N-Hydroxy-5-Norbornene-2,3-Dicarboxylic Acid Imide N-羟基-5-降冰片烯-2,3-二甲酰亚胺
CAS 21715-90-2 MFCD00065691
化学结构图
SMILES: O=C1[C@H]2[C@H]3C=C[C@H](C3)[C@H]2C(=O)N1O
化学属性
| Mol. Formula | C9H9NO3 |
|---|---|
| Mol. Weight | 179 |
| Melting Point | 165-170 |
| TSCA | Yes |
| Density | 1.574 |
别名和识别编码
| Chemical Name | N-Hydroxy-5-Norbornene-2,3-Dicarboxylic Acid Imide |
|---|---|
| MDL Number | MFCD00065691 |
| Synonym | HONBendo-N-Hydroxybicyclo[2.2.1]hept-5-ene-2,3-dicarboximide N-羟基-5-降冰片稀-2,3-二酰亚胺 |
| EC Number | 244-538-6 |
| CAS Number | 21715-90-2 |
| Beilstein Registry Number | 13540 |
| PubChem Substance ID | 24853563 |
| Chemical Name Translation | N-羟基-5-降冰片烯-2,3-二甲酰亚胺 |
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分类
- {SNA} Active Esters/Additives, Alicyclic/Etch-Resistant Monomers, Chemical Biology, Chemical Synthesis, Coupling, Lithography Monomers, Micro/NanoElectronics, Monomers, Norbornene Monomers, Peptide Chemistry, Peptide Coupling, Polymer Science, Self Assembly & Contact Printing, Synthetic Reagents, 材料科学
- {SNA} Active Esters/Additives, Alicyclic/Etch-Resistant Monomers, Chemical Biology, Chemical Synthesis, Coupling, Lithography Monomers, Materials Science, Micro/NanoElectronics, Peptide Chemistry, Peptide Coupling,
- {SNA} Active Esters/Additi
产品应用
- 多肽合成中的消旋抑制剂。有报道称其效果优于N-羟基琥珀酰亚胺(HOSu，NHS)
相关文献及参考
- Beilstein: 21,V,10,188
- Reagent for preparation of O-alkylhydroxylamines by O-alkylation and cleavage with hydrazine: Bull. Soc. Chim. Fr., 833 (1976). Compare N-Hydroxyphthalimide, A13862.
- Reportedly superior to N-Hydroxysuccinimide, A10312 as a racemization suppressant in peptide synthesis: Chem. Pharm. Bull., 22, 1857 (1974); 26, 585 (1978). See Appendix 6.
安全信息
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
