Acetyl chloride, 2-phenoxy- 苯氧乙酰氯

CAS 701-99-5 MFCD00000726

化学结构图

701-99-5
SMILES: O=C(Cl)COc1ccccc1

化学属性

Mol. FormulaC8H7ClO2
Mol. Weight171
Density1.235
Refractive index1.5320 to 1.5390
Flash Point108°C(lit.)
TSCAYes
Boiling Point225-226

别名和识别编码

Chemical NameAcetyl chloride, 2-phenoxy-
CAS Number701-99-5
EC Number211-862-4
Beilstein Registry Number607585
MDL NumberMFCD00000726
PubChem Substance ID87574369
Synonym Acetylchloride,phenoxy- 苯氧基乙酰氯 苯氧乙酰氯 PHENOXYACETYL CHLORIDE Acyl chloride kind Phenyloxyacetyl chloride phenoxy-acetylchlorid LABOTEST-BB LT00643586 AKOS BBS-00003927 Phenoxyacetic acid chloride
Reaxys-RN607585
Chemical Name Translation苯氧乙酰氯
InChIKeyPKUPAJQAJXVUEK-UHFFFAOYSA-N
LabNetwork Molecule IDLN00192054
InChIInChI=1S/C8H7ClO2/c9-8(10)6-11-7-4-2-1-3-5-7/h1-5H,6H2
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分类

  • {SNA} Acid Halides, Building Blocks, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks

相关文献及参考

  • Can be used to protect OH groups. The phenoxyacetate group is 50x more labile to aqueous ammonia than acetate: Tetrahedron Lett., 4273 (1968). It can also be cleaved with methanolic t-BuNH 2 : Chem. Lett., 965 (1982).

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S8 Keep container dry 保持容器干燥;
Risk Statements
  • R14 Reacts violently with water 遇水会猛烈反应
  • R34 Causes burns 会导致灼伤
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Packing GroupII
UN Number 3265
Storage condition Moisture Sensitive Store at RT.
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 8 C
Hazard Class8

其他信息

  • Sigma Aldrich:701-99-5(sigmaaldrich)
  • 图谱信息:苯氧乙酰氯(701-99-5)质谱(MS) 苯氧乙酰氯(701-99-5)核磁图( 13 CNMR) 苯氧乙酰氯(701-99-5)核磁图( 1 HNMR) 苯氧乙酰氯(701-99-5)红外图谱(IR1)
  • 海关编码:29189090
  • TCI Shanghai:苯氧基乙酰氯 Phenoxyacetyl Chloride,>;98.0%(GC)(T)(701-99-5)
  • Alfa Aesar:苯氧乙酰氯,98% Phenoxyacetyl chloride, 98%(701-99-5)
  • F:10-19
  • MOL 文件:701-99-5.mol
  • Acros Organics:苯氧基乙酰氯 Phenoxyacetyl chloride, 98%(701-99-5)
  • 苯氧乙酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0113 苯氧基乙酰氯 Phenoxyacetyl Chloride 25G 248元 2014/06/02 P0113 苯氧基乙酰氯 Phenoxyacetyl Chloride 500G 2020元 2010/06/21 169940500 苯氧乙酰氯 Phenoxyacetyl chloride 98% 50 GR 648元
  • MSDS 信息:Phenoxyacetyl chloride(701-99-5).msds
  • 敏感性:Moisture Sensitive

系列性分类


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