Dichloromethylphenylsilane 二氯(甲基)苯基硅烷
CAS 149-74-6 MFCD00000490
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分类
- {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
- {SNA} Chemical Synthesis, Protecting and Derivatizing Reagents, Protection and Derivatization, Silicon-Based, Synthetic Reagents
相关文献及参考
- Short: III/35D2
- Short: III/20b
- Bifunctional reagent for the preparation of methylphenylsilyl derivatives of diols.
安全信息
- R14 Reacts violently with water 遇水会猛烈反应
- R34 Causes burns 会导致灼伤
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
GHS Symbol

- H227 Combustible liquid 可燃液体
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331+P310
- P305+P351+P338
- P305+P351+P338+P310
- P308+P313
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P370+P378
- P501 Dispose of contents/container to..… 处理内容物/容器.....
TYPE OF TEST : LCLo - Lowest published lethal concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 30 mg/m3/2H TOXIC EFFECTS : Lungs, Thorax, or Respiration - other changes Liver - fatty liver degeneration Blood - changes in spleen REFERENCE : TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 3,61,1961
TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Subcutaneous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 100 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other th
TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 100 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 3,81,1961
TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 100 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 3,81,1961
其他信息
- 海关编码:29310095
- Alfa Aesar:二氯甲基苯基硅烷,98% Dichloromethylphenylsilane, 98%(149-74-6)
- Sigma Aldrich:149-74-6(sigmaaldrich)
- 急性毒性:腹注- 大鼠 LDL0: 100 毫克/ 公斤; 腹注- 小鼠 LDL0: 100 毫克/ 公斤
- 用途一:用于有机硅的合成
- 用途二:用于合成有机硅树脂及含苯基硅化合物中,是有机硅重要的单体之一
- 图谱信息:甲基苯基二氯硅烷(149-74-6)核磁图( 13 CNMR) 甲基苯基二氯硅烷(149-74-6)红外图谱(IR1) 甲基苯基二氯硅烷(149-74-6)质谱(MS) 甲基苯基二氯硅烷(149-74-6)核磁图( 1 HNMR)
- 储运特性:库房通风低温干燥; 与氧化剂、H发孔剂、氰化物、碱类分开存放
- 可燃性危险特性:遇氧化剂可燃, 易燃; 燃烧产生有毒氯化物烟雾
- F:10-21
- TSCA:Yes
- MSDS 信息:甲基苯基二氯硅烷(149-74-6).msds
- Acros Organics:二氯甲基苯基硅烷 Dichloromethylphenylsilane, 98%(149-74-6)
- 类别:腐蚀物品
- 甲基苯基二氯硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0790 二氯(甲基)苯基硅烷 Dichloro(methyl)phenylsilane 250G 872元 2014/06/02 P0790 二氯(甲基)苯基硅烷 Dichloro(methyl)phenylsilane 25G 189元 2010/06/21 147381000 甲基苯基二氯硅烷 Dichloromethylphenylsilane 98% 100 ML 403元
- 下游产品:甲基苯基二甲氧基硅烷
- 用途三:用于含苯基硅油及硅橡胶的聚合,提高硅油及硅橡胶的耐热或耐低温性能,是有机硅重要的单体之一。
- 灭火剂:砂土、雾状水、二氧化碳
- MOL 文件:149-74-6.mol
- 毒性分级:高毒
- TCI Shanghai:甲基苯基二氯硅烷 Dichloro(methyl)phenylsilane,>;98.0%(GC)(149-74-6)
- 外观性质:无色透明液体。
- 敏感性:Moisture Sensitive