1,4-Bis(Methylamino)Anthraquinone 1,4-双(甲基氨基)蒽醌

CAS 2475-44-7 MFCD00001198

化学结构图

2475-44-7
SMILES: CNc1ccc(NC)c2c1C(=O)c1ccccc1C2=O

化学属性

Mol. FormulaC16H14N2O2
Mol. Weight266.29
Melting Point220-222 °C
TSCAYes
Appearance 蓝色粉末。不溶于水,溶于丙酮、乙醇、冰醋酸、硝基苯、吡啶和甲苯。于浓硫酸中呈红光棕色。
Boiling Point409.5 °C at 760 mmHg

别名和识别编码

Chemical Name1,4-Bis(Methylamino)Anthraquinone
Synonym 1,4-Bis(methylamino)anthracene-9,10-dione {LY} 1,4-Bis(methylamino)anthracene-9,10-dione {} {LY} 1,4-Bis(methylamino)anthracene-9,10-dione {} {} {LY} 1,4-Bis(methylamino)anthracene-9,10-dione {} {} {} {LY} 1,4-Bis(methylamino)anthracene-9,10-dione {} {} {} {} {LY} 1,4-Bis(methylamino)anthracene-9,10-dione {} {} {} {} {} {LY} 1,4-Bis(methylamino)anthracene-9,10-dione {} {} {} {} {} {} {LY} 1,4-Bis(methylamino)anthracene-9,10-dione {} {} {} {} {} {} {} {LY} 1,4-Bis(methylamino)anthracene-9,10-dione {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Bis(methylamino)anthracene-9,10-dione {} {} {} {} {} {} {} {} {} {LY} 1,4-Bis(methylamino)anthracene-9,10-dione {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Bis(methylamino)anthracene-9,10-dione {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Bis(methylamino)anthracene-9,10-dione {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Bis(methylamino)anthracene-9,10-dione {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00001198
CAS Number2475-44-7
EC Number219-602-1
Beilstein Registry Number2220693
PubChem Substance ID87558976
Reaxys-RN2220693
Chemical Name Translation1,4-双(甲基氨基)蒽醌
InChIKeyQOSTVEDABRQTSU-UHFFFAOYSA-N
LabNetwork Molecule IDLN00222679
InChIInChI=1S/C16H14N2O2/c1-17-11-7-8-12(18-2)14-13(11)15(19)9-5-3-4-6-10(9)16(14)20/h3-8,17-18H,1-2H3
Canonical SMILESO=C1C2=C(C=CC=C2)C(C3=C(NC)C=CC(NC)=C13)=O
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分类

  • {SNA} D, Stains & Dyes, A to Z, Stains and Dyes, 细胞生物学, 血液学和组织学
  • {uni_hamburg} no charge; carbocycle; aromatic; large ring; fused rings; 6ring; 10ring; 14ring; ketone; 1fragment
  • {Chemicalbook} 染料: 溶剂染料: 溶剂染料
  • {SNA} D, Hematology and Histology, Stains & Dyes, A to Z, Stains and Dyes

相关文献及参考

  • Short: III/35D2 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Carbon-13, Part 2: Aromatic Compounds Author: Mikhova, B. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35D2 Year: 2005 Keyword: aromatic compounds; carbon-13; chemical shift; coupling constant; molecular structure ISBN: 978-3-540-20189-2 ISBN: 3-540-20189-0 Internet Resource: DOI:10.1007/b83345 RefComment: VIII, 291 p., Hardcover RefComment: Written for Science and engineers in the fields of physics, chemistry and physical chemistry who inted to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, orient by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum. The spectral lines of the nuclei are highly influenced by the chemical environment i.e. the structure and interaction of the molecules. NMR is now the leading technique and a powerful tool for the investigation of the structure and interaction of molecules. The present Landolt-Börnstein volume III/35 Nuclear Magnetic Resonance (NMR) Data is therefore of major interest to all scientists and engineers who intend to use NMR to study the structure and the binding of molecules. Volume III/35 "NMR-Data" is divided into several subvolumes and parts. Subvolume III/35A contains the nuclei 11B and 31P, subvolume III/35B contains the nuclei 19F and 15N, subvolume III/35C contains the nucleus 1H, subvolume III/35D contains the nucleus 13C, subvolume III/35E contains the nucleus 17O, and subvolume III/35G contains the nucleus 77Se. More nuclei will be presented later.
  • Short: IV/20C Title: Vapor Pressure and Antoine Coefficients for Nitrogen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume:

安全信息

RTECSCB5750000
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Hazard Codes Xi
GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 180 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#01356

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 5 mg/plate
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   19(Suppl 20),8,1992

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • MOL 文件:2475-44-7.mol
  • 可燃性危险特性:可燃; 受热分解有毒氮氧化物烟雾
  • 毒性分级:高毒
  • 急性毒性:静脉-小鼠 LD50: 180 毫克/公斤
  • Sigma Aldrich:2475-44-7(sigmaaldrich)
  • TCI Shanghai:分散蓝14 Disperse Blue 14(2475-44-7)
  • 灭火剂:干粉,泡沫,砂土,二氧化碳, 雾状水
  • 用途一:透明蓝 GP 用于各种热塑性塑料的着色,也用于制造烟花。
  • MSDS 信息:1,4-Bis(methylamino)anthraquinone(2475-44-7).msds
  • 色指数:61500
  • Alfa Aesar:1,4-双(甲基氨基)蒽醌,95% 1,4-Bis(methylamino)anthraquinone, 95%(2475-44-7)
  • 方法一:以 1,4-二羟基蒽醌和一甲胺为原料,将两者在锌粉存在下缩合即得产物。经过滤、干燥得成品。。
  • 上游原料:1,4-二羟基蒽醌
  • 储运特性:库房通风低温干燥; 与食品原料分开存放
  • 分散蓝 14价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D3280 分散蓝14 Disperse Blue 14 25G 1030元 2010/05/25 L00903 1,4-双(甲基氨基)蒽醌, 95% 1,4-Bis(methylamino)anthraquinone, 95% 5g 396元 2010/05/25 L00903 1,4-双(甲基氨基)蒽醌, 95% 1,4-Bis(methylamino)anthraquinone, 95% 25g 1414元
  • 类别:有毒物品

系列性分类


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