CAS 1885-14-9 MFCD00000637-Phenyl Chloroformate 氯甲酸苯酯 TAO{mole}

Phenyl Chloroformate 氯甲酸苯酯

CAS 1885-14-9 MFCD00000637

化学结构图

SMILES: O=C(Cl)Oc1ccccc1

化学属性

Mol. Formula	C₇H₅ClO₂
Mol. Weight	156.57
Density	1.248
Refractive index	1.5100 to 1.5130
Vapor Density	1 (vs air)
Boiling Point
Vapor Pressure	1.22 psi ( 20 °C)
Flash Point	75.56°C
TSCA	Yes
Melting Point	No Data Available
Solubility	水解
Stability	对湿度敏感,对热敏感

别名和识别编码

Chemical Name	Phenyl Chloroformate
Synonym	Phenyl Chloroformate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
CAS Number	1885-14-9
EC Number	217-547-8
Beilstein Registry Number	606778
MDL Number	MFCD00000637
PubChem Substance ID	15891
Reaxys-RN	606778
Chemical Name Translation	氯甲酸苯酯
LabNetwork Molecule ID	LN00226528
InChI	InChI=1S/C7H5ClO2/c8-7(9)10-6-4-2-1-3-5-6/h1-5H
Canonical SMILES	O=C(Cl)OC1=CC=CC=C1

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品牌质保精细包装现货库存一流品牌服务

产品应用

用于有机合成产品的中间体。

安全信息

Signal word Danger

GHS Symbol

WGK Germany3

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；

Risk Statements

R22 Harmful if swallowed 吞咽有害
R26 Very toxic by inhalation 吸入极毒
R29 Contact with water liberates toxic gas. 遇水释放出有毒气体
R34 Causes burns 会导致灼伤
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R37 Irritating to respiratory system 刺激呼吸道
R38 Irritating to skin 刺激皮肤
R41 Risk of serious damage to eyes 有严重损伤眼睛的危险

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P234 Keep only in original container. 只保留在原来的容器中。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P284 Wear respiratory protection.? 佩戴呼吸保护装置。
P301+P312
P301+P317
P301+P330+P331
P301+P330+P331+P310
P302+P352
P302+P361+P354
P303+P361+P353
P303+P361+P353+P310+P363
P304+P340
P304+P340+P310
P305+P351+P338
P305+P351+P338+P310
P305+P354+P338
P308+P313
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
P316
P317
P319
P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P330 Rinse mouth. 漱口
P332+P313
P332+P317
P333+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P362+P364
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P370+P378
P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
P403 Store in a well-ventilated place. 储存在通风良好的地方。
P403+P233
P403+P235
P404 Store in a closed container. 贮存于密闭容器中。
P405 Store locked up. 上锁保管。
P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H227 Combustible liquid 可燃液体
H290 May be corrosive to metals 可能腐蚀金属。
H302 Harmful if swallowed 吞食有害
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H315 Causes skin irritation 会刺激皮肤
H317 May cause an allergic skin reaction 可能导致皮肤过敏
H318 Causes serious eye damage 严重伤害眼睛
H330 Fatal if inhaled 吸入致命
H335 May cause respiratory irritation 可能导致呼吸道刺激

Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSFG3850000

Packing GroupII

UN Number 2746 UN 2746 6.1/PG 2

Storage condition 2-8°C {LY} 2-8°C Moisture Sensitive Refrigerator {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

Hazard Codes 6.1 T+

Hazard Class6.1/8

Warnings 危化品目录(2015)

Restrict 危险品

其他信息

存储注意事项:氮气保护;湿度敏感
F:10-19-21
可燃性危险特性:遇水, 或受热放出有毒氯化氢气体
TCI Shanghai:氯甲酸苯酯 Phenyl Chloroformate,>;98.0%(GC)(T)(1885-14-9)
类别:有毒物品
Alfa Aesar:苯基氯甲酸酯,97% Phenyl chloroformate, 99%(1885-14-9)
有刺激味，溶于醇、醚等溶剂中，不溶于水、受热分解。
下游产品:亮丙瑞林 --> 对苯二甲醇 --> 利美尼啶 --> 卡马西泮 --> 富马酸扎莫特罗
Acros Organics:氯甲酸苯酯 Phenyl chloroformate, 99%(1885-14-9)
氯甲酸苯酯价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 xw010346 氯甲酸苯酯;苯基氯甲酸酯 100ml 300元 2011/04/16 C0649 氯甲酸苯酯 Phenyl Chloroformate 500ML 1410元 2011/04/16 C0649 氯甲酸苯酯 Phenyl Chloroformate 25ML 240元
外观性质:无色油状液体。
海关编码:29159020
蒸气压:1.22 psi ( 20 °C)
Sigma Aldrich:1885-14-9(sigmaaldrich)
刺激数据:皮肤-兔子 500 毫克/24小时轻度; 眼睛-兔子 0.05 毫克/24小时重度
急性毒性:吸入-大鼠 LCL0: 44 PPM/4 分; 吸入-小鼠 LC 0.8 毫克/立方米/10 分
图谱信息:氯甲酸苯酯(1885-14-9)质谱(MS) 氯甲酸苯酯(1885-14-9)Raman光谱氯甲酸苯酯(1885-14-9)核磁图( 13 CNMR) 氯甲酸苯酯(1885-14-9)红外图谱(IR1)
MOL 文件:1885-14-9.mol
用途一:用作有机合成试剂
储运特性:库房通风低温干燥; 与氧化剂, 食品分开储运
蒸气密度:1 (vs air)
上游原料:二氯甲烷 --> 苯酚 --> 无水氯化钙 --> N,N-二甲基苯胺 --> 二(三氯甲基)碳酸酯
毒性分级:高毒
方法一:由苯酚与光气反应而得。将苯酚溶于氯仿，在冷却下通入光气，使吸收的光气量与苯酚等摩尔比，于5-10℃搅拌下滴加等摩尔的N，N-二甲基苯胺。然后加冷水稀释，分取油层，依次用稀盐酸和水洗涤。经无水氯化钙干燥后，蒸除氯仿，再减压蒸馏，收集74-75℃（1.73kPa）馏分，即为氯甲酸苯酯。收率90%左右。
MSDS 信息:氯甲酸苯酯(1885-14-9).msds
用途二:用于有机合成。
灭火剂:干粉, 砂土, 泡沫, 二氧化碳
敏感性:Moisture Sensitive
用途三:用于有机合成产品的中间体。