Triphenylmethyl bromide 三苯基甲基溴
CAS 596-43-0 MFCD00000120
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分类
- {SNA} Aryl, Building Blocks, C13 to C37+, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
- {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
- Aryl, Building Blocks, C13 to C37+, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
相关文献及参考
- Beil. 5 ,IV,2500
- Fieser 1 ,1254 / Fieser 16 ,375
- Aldrich MSDS 1 , 1806:D / Corp MSDS 1 (2), 3518:D / FT-IR 2 (2), 1760:C / FT-IR 1 (1), 1024:C / FT-NMR 1 (2), 163:B / IR-Spectra (3), 615:F / IR-Spectra (2), 548:B / NMR-Reference 2 (1), 823:C / RegBook 1 (1), 1217:K / Sax 6 , 542 / Structure Index 1 , 186:E:5
- More reactive reagent than Chlorotriphenylmethane, A11799 for the preparation of trityl esters: J. Org. Chem., 27, 3595 (1962). One-pot conversion of amino acids to their N-trityl derivatives involves N,O-ditritylation and selective methanolysis of the trityl ester: Synthesis, 198 (1989). See also Appendix 6.
- Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
- Short: III/5b Title: Structure Data of Organic Crystals: C 14 ... C 120 Author: Schudt, E.; Weitz, G. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/5b Year: 1971 ISBN: 3-540-05177-5 ISBN: 978-3-540-05177-0 Internet Resource: DOI:10.1007/b19970 RefComment: XXI, 736 pages, and VII, 890 pages. Hardcover Abstract: Volume III/5 offers a compitation as complete as possible of the space groups and lattice con-stan
安全信息
GHS Symbol
- H290 May be corrosive to metals 可能腐蚀金属。
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- P234 Keep only in original container. 只保留在原来的容器中。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331
- P302+P361+P354
- P303+P361+P353
- P303+P361+P353+P310+P363
- P304+P340
- P305+P351+P338
- P305+P354+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P316
- P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 180 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#04015
其他信息
- 图谱信息:三苯基甲基溴(596-43-0)红外图谱(IR2) 三苯基甲基溴(596-43-0)核磁图( 1 HNMR) 三苯基甲基溴(596-43-0)质谱(MS) 三苯基甲基溴(596-43-0)核磁图( 13 CNMR) 三苯基甲基溴(596-43-0)红外图谱(IR1)
- MSDS 信息:Trityl bromide(596-43-0).msds
- Sigma Aldrich:596-43-0(sigmaaldrich)
- Alfa Aesar:溴三苯基甲烷,98% Bromotriphenylmethane, 98%(596-43-0)
- 三苯基甲基溴价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0512 三苯基甲基溴 Trityl Bromide 100G 1710元 2014/06/02 T0512 三苯基甲基溴 Trityl Bromide 25G 614元 2010/06/21 140390500 三苯基甲基溴 Triphenylmethyl bromide 98% 50 GR 1110元
- Acros Organics:三苯基溴甲烷 Triphenylmethyl bromide, 98%(596-43-0)
- MOL 文件:596-43-0.mol
- 存储注意事项:氮气保护
- 下游产品:纳美芬
- 检测方法:T
- 上游原料:乙酐 --> 苯 --> 氢溴酸 --> 乙酰溴 --> 三苯基甲醇
- 敏感性:Moisture Sensitive
- TCI Shanghai:三苯基甲基溴 Triphenylmethyl Bromide,>;98.0%(T)(596-43-0)