1-Indanone 1-茚酮

CAS 83-33-0 MFCD00003785

化学结构图

83-33-0
SMILES: O=C1CCc2ccccc21

化学属性

Mol. FormulaC9H8O
Mol. Weight132.16
Density1.1
Boiling Point244°C at 760 mmHg
Melting Point38-40°C
Flash Point111.7°C
TSCAYes
Solubility6.5 G/L (20 C)
Appearance 白色片状结晶。熔点42℃，沸点243-245℃，129℃（1.73kPa）。

别名和识别编码

Chemical Name1-Indanone
CAS Number83-33-0
Alfabeta NameINDANONE 1-
MDL NumberMFCD00003785
Synonym 1-Indanone {LY} 1-Indanone {} {LY} 1-Indanone {} {} {LY} 1-Indanone {} {} {} {LY} 1-Indanone {} {} {} {} {LY} 1-Indanone {} {} {} {} {} {LY} 1-Indanone {} {} {} {} {} {} {LY} 1-Indanone {} {} {} {} {} {} {} {LY} 1-Indanone {} {} {} {} {} {} {} {} {LY} 1-Indanone {} {} {} {} {} {} {} {} {} {LY} 1-Indanone {} {} {} {} {} {} {} {} {} {} {LY} 1-Indanone {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Indanone {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Indanone {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Indanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Indanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Indanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Indanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Indanone {} {} {} {} {} {} {} {} {} {} {} {} {}
EC Number201-470-1
Beilstein Registry Number507957
PubChem Substance ID6735
Reaxys-RN507957
Chemical Name Translation1-茚酮
LabNetwork Molecule IDLN00008483
InChIInChI=1S/C9H8O/c10-9-6-5-7-3-1-2-4-8(7)9/h1-4H,5-6H2
Canonical SMILESO=C1CCC2=C1C=CC=C2
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; alicycle; large ring; fused rings; 5ring; 6ring; 9ring; ketone; 1fragment
  • {SNA} Building Blocks, C9, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
  • Intermediates
  • Aromatics
  • Metabolites & Impurities

产品应用

  • 用于有机合成。

相关文献及参考

  • Beilstein:7,360
  • Billings, R.E. et al.: Biochemistry, 9, 1256 (1970); Braun, A.G. et al.: Biochem. Pharmacol., 33, 1471 (1984); Serve, M.P. et al.: J. Toxicol. Environ. Health, 29, 409 (1990);
  • Can be carboxylated at the 2-position in the presence of diphenylcarbodiimide: Chem. Lett., 39 (1990):
  • Short: III/35E
  • Short: III/38B

安全信息

Warnings IRRITANT
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Hazard Codes Xn Xn,Xi
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • MSDS 信息:2,3-Dihydro-1H-inden-1-one(83-33-0).msds
  • 用途一:用于有机合成
  • 海关编码:29143900
  • 下游产品:2-溴-1-茚满酮
  • 1-茚酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 I0013 1-茚酮 1-Indanone 25G 688元 2014/06/02 I0013 1-茚酮 1-Indanone 5G 251元 2010/06/21 122111000 1-茚酮 1-Indanone 99+% 100 GR 2827元
  • 方法一:将干燥的氯化氢通入新蒸过的茚中，温度保持在5-10℃，反应需要8-10h，反应产物进行减压蒸馏，收集90-103（1.73kPa）得α-氯二氢茚。将其用三氧化铬在冰乙酸中氧化，温度保持35-40℃，即生成二氢-1-茚酮。收率50%-60%。
  • 图谱信息:1-茚酮(83-33-0)红外图谱(IR3) 1-茚酮(83-33-0)红外图谱(IR1) 1-茚酮(83-33-0)红外图谱(IR2) 1-茚酮(83-33-0)核磁图( 13 CNMR) 1-茚酮(83-33-0)核磁图( 1 HNMR) 1-茚酮(83-33-0)质谱(MS)
  • TCI Shanghai:1-茚酮 1-Indanone,>;98.0%(GC)(83-33-0)
  • Hazard Note:Irritant
  • 上游原料:乙酸 --> 三氧化铬 --> 茚
  • Acros Organics:1-茚酮 1-Indanone, 99+%(83-33-0)
  • Alfa Aesar:1-茚满酮,99+% 1-Indanone, 99+%(83-33-0)
  • 检测方法:GC,NMR
  • 水中溶解度: 6.5 g/l (20 C) ，溶于乙醇、乙醚和氯仿。
  • 用途二:合成Indinavir(茚地那韦，佳息患)的重要中间体。
  • Sigma Aldrich:83-33-0(sigmaaldrich)
  • MOL 文件:83-33-0.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones - Carbonyl Compounds
  6. C9 - Ketones
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones 酮
  6. C7 to C8