CAS 598-22-1 MFCD00000116-Propionyl Bromide 丙酰溴 TAO{mole}

Propionyl Bromide 丙酰溴

CAS 598-22-1 MFCD00000116

化学结构图

SMILES: CCC(=O)Br

化学属性

Mol. Formula	C3H5BrO
Mol. Weight	136.98
Density	1.521 g/mL at 25 °C(lit.)
Refractive index	1.4540 to 1.4580
Boiling Point	104°C
Flash Point	52°C(lit.)
Solubility	溶于乙醚。
Stability	对光和湿度敏感

别名和识别编码

Chemical Name	Propionyl Bromide
Synonym	Propionic acid bromide Propanoyl bromide Propionyl bromide PROPIONYL BROMIDE 丙酰溴;溴丙酰;溴化丙酰溴(化)丙酰溴丙酰溴化丙酰 Propanoic acid bromide 丙醯溴丙酰溴 Propionylbromid 丙酰溴 PROPIONYL BROMIDE 1-Bromo-1-propanone
MDL Number	MFCD00000116
CAS Number	598-22-1
Beilstein Registry Number	2(4)724
EC Number	209-924-0
PubChem Substance ID	87574698
Reaxys-RN	1736651
Chemical Name Translation	丙酰溴
InChIKey	RIBFXMJCUYXJDZ-UHFFFAOYSA-N
LabNetwork Molecule ID	LN01306964

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安全信息

WGK Germany3

GHS Symbol

Hazard statements

H226 Flammable liquid and vapour 易燃液体和蒸气
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤

Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Precautionary statements

P501 Dispose of contents/container to..… 处理内容物/容器.....
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P303+P361+
P304+P340
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338+P310
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P301+P330+P331+P310
P303+P361+P353
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P370+P378

Signal word Danger

Hazard Codes C

Safety Statements

S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；

Risk Statements

R34 Causes burns 会导致灼伤
R14 Reacts violently with water 遇水会猛烈反应
R10 Flammable 易燃

UN Number 2920 UN 2920 8/PG 2

Packing GroupII

Storage condition Flammables area 密封避光保存。

Hazard Class8/3

Warnings 危化品目录(2015) 危险化学品

其他信息

外观性质:无色或浅黄色液体。
Sigma Aldrich:598-22-1(sigmaaldrich)
Acros Organics:Propionyl bromide, 95%(598-22-1)
用途一:用作医药中间体，用于有机合成
方法一:将无水丙酸在红磷的存在下与溴反应而得。
下游产品:萘丙胺 --> 硫普罗宁 --> 丙胺卡因
和水剧烈反应。
丙酰溴价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 P0515 丙酰溴 Propionyl Bromide 25G 789元 2010/06/21 392360250 丙酰溴 Propionyl bromide 95% 25 GR 1095元 2010/06/21 392361000 丙酰溴 Propionyl bromide 95% 100 GR 3577元
MSDS 信息:丙酰溴(598-22-1).msds
上游原料:红磷
MOL 文件:598-22-1.mol
TCI Shanghai:丙酰溴 Propionyl Bromide,>;98.0%(T)(598-22-1)
图谱信息:丙酰溴(598-22-1)质谱(MS) 丙酰溴(598-22-1)核磁图( 13 CNMR) 丙酰溴(598-22-1)核磁图( 1 HNMR) 丙酰溴(598-22-1)红外图谱(IR1)