Bis(triphenylsilyl)chromate 双(三苯基甲硅烷基)铬酸酯
CAS 1624-02-8 MFCD01736354
化学结构图
SMILES: O.O.[Cr+2].[O-][Si](c1ccccc1)(c1ccccc1)c1ccccc1.[O-][Si](c1ccccc1)(c1ccccc1)c1ccccc1
化学属性
| Mol. Formula | [(C6H5)3SiO]2CrO2 |
|---|---|
| Mol. Weight | 635 |
| Melting Point | 159 °C (dec.)(lit.) |
别名和识别编码
| Chemical Name | Bis(triphenylsilyl)chromate |
|---|---|
| Synonym | 铬酸双(三苯甲基硅烷基)酯 Silanol, triphenyl-, diester with chromic acid (H2CrO4) Bis(triphenylsilyl)chromate Silanol, triphenyl-, chromate(VI) bis(triphenylsilyl) chromate Bis(triphenylsilyl) ester chromic acid Chromsäurebis(triphenylsilyl)ester 铬酸双(三苯基甲硅烷基)酯 Chromic acid (H2CrO4), bis(triphenylsilyl) ester Chromic acid, bis(triphenylsilyl) ester |
| MDL Number | MFCD01736354 |
| CAS Number | 1624-02-8 |
| PubChem Substance ID | 102059955 |
| EC Number | 216-612-8 |
| Chemical Name Translation | 双(三苯基甲硅烷基)铬酸酯 |
| InChIKey | AQLZCGLPNYEIDH-UHFFFAOYSA-N |
| Wiswesser Line Notation | R-SI-R&R&O-CR-WO-SI-R&R&R |
| Beilstein Registry Number | 4169614 |
| InChI | InChI=1S/2C18H15OSi.Cr.2H2O/c2*19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;;2*1H2/q2*-1;+2;; |
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分类
- {SNA} Chemical Synthesis, Other Oxidizing Agents, Oxidizing Agents, Synthetic Reagents
- {SNA} Chemical Synthesis, Others, Oxidizing Agents, Synthetic Reagents
- {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
相关文献及参考
- Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
- Short: III/10b Title: Structure Data of Organic Crystals: C 16 ... C 168 Author: Schudt-Weitz, G.; Strell, I. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/10b Year: 1985 ISBN: 3-540-13932-X ISBN: 978-3-540-13932-4 Internet Resource: DOI:10.1007/b19985 RefComment: XIX,652 pages. Hardcover
安全信息
GHS Symbol
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P308+P313
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P201 Obtain special instructions before use. 使用前获取专门指示。
- H350 May cause cancer 可能致癌
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
- R50/53
- R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
- R49 May cause cancer by inhalation 吸入会致癌
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 3360 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 28,313,1974
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 710 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 28,313,1974
