Ethylmagnesium Chloride 乙基氯化镁

CAS 2386-64-3 MFCD00000472

化学结构图

2386-64-3
SMILES: CC[Mg]Cl

化学属性

Density0.978
Solubility起反应
Flash Point1 °F
Mol. FormulaC2H5ClMg
Mol. Weight88.82
Appearance liq.
Stabilityair sensitive, moisture sensitive

别名和识别编码

Chemical NameEthylmagnesium Chloride
EC Number250-023-7
Beilstein Registry Number3647886
PubChem Substance ID87569432
Synonym Ethyl magnesium chloride,2.0M solution in THF,Safeseal {LY} Ethyl magnesium chloride,2.0M solution in THF,Safeseal Ethylmagnesium Chloride (18% in Tetrahydrofuran, ca. 2mol/l) Ethylmagnesium Chloride 2.0 M In Diethyl Ether Ethylmagnesium Chloride 2.0 M In Tetrahydrofuran Ethylmagnesium chloride, 1-2M in ether Ethylmagnesium chloride, 2.0M solution in THF Ethylmagnesium chloride, 25 wt% solution in THF Ethylmagnesium chloride, 2m solution in THF {} {LY} Ethyl magnesium chloride,2.0M solution in THF,Safeseal {} {} {LY} Ethyl magnesium chloride,2.0M solution in THF,Safeseal {} {} {} {LY} Ethyl magnesium chloride,2.0M solution in THF,Safeseal {} {} {} {} {LY} Ethyl magnesium chloride,2.0M solution in THF,Safeseal {} {} {} {} {} {LY} Ethyl magnesium chloride,2.0M solution in THF,Safeseal {} {} {} {} {} {} { {} {} {} {} {} {} {LY} Ethyl magnesium chloride,2.0M soluti
Reaxys-RN3910296
Chemical Name Translation乙基氯化镁
InChIKeyZWNJJACKPNTXHY-UHFFFAOYSA-M
LabNetwork Molecule IDLN00224846
MDL NumberMFCD00000472
CAS Number2386-64-3
Canonical SMILESCC[Mg]Cl
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分类

  • {SNA} Acids & Bases, Alkyl, Bases, Chemical Synthesis, Grignard Reagents, Organic Bases, Organometallic Reagents, Synthetic Reagents
  • {SNA} Alkyl, Chemical Synthesis, Grignard Reagents, Organic Bases, Organometallic Reagents, Synthetic Reagents

相关文献及参考

  • Beilstein: 4,656

安全信息

Signal word Danger
GHS Symbol
WGK Germany1
Safety Statements
  • S12 Do not keep the container sealed 不要将容器密封;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S30 Never add water to this product 切勿将水加入该产品中;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S6 Keep under ... (inert gas to be specified by the manufacturer) 将该物质保存在生产厂家指定的惰性气体中;
  • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中,保持干燥;
Risk Statements
  • R11 Highly flammable 非常易燃
  • R12 Extremely flammable 极端易燃
  • R14 Reacts violently with water 遇水会猛烈反应
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应,释放出高度可燃气体
  • R17 Spontaneously flammable in air 在空气中能够自燃
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R37 Irritating to respiratory system 刺激呼吸道
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P222 Do not allow contact with air. 不要与空气接触。
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能,因为会剧烈反应可能产生闪火。
  • P231+P232
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353
  • P305+P351+P338+P310
  • P335+P334
  • P370+P378
  • P402+P404
  • P403+P233
  • P403+P235
  • P422 Store contents under… 存储目录在…之下。
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H351 Suspected of causing cancer 怀疑致癌
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体,可自燃。
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 4.3 F+,C,F F,C
UN Number 3399
Packing GroupI
Hazard Class4.3/3
Storage condition -20°C {LY} -20°C {} {LY} -20°C {} {} {LY} -20°C {} {} {} {LY} -20°C {} {} {} {} {LY} -20°C {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Restrict 危险品

其他信息

  • Sigma Aldrich:2386-64-3(sigmaaldrich)
  • 下游产品:四氢芳樟醇 --> 异维 A 酸 --> 4-(2,6,6-三-甲基3-环己烯-1-基)2-丁烯-1-酮
  • 乙基氯化镁价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 E0135 乙基氯化镁(18%的四氢呋喃溶液,约2mol/L) Ethylmagnesium Chloride (18% in Tetrahydrofuran, ca. 2mol/L) 250G 220元 2010/06/21 252578000 乙基氯化镁 Ethylmagnesium chloride , 2.7M (25 wt.%) solution in THF, AcroSeal® 800 ML 1914元 2010/06/21 252570024 乙基氯化镁 Ethylmagnesium chloride , 2.7M (25 wt.%) solution in THF, AcroSeal® 2.4 LT 4893元
  • Acros Organics:乙基氯化镁 Ethylmagnesium chloride, 2.0M solution in THF, AcroSeal?(2386-64-3)
  • 存储注意事项:湿度敏感;惰性气体保护
  • F:1-3-10
  • TCI Shanghai:乙基氯化镁(18%的四氢呋喃溶液,约2mol/L) Ethylmagnesium Chloride (18% in Tetrahydrofuran, ca. 2mol/L)(2386-64-3)
  • MOL 文件:2386-64-3.mol

系列性分类


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