CAS 75-25-2 MFCD00000128-Bromoform 三溴甲烷 TAO{mole}

Bromoform 三溴甲烷

CAS 75-25-2 MFCD00000128

化学结构图

SMILES: BrC(Br)Br

化学属性

Mol. Formula	CHBr₃
Mol. Weight	252.73
Density	2.89
Refractive index	1.5950 to 1.5990
Vapor Density	8.7 (vs air)
Boiling Point	146-150
Vapor Pressure	5 mmHg ( 20 °C)
Melting Point	5-8
Flash Point	None
TSCA	Yes
Solubility	略溶于水, 0.301 G/100 ML
Stability	对光敏感
pH	:A

别名和识别编码

Chemical Name	Bromoform
Synonym	Bromoform {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {ALD} {} {} {} {} {} {} {} {} {} {Chemicalbook} tribromomethane(bromoform) {} {} {} {} {} {} {} {} {} {} {Ch {} {} {} {} {} {} {} {} {} {} {Chemicalbook} tribromo-methan {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} tribromide {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} methyltribromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {uni_hamburg} methane, tribromo- {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {uni_hamburg} bromoform {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {ALF} Tribromomethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {uni_hamburg} Tribrommethan {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {hazard_com} Tribrommethaan {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} Rcra waste number U225 {} {} {} {} {} {} {} {} {} {}
CAS Number	75-25-2
EC Number	200-854-6
Beilstein Registry Number	1731048
MDL Number	MFCD00000128
PubChem Substance ID	5558
Merck Number	1420
Reaxys-RN	1731048
Chemical Name Translation	三溴甲烷
Wiswesser Line Notation	EYEE
LabNetwork Molecule ID	LN00195512
InChI	InChI=1S/CHBr3/c2-1(3)4/h1H

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分类

{SA} Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
{SNA} A-B, Alpha Sort, Alphabetical Index
{SNA} A-B, Alpha Sort, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Applications, B, BI - BZ, Bromo, Chemical Class, Chromatography, Disinfection Byproducts, Disinfection Product Residues and Solvents, Environmental Standards, Food & Beverage Analysis, Halogenated, Processing/Packaging Contaminants, Volatiles/ Semivolatiles, Waste water

产品应用

测定分子量的溶剂，测定矿物的折射指数。按比重分离各种矿石。
标准溶液用于水分析等以下用途。
1、测定分子量的溶剂，测定矿物的折射指数。按比重分离各种矿石。
2、工业上染料中间体、医药镇痛剂、空气熏蒸消毒剂、致冷剂、抗爆剂组分、树脂和石蜡的溶剂等。
校准仪器和装置；评价方法；工作标准；质量保证/质量控制；其他。
用于ICP-AES、AAS、AFS、ICP-MS、离子色谱等。滴定分析用标准溶液。

安全信息

Signal word Danger

GHS Symbol

WGK Germany3

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S63

Risk Statements

R11 Highly flammable 非常易燃
R22 Harmful if swallowed 吞咽有害
R23 Toxic by inhalation 吸入有毒
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
R51/53

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P312+P330
P302+P350
P305+P351+P338
P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
P332+P313
P337+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H302 Harmful if swallowed 吞食有害
H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H315 Causes skin irritation 会刺激皮肤
H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
H331 Toxic if inhaled 吸入中毒
H319 Causes serious eye irritation 严重刺激眼睛

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSPB5600000

Packing GroupIII

UN Number 2515

Storage condition 0-6°C 密封避光保存。储存温度2-8℃ Light Sensitive 0-10°C 0-10

Hazard Codes 6.1 T,N T,N,F

Hazard Class6.1

Warnings 危化品目录(2015)

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1100 mg/kg/8W-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   37,2717,1977

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 10400 mg/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Gastrointestinal - tumors
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-350,1989

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1274 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 20(12),52,1976

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1820 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   4,354,1962

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 414 mg/kg
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Behavioral - somnolence (general depressed activity)
   Behavioral - antipsychotic
REFERENCE :
   TOLED5 Toxicology Letters.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1977-  Volume(issue)/page/year: 15,251,1983

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human
DOSE/DURATION           : 143 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals,"

TYPE OF TEST            : Micronucleus test
ROUTE OF EXPOSURE       : Multiple routes
TEST SYSTEM             : Non-mammalian species
DOSE/DURATION           : 5 ppm
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 292,83,1993

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 80 umol/L
REFERENCE :
   ENVRAL Environmental Research.  (Academic Press, Inc., 1 E. First St.,
   Duluth, MN 55802) V.1-    1967-  Volume(issue)/page/year: 32,72,1983

TYPE OF TEST            : Specific locus test
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 3000 ppm
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-350,1989

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 666 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 5(Suppl
   1),3,1983

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - rat Leukocyte
DOSE/DURATION           : 20 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 300,241,1993

{hazar

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 110 ug/L
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 7,1,1985

Restrict 危险品

其他信息

Acros Organics:三溴甲烷/溴仿 Bromofo
爆炸物危险特性:与冠醚，或KOH 反应爆炸
毒性分级:中毒
外观性质:
储运特性:库房通风低温干燥; 与食品添加剂分开存放
用途六:可用作染料中间体、消毒剂、镇痛剂、麻醉剂、制冷剂、选矿剂、沉淀剂、溶剂和抗爆液组分等。用于ICP-AES、AAS、AFS、ICP-MS、离子色谱等。滴定分析用标准溶液。
MSDS 信息:三溴甲烷(75-25-2).msds
{Chemi
图谱信息:三溴甲烷(75-25-2)红外图谱(IR1) 三溴甲烷(75-25-2)核磁图( 1 HNMR) 三溴甲烷(75-25-2)核磁图( 13 CNMR) 三溴甲烷(75-25-2)质谱(MS)
职业标准:TWA
敏感性:Light Sensitive
Alfa Aesa
三溴甲烷价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 10022916 三溴甲烷;溴仿 100ml 115元 2011/08/23 10022926 三溴甲烷;溴仿 100ml 70元 2011/08/23 xp400265 三溴甲烷;溴仿 5ml 98元
无色重质液体。有氯仿气味，味甜。能与醇、苯、氯仿醚、石油醚、丙酮和油类等任意混和，难溶于水。久贮逐渐分解成黄色液体，空气及光可加速其分解，可加入乙醇作稳定剂。
用途四:1、测定分子量的溶剂，测定矿物的折射指数。按比重分离各种矿石。2、工业上染料中间体、医药镇痛剂、空气熏蒸消毒剂、致冷剂、抗爆剂组分、树脂和石蜡的溶剂等。校准仪器和装置；评价方法；工作标准；质量保证/质量控制；其他。
TCI Shanghai:溴仿(含稳定剂二苯胺) Bromoform (stabiliz
挥发性有机化合物(VOCs)单组分标准液
蒸气压:5 mm Hg ( 20 °C)
方法一:由丙酮与次溴酸钠反应而得。先用溴素与碱液配制次溴酸钠，在碱性条件下，将丙酮迅速加入0-5℃的次溴酸钠中，使温度保持在30-50℃，待温度下降后，继续搅拌10min。丙酮与次溴酸钠反应经由三溴丙酮而分解为溴仿。静置分层，蒸馏，洗涤、过滤，干燥而得成品。原料消耗定额：丙酮650kg/t、溴素3500kg/t。
Acros O
类别:有毒物质
Acros Or
上游原料:氢氧化钠 --> 硫酸 --> 碳酸钠 --> 溴 --> 氢氧化钾 --> 丙酮 --> 盐酸羟胺 --> 硫代硫酸钠 --> 硫代硫酸钠 --> 溴丙酮 --> 亚溴酸钠 --> 次溴酸钠
蒸气密度:8.7 (vs air)
用途五:测定分子量的溶剂，测定矿物的折射指数。按比重分离各种矿石。
用途一:用作消毒剂、镇痛剂、致冷剂、灭水剂、抗爆剂、溶剂等
可燃性危险特性:不燃；高热分解; 燃烧释放有毒溴化物烟雾
Sigma Aldrich:75-25-2(sigmaaldrich)
下游产品:1R,3R-二溴菊酸 --> 二溴甲烷
用途二:用作分析试剂及测定分子量时的溶剂
用途三:可用作染料中间体、消毒剂、镇痛剂、麻醉剂、制冷剂、选矿剂、沉淀剂、溶剂和抗爆液组分等。
{Chemic
MOL 文件:75-25-2.mol
急性毒性:口服-大鼠 LD50: 933 毫克/公斤; 口服-小鼠 LD50: 1072 毫克/公斤
灭火剂:雾状水、泡沫、二氧化碳、砂土。