Phthaloyl Dichloride 邻苯二甲酰氯
CAS 88-95-9 MFCD00000666
信息真实价格透明
资金保障
专业采购外包团队在线服务
信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; carbonyl chloride; 1fragment
- {SNA} Acid Halides, Building Blocks, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks
产品应用
- 有机合成中间体。
相关文献及参考
- Merck: 14,7375
- Can be used for the preparation of volatile acid chlorides from the acids by exchange and distillation of the product from the reaction medium; see, e.g.: Org. Synth. Coll., 3, 422 (1955). For a one step conversion of ethyl esters to the corresponding acid chlorides, with loss of ethyl chloride, see: J. Org. Chem., 44, 2291 (1979).
- Acts as a trap for the nitrite ion in the fluorodenitration of aromatic substrates with Potassium fluoride, 14130: Chem. Lett., 2213 (1989); J. Org. Chem., 56, 6406 (1991).
- Merck: 14,7375 Beilstein:9,805
- Short: III/20b
- Short: III/31a
安全信息
GHS Symbol
- H290 May be corrosive to metals 可能腐蚀金属。
- H312 Harmful in contact with skin 皮肤接触有害
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H318 Causes serious eye damage 严重伤害眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- P234 Keep only in original container. 只保留在原来的容器中。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P264+P265
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331
- P302+P352
- P302+P361+P354
- P303+P361+P353
- P303+P361+P353+P310+P363
- P304+P340
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P305+P354+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
- P316
- P317
- P319
- P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
- P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
- P362+P364
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
- P403+P233
- P405 Store locked up. 上锁保管。
- P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- R34 Causes burns 会导致灼伤
- S20 When using do not eat or drink 使用时,不得进食,饮水;
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
其他信息
- TCI Shanghai:邻苯二甲酰氯 Phthaloyl Chloride,>;98.0%(T)(88-95-9)
- Sigma Aldrich:88-95-9(sigmaaldrich)
- 图谱信息:邻苯二甲酰氯(88-95-9)核磁图( 13 CNMR) 邻苯二甲酰氯(88-95-9)核磁图( 1 HNMR) 邻苯二甲酰氯(88-95-9)质谱(MS) 邻苯二甲酰氯(88-95-9)红外图谱(IR1)
- 遇水、醇分解,溶于醚、氯仿和苯。
- 用途一:有机合成中间体。
- 外观性质:无色至浅黄色液体。
- MSDS 信息:邻苯二甲酰氯(88-95-9).msds
- 下游产品:吡虫啉 --> 庚烯磷 --> 反丁烯二酰氯
- Acros Organics:邻苯二甲酰氯 o-Phthaloyl dichloride, remainder mainly phthalic acid, 90%(88-95-9)
- 邻苯二甲酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0405 邻苯二甲酰氯 Phthaloyl Chloride 25G 185元 2014/06/02 P0405 邻苯二甲酰氯 Phthaloyl Chloride 500G 1120元 2010/06/21 131115000 邻苯二甲酰氯 o-Phthaloyl dichloride 90%, remainder mainly phthalic acid 500 ML 1972元
- 蒸气压:30 mm Hg ( 47 °C)
- 方法一:将148g苯酐与220g五氯化磷混合,加热,逐渐升温至250℃,逸出三氯氧磷,将反应产物减压蒸馏,收集131-133℃(1.2-1.33kPa)馏分,得187g邻苯二甲酰氯。
- Alfa Aesar:苯二甲酰氯,94% Phthaloyl chloride, 94%(88-95-9)
- 敏感性:Moisture Sensitive
- F:21
- 海关编码:29173980
- MOL 文件:88-95-9.mol