Triisopropyl Phosphite 三异丙基亚磷酸酯
CAS 116-17-6 MFCD00008874
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分类
- Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds
- {uni_hamburg} no charge; 1fragment
- {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds
相关文献及参考
- Beilstein: 1,IV,1476
- Short: III/38A
- Convenient means of introduction of an isopropyl group into an
- {A
- Short: EINECS
- Reagent for the preparation of phosphonate esters by the Arbuzov reaction; cf Triethyl phosphite, L00339. Has the advantage over primary phosphites that the bulky alkyl groups minimize the product of self-alkylation. For an example (diisopropyl methanephosphonate), see: Org. Synth. Coll., 4, 325 (1963).
安全信息
GHS Symbol

- H301 Toxic if swallowed 吞食有毒
- H315 Causes skin irritation 会刺激皮肤
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P310
- P302+P352
- P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
- P330 Rinse mouth. 漱口
- P332+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- R25 Toxic if swallowed 吞咽有毒
- R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
- R38 Irritating to skin 刺激皮肤
- R10 Flammable 易燃
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
- S37 Wear suitable gloves 戴适当手套;
- S46 If swallowed, seek medical advice immediately and show this container or label 食入时,立即求医并出示容器/标签;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : >2 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : ALBRW* Albright & Wilson Inc. (P.O. Box 26229, Richmond, VA 23260-6229) Volume(issue)/page/year: #OPB-3,1984
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 167 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : ALBRW* Albright & Wilson Inc. (P.O. Box 26229, Richmond, VA 23260-6229) Volume(issue)/page/year: #OPB-3,1984
TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 500 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : CBCCT* "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. (National Academy of Science Library, 2101 Constitution Ave., NW, Washington, DC 20418) Volume(issue)/page/year: 9,130,1957
TYPE OF TEST : Sex chromosome loss and nondisjunction ROUTE OF EXPOSURE : Oral TEST SYSTEM : Insect - Drosophila melanogaster DOSE/DURATION : 50 mmol/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 28,405,1975
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 5 mg/plate REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 28,405,1975
其他信息
- 三异丙基亚磷酸酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 372385000 三异丙基亚磷酸酯 Triisopropyl phosphite 96% 500 GR 1639元 2010/06/21 372380050 三异丙基亚磷酸酯 Triisopropyl phosphite 96% 5 GR 247元 2010/06/21 372381000 三异丙基亚磷酸酯 Triisopropyl phosphite 96% 100 GR 482元
- MSDS 信息:亚磷酸三异丙酯(116-17-6).msds
- 用途一:三异丙基亚磷酸酯(116-17-6)是烷基膦酸酯生产的中间体,也用作塑料增塑剂、稳定剂。
- 蒸气压:<;2 mm Hg ( 20 °C)
- 不溶于水,易溶于苯等有机溶剂。
- Acros Organics:亚磷酸三异丙酯 Triisopropyl phosphite, tech., 90%(116-17-6)
- MOL 文件:116-17-6.mol
- 敏感性:Moisture Sensitive
- Hazard Note:Toxic/Flammable/Moisture Sensitive/
- Alfa Aesar:亚磷酸三异丙酯,90+% Triisopropyl phosphite, 90+%(116-17-6)
- 外观性质:无色液体。
- F:1-10
- 上游原料:石油醚 --> 三乙胺 --> 异丙醇 --> 三氯化磷
- 存储注意事项:湿度敏感
- Sigma Aldrich:116-17-6(sigmaaldrich)
- 图谱信息:三异丙基亚磷酸酯(116-17-6)核磁图( 13 CNMR) 三异丙基亚磷酸酯(116-17-6)核磁图( 1 HNMR) 三异丙基亚磷酸酯(116-17-6)红外图谱(IR1) 三异丙基亚磷酸酯(116-17-6)质谱(MS)