Propyl chloroformate 氯甲酸丙酯
CAS 109-61-5 MFCD00000649
信息真实价格透明
资金保障
专业采购外包团队在线服务
信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- {SNA} Acid Halides, Analytical Reagents, Analytical/Chromatography, Building Blocks, Carbonyl Chlorides, Carbonyl Compounds, Chemical Synthesis, Derivatization Reagents, Derivatization Reagents HPLC, Fluorescence, Organic Building Blocks
- {uni_hamburg} no charge; carbonyl chloride; 1fragment
相关文献及参考
- Short: III/20a
- Merck:13,7940 Beilstein:3(4)24
- Merck:13,7940
- Short: II/14a
- Short: III/38B
安全信息
GHS Symbol
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36 Wear suitable protective clothing 穿戴适当的防护服;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- R10 Flammable 易燃
- R11 Highly flammable 非常易燃
- R23 Toxic by inhalation 吸入有毒
- R34 Causes burns 会导致灼伤
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P303+P361+P353
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P403+P233
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H331 Toxic if inhaled 吸入中毒
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H226 Flammable liquid and vapour 易燃液体和蒸气
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 650 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 37ASAA "Kirk-Othmer Encyclopedia of Chemical Technology," 3rd ed., Grayson, M., and D. Eckroth, eds., New York, John Wiley & Sons, Inc., 1978 Volume(issue)/page/year: 4,758,1978
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 319 ppm/1H TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 37ASAA "Kirk-Othmer Encyclopedia of Chemical Technology," 3rd ed., Grayson, M., and D. Eckroth, eds., New York, John Wiley & Sons, Inc., 1978 Volume(issue)/page/year: 4,758,1978
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : >10 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 37ASAA "Kirk-Othmer Encyclopedia of Chemical Technology," 3rd ed., Grayson, M., and D. Eckroth, eds., New York, John Wiley & Sons, Inc., 1978 Volume(issue)/page/year: 4,758,1978
其他信息
- Sigma Aldrich:109-61-5(sigmaaldrich)
- 储运特性:库房通风低温干燥; 与氧化剂, 碱类, 食品分开储运
- 灭火剂:干粉, 砂土, 泡沫, 二氧化碳
- 蒸气压:0.87 psi ( 20 °C)
- 方法一:其制备方法是在通光气釜内加入正丙醇,启动搅拌,然后通过光气流量计通入光气,通光气温度为30℃左右,继续通光气若干小时,接近终点时取样分析,达标后停止通光气,冷却,然后通氮气赶走光气和氯化氢,对光气进行破坏,取样分析为产品。反应方程式:CH 3 CH 2 CH 2 OH+COCl 2 →ClCOOCH 2 CH 2 CH 3
- 毒性分级:高毒
- 用途二:氯甲酸正丙酯是杀菌剂霜霉威的中间体。
- 上游原料:盐酸 --> 流量计
- 可燃性危险特性:可燃; 遇水, 或受热放出有毒氯化氢气体
- TCI Shanghai:氯甲酸正丙酯 Propyl Chloroformate,>;95.0%(T)(109-61-5)
- MSDS 信息:氯甲酸(正)丙酯(109-61-5).msds
- 氯甲酸丙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010348 氯甲酸正丙酯 100ml 300元 2011/04/16 C0929 氯甲酸丙酯 Propyl Chloroformate 500ML 2470元 2011/04/16 C0929 氯甲酸丙酯 Propyl Chloroformate 25ML 278元
- 外观性质:无色液体。
- 用途一:用作浮选剂及有机合成试剂
- MOL 文件:109-61-5.mol
- 图谱信息:氯甲酸丙酯(109-61-5)Raman光谱 氯甲酸丙酯(109-61-5)核磁图( 1 HNMR) 氯甲酸丙酯(109-61-5)红外图谱(IR1) 氯甲酸丙酯(109-61-5)质谱(MS) 氯甲酸丙酯(109-61-5)核磁图( 13 CNMR)
- 急性毒性:口服-小鼠 LD50: 650 毫克/公斤
- 类别:有毒物品