Bis(2,2,2-trichloroethyl)azodicarboxylate 双(2,2,2-三氯乙基)偶氮二甲酸酯

CAS 38857-88-4 MFCD00010607

化学结构图

38857-88-4
SMILES: O=C(/N=N/C(=O)OCC(Cl)(Cl)Cl)OCC(Cl)(Cl)Cl

化学属性

Mol. FormulaCCl3CH2OCON=NCOOCH2CCl3
Mol. Weight380.82
Melting Point109-111 °C(lit.)

别名和识别编码

Chemical NameBis(2,2,2-trichloroethyl)azodicarboxylate
Synonym 偶氮基二羧酸双(2,2,2-三氯乙酯) 偶氮二甲酸二(2,2,2-三氯乙基)酯
Beilstein Registry Number2141527
PubChem Substance ID24857539
CAS Number38857-88-4
MDL NumberMFCD00010607
Reaxys-RN2141527
Chemical Name Translation双(2,2,2-三氯乙基)偶氮二甲酸酯
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分类

  • {SNA} Azo/Diazo Compounds, Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks
  • {SA} C-X Bond Formation (Non-Halogen), Chemical Synthesis, Mitsunobu, Synthetic Reagents
  • Azo/Diazo Compounds, Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks

相关文献及参考

  • 1. Org. Synth. 61 , 17, (1983)
  • Fieser 12 ,62
  • FT-IR 2 (1), 1488:A / FT-NMR 1 (1), 1415:B / RegBook 1 (1), 1037:G / Structure Index 1 , 161:B:2

安全信息

Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P301+P312+P330
  • P302+P350
  • P337+P313
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P403+P235
  • P304+P340+P312
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P420 Store away from other materials. 远离其他材料。
  • P305+P351+P338+P337+P313
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P302+P352+P312+P362+P364
WGK Germany3
GHS Symbol
Signal word {TCI} Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H242 Heating may cause a fire 加热可能会引起火灾
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
UN Number 3224
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Hazard Class4.1

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-X Bond Formation (Non-Halogen) - Synthetic Reagents
  4. Mitsunobu - C-X Bond Formation (Non-Halogen)
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Azo/Diazo Compounds - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Oximes - Nitrogen Compounds
  1. Functional Group 官能团索引
  2. azo compound

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