，用香叶醇合成的各种酯，也是很好的香料。
检测方法:GC,NMR
食品添加剂最大允许使用量最大允许残留量标准:添加剂中文名称允许使用该种添加剂的食品中文名称添加剂功能最大允许使用量（g/kg）最大允许残留量（g/kg）香叶醇食品食品用香料用于配制香精的各香料成分不得超过在GB 2760中的最大允许使用量和最大允许残留量
MOL 文件:106-24-1.mol
用途二:是重要香料之一。常与香茅醇、苯乙醇共用，是各类玫瑰香精和配制香叶油的基本香料，广泛应用于花香香精，特别是
方法一:可从香茅油、印度玫瑰香草油等天然精油中游离而得
方法一:可从香茅油、印度玫瑰香草油等天然精油中游离而得：在精油中加入无水氯化钙，可生成香叶醇的结晶衍生物，遇水即分解为香叶醇和氯化钙，析出的油层经温水洗涤，再经水蒸气蒸馏而得纯品。柠檬醛在醋酸的稀乙醇溶液中，在钠汞
含量分析:醇的总含量(以香叶醇计)按总醇量测定
MSDS 信息:(2E)-3,7-Dimethyl-2,6-octadien-1-ol(106-24-1).msds
食品添加剂最大允许使用量最大允许残留量标准:添加剂中文名称允许使用该种添加剂的食品中文名称添加剂功能最大允许使用量（g/kg）最大允许残留量（g/kg）香叶醇食品食品用香料用于配制香精的各香料成分不
Alfa Aesar:香叶醇,97% Geraniol, 97%(106-24-1)
用途二:是重要香料之一。常与香茅醇、苯乙醇共用，是各类玫瑰香精和配制香叶油的基本香料，广泛应用于花香香精，特别是玫瑰。也可限量用于晚香玉、香罗兰、金合欢、橙花、紫罗兰、桂花、依兰、香石竹、玉兰等香精中。还可适量用于苹果、杏子、草莓、悬钩子、李子、桃子、蜂蜜、樱桃等香型的食用香精中。
使用限量:FEMA(mg/kg)：软饮料2.1；冷饮3.3；糖果10；焙烤食品11；布丁类2.0；胶姆糖0.80～2.9；裱花层1.0。
蒸气密度:5.31 (vs air)