Triphenylphosphine Selenide 硒化三苯膦
CAS 3878-44-2 MFCD00013477
化学结构图
SMILES: [Se]=P(c1ccccc1)(c1ccccc1)c1ccccc1
化学属性
| Mol. Formula | C18H15PSe |
|---|---|
| Mol. Weight | 341.25 |
| Melting Point | 186-188 °C |
| Boiling Point | 448.6±28.0 °C at 760 mmHg |
别名和识别编码
| Chemical Name | Triphenylphosphine Selenide |
|---|---|
| Synonym | Triphenylphosphine selenide {LY} Triphenylphosphine selenide {} {LY} Triphenylphosphine selenide {} {} {LY} Triphenylphosphine selenide {} {} {} {LY} Triphenylphosphine selenide {} {} {} {} {LY} Triphenylphosphine selenide {} {} {} {} {} {LY} Triphenylphosphine selenide {} {} {} {} {} {} {LY} Triphenylphosphine selenide {} {} {} {} {} {} {} {LY} Triphenylphosphine selenide {} {} {} {} {} {} {} {} {LY} Triphenylphosphine selenide {} {} {} {} {} {} {} {} {} {LY} Triphenylphosphine selenide {} {} {} {} {} {} {} {} {} {} {LY} Triphenylphosphine selenide {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylphosphine selenide {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylphosphine selenide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylphosphine selenide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylphosphine selenide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylphosphine selenide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphen |
| MDL Number | MFCD00013477 |
| CAS Number | 3878-44-2 |
| EC Number | 223-406-1 |
| Reaxys-RN | 2269139 |
| Beilstein Registry Number | 16(3)866 |
| PubChem Substance ID | 298720 |
| Chemical Name Translation | 硒化三苯膦 |
| InChIKey | GYWJISIUKYLCGC-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN01743744 |
| InChI | InChI=1S/C18H15PSe/c20-19(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H |
| Canonical SMILES | [Se]=P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3 |
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分类
- {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
相关文献及参考
- Short: III/35D2 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Carbon-13, Part 2: Aromatic Compounds Author: Mikhova, B. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35D2 Year: 2005 Keyword: aromatic compounds; carbon-13; chemical shift; coupling constant; molecular structure ISBN: 978-3-540-20189-2 ISBN: 3-540-20189-0 Internet Resource: DOI:10.1007/b83345 RefComment: VIII, 291 p., Hardcover RefComment: Written for Science and engineers in the fields of physics, chemistry and physical chemistry who inted to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, orient by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum. The spectral lines of the nuclei are highly influenced by the chemical environment i.e. the structure and interaction of the molecules. NMR is now the leading technique and a powerful tool for the investigation of the structure and interaction of molecules. The present Landolt-Börnstein volume III/35 Nuclear Magnetic Resonance (NMR) Data is therefore of major interest to all scientists and engineers who intend to use NMR to study the structure and the binding of molecules. Volume III/35 "NMR-Data" is divided into several subvolumes and parts. Subvolume III/35A contains the nuclei 11B and 31P, subvolume III/35B contains the nuclei 19F and 15N, subvolume III/35C contains the nucleus 1H, subvolume III/35D contains the nucleus 13C, subvolume III/35E contains the nucleus 17O, and subvolume III/35G contains the nucleus 77Se. More nuclei will be presented later.
- Short: III/35G Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Selenium-77 Author: Duddeck, H. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35G Year: 2004 Keyword: chemical shift;
安全信息
- H301 Toxic if swallowed 吞食有毒
- H331 Toxic if inhaled 吸入中毒
- H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
- H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P273 Avoid release to the environment. 避免释放到环境中。
- P301+P316
- P304+P340
- P304+P340+P311
- P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
- P316
- P319
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P330 Rinse mouth. 漱口
- P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
GHS Symbol
TYPE OF TEST : LD - Lethal dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : >500 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : NCNSA6 National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. (Washington, DC) Volume(issue)/page/year: 5,39,1953
