(Chloromethyl)Trichlorosilane (氯甲基)三氯硅烷
CAS 1558-25-4 MFCD00000873
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分类
- {SNA} Chemical Synthesis, Protecting and Derivatizing Reagents, Protection and Derivatization, Silicon-Based, Synthetic Reagents
- {SA} Chemical Synthesis, Materials Science, Nanomaterials, POSS Precursors and Intermediates, Protecting and Derivatizing Reagents, Protection and Derivatization, RSiCl3, Silicon-Based, Silsesquioxanes: POSS Nanohybrids, Synthetic Reagents
- {uni_hamburg} no charge; 1fragment
相关文献及参考
- Short: II/25B Title: Structure Data Of Free Polyatomic Molecules: Molecules containing One or Two Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25B Year: 1999 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-63645-5 ISBN: 978-3-540-63645-8 Internet Resource: DOI:10.1007/b68834 RefComment: IX, 512 pages. Hardcover Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.
- Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
- Short: III/35F Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and
安全信息
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H330 Fatal if inhaled 吸入致命
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P301+P330+P331
- P304+P340
- P305+P351+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P402+P404
- R14 Reacts violently with water 遇水会猛烈反应
- R26 Very toxic by inhalation 吸入极毒
- R34 Causes burns 会导致灼伤
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S8 Keep container dry 保持容器干燥;
TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 100 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,37,1982
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 60 mg/m3/2H TOXIC EFFECTS : Brain and Coverings - other degenerative changes Lungs, Thorax, or Respiration - dyspnea Blood - hemorrhage REFERENCE : TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 3,33,1961
TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 100 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 3,81,1961
TYPE OF TEST : LC - Lethal concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : >5 mg/m3/2H TOXIC EFFECTS : Brain and Coverings - other degenerative changes Lungs, Thorax, or Respiration - dyspnea
其他信息
- 可燃性危险特性:易燃; 火场排放有毒硅氧化物, 氯化物烟雾
- Acros Organics:氯甲基三氯硅烷 (Chloromethyl)trichlorosilane, 95%(1558-25-4)
- 下游产品:氯甲基三乙氧基硅烷
- 毒性分级:高毒
- 图谱信息:(氯甲基)三氯硅烷(1558-25-4)红外图谱(IR1) (氯甲基)三氯硅烷(1558-25-4)质谱(MS)
- 类别:腐蚀物质
- (氯甲基)三氯硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 320470050 (氯甲基)三氯硅烷 (Chloromethyl)trichlorosilane 95% 5 GR 437元 2010/06/21 320470250 (氯甲基)三氯硅烷 (Chloromethyl)trichlorosilane 95% 25 GR 903元 2010/05/25 L16433 (氯甲基)三氯硅烷, 97% (Chloromethyl)trichlorosilane, 97% 5g 230元
- 存储注意事项:湿度敏感
- MOL 文件:1558-25-4.mol
- 敏感性:Moisture Sensitive
- 爆炸物危险特性:与水反应激烈; 放出腐蚀物质氯化氢等
- 储运特性:库房低温, 通风, 干燥 ; 防潮, 密闭封存
- Sigma Aldrich:1558-25-4(sigmaaldrich)
- F:10
- 职业标准:STEL 1 毫克/立方米
- MSDS 信息:(Chloromethyl)trichlorosilane(1558-25-4).msds
- 急性毒性:口服-小鼠 LDL0: 100 毫克/公斤; 吸入-大鼠 LC >; 5 毫克/立方米/2小时
- TSCA:Yes
- 灭火剂:二氧化碳, 泡沫, 干粉
- Alfa Aesar:(氯甲基)三氯硅烷,97% (Chloromethyl)trichlorosilane, 97%(1558-25-4)