2-Aminoanthraquinone 2-氨基蒽醌
CAS 117-79-3 MFCD00001233
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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分类
- Building Blocks, C13 to C14, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
- {SNA} Building Blocks, C13 to C14, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
相关文献及参考
- Beil. 14 ,IV,447
- Aldrich MSDS 1 , 58:B / Corp MSDS 1 (1), 135:C / FT-IR 1 (2), 89:D / FT-IR 2 (2), 2498:D / IR-Spectra (3), 901:D / IR-Spectra (2), 788:F / RegBook 1 (2), 1691:H / Sax 6 , 190 / Structure Index 1 , 268:B:7
安全信息
GHS Symbol
- H351 Suspected of causing cancer 怀疑致癌
- H302+H312+H332
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P308+P313
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P301+P312+P330
- P302+P350
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
- P281 Use personal protective equipment as required. 使用所需的个人防护装备。
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
- R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
TYPE OF TEST : TD - Toxic dose (other than lowest) ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 3780 gm/kg/78W-C TOXIC EFFECTS : Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors REFERENCE : IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 27,191,1982
TYPE OF TEST : TD - Toxic dose (other than lowest) ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 5600 gm/kg/80W-C TOXIC EFFECTS : Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors REFERENCE : IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 27,191,1982
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 115 gm/kg/78W-C TOXIC EFFECTS : Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors REFERENCE : NCITR* National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD) No.0-205. For publisher information, see NTPTR*. Volume(issue)/page/year: NCI-TR-144,1978
TYPE OF TEST : TD - Toxic dose (other than lowest) ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 1890 gm/kg/78W-C TOXIC EFFECTS : Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors REFERENCE : IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 27,191,1982
{hazard
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 1500 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 21(12),27,1977
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 1 mg/plate REFERENCE : ENMUDM Environmental Mutagenesis. (New York, NY) V.1-9, 1979-87. For publisher information, see EMMUEG. Volume(issue)/page/year: 7(Suppl 5),1,1985
TYPE OF TEST : Micronucleus test TEST SYSTEM : Rodent - mouse Cells - not otherwise specified DOSE/DURATION : 6 mg/L REFERENCE : EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 24,96,1994
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Escherichia coli DOSE/DURATION : 1 mg/plate REFERENCE : ENMUDM Environmental Mutagenesis. (New York, NY) V.1-9, 1979-87. For publisher information, see EMMUEG. Volume(issue)/page/year: 7(Suppl 5),1,1985
其他信息
- MSDS 信息:2-氨基蒽醌(117-79-3).msds
- Alfa Aesar:2-氨基蒽醌,tech.90% 2-Aminoanthraquinone, tech. 90%(117-79-3)
- 2-氨基蒽醌价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0255 2-氨基蒽醌 2-Aminoanthraquinone 500G 883元 2014/06/02 A0255 2-氨基蒽醌 2-Aminoanthraquinone 25G 195元 2010/05/25 L03368 2-氨基蒽醌, tech. 90% 2-Aminoanthraquinone, tech. 90% 500g 830元
- 毒性分级:中毒
- 类别:有毒物品
- 用途一:用于制蒽醌染料等
- 上游原料:硫酸铜 --> 3-硝基苯磺酸钠 --> 2-蒽醌磺酸 --> 2-氯蒽醌 --> 防染盐S
- 外观性质:红色或橙棕色针状结晶。
- 图谱信息:2-氨基蒽醌(117-79-3)红外图谱(IR1) 2-氨基蒽醌(117-79-3)核磁图( 1 HNMR) 2-氨基蒽醌(117-79-3)红外图谱(IR2) 2-氨基蒽醌(117-79-3)核磁图( 13 CNMR) 2-氨基蒽醌(117-79-3)质谱(MS)
- 急性毒性:腹腔-小鼠LD50: 1500 毫克/公斤
- Sigma Aldrich:117-79-3(sigmaaldrich)
- 下游产品:颜料蓝 60 --> 阳离子蓝 FGL --> 还原黄G --> 还原棕 3 --> 还原橙16 --> 溶剂蓝63 --> 还原蓝 6
- TCI Shanghai:2-氨基蒽醌 2-Aminoanthraquinone,>;80.0%(LC)(117-79-3)
- 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
- 储运特性:库房通风低温干燥
- 方法一:(1)由蒽醌-2-磺酸铵盐氨化制得,工艺过程如下:将蒽醌-2-磺酸铵盐240kg、间硝基苯磺酸钠(防染盐S)70kg及25%氨水(含氨100%174kg)打浆,压入高压釜。加热至184-188℃,压力为3.73-3.92MPa(表压),保温压反应10h,反应毕,边冷却,边放氨。冷至80℃,将物料压入脱氨锅在80℃脱氨2h。升温至100℃,吸滤,用100℃热水3000L洗涤。将滤饼烘干,得2-氨基蒽醌。收率70%。(2)2-氯蒽醌和氨水在催化剂硫酸铜的悬浮物中经高温压反应,制得2-氨基蒽醌。先将2-氯蒽醌、硫酸铜、氨水打浆,充分混合压入氨化高压锅中,升温至213-215℃,于5.1-5.39MPa压力下反应5h,放压回收余氨。将反应产物压入过滤器,经过滤、水洗、干燥而得成品。产品规格:外观为红棕色粉末的工业品含量(以总氨值计)86.0%。原料消耗定额:2-氯蒽醌(96%)1150kg/t、氨水(95%)400kg/t、硫酸铜(96%)87.8kg/t。
- 用途二:还原染料的中间体,主要用于制造还原蓝RSN,还原黄G,还原黄8G和1-氯-2-氨基蒽醌染料。此外,在造纸工业中可用作催化剂以节约烧碱。
- 可燃性危险特性:可燃;燃烧产生有毒氮氧化物烟雾
- MOL 文件:117-79-3.mol