1,1-Bis(diphenylphosphino)ferrocene 1,1'-双(二苯基膦)二茂铁
CAS 12150-46-8 MFCD00001422
化学结构图
SMILES: [CH]1[CH][CH][C](P(c2ccccc2)c2ccccc2)[CH]1.[CH]1[CH][CH][C](P(c2ccccc2)c2ccccc2)[CH]1.[Fe]
化学属性
| Mol. Formula | C34H28FeP2 |
|---|---|
| Mol. Weight | 554.39 |
| Melting Point | 181-182 °C (dec.)(lit.) |
| TSCA | No |
| Density | 1.527 |
| Stability | 对湿度敏感 |
| Appearance | yellow to orange xtl. |
别名和识别编码
| Chemical Name | 1,1-Bis(diphenylphosphino)ferrocene |
|---|---|
| CAS Number | 12150-46-8 |
| Alfabeta Name | BISDIPHENYLPHOSPHINOFERROCENE 11()-,' |
| MDL Number | MFCD00001422 |
| Synonym | 1,1'-Bis(diphenylphosphino)ferrocene 1,1'-Bis-(diphenylphosphino)-ferrocen 1,1'-Ferrocenbis-(diphenylphosphin) 1,1'-Ferrocenebis(diphenylphosphine) 1,1'-bis(diphenylphosphino) ferrocene 1,1'-Ferrocendiylbis(diphenylphosphine) 1,1'-Ferrocenebis(diphenylphosphine); 1,1'-Ferrocenediyl-bis(diphenylphosphine) 1,1'-双(二苯基膦)二茂铁 1,1-Bis(diphenylphosphino)ferrocene 1,1′-Ferrocenediyl-bis(diphenylphosphine), 1,1′-Ferrocenebis(diphenylphosphine) 1,1′-二茂铁二基-双(二苯基膦) 1,1′-双(二苯基膦)二茂铁 dppf 1,1′-二茂铁二基-双(二苯基膦) dppf 1,1′-双(二苯基膦)二茂铁 Cyclopentadienyldiphenylphosphine Dppf dppf 双(二苯基膦)二茂铁 双(二苯基膦)二茂铁;1,1′-二茂铁二基-双(二苯基膦) 锆离子载体 I |
| PubChem Substance ID | 87564906 |
| EC Number | 430-420-3 |
| Beilstein Registry Number | 2384789 |
| Chemical Name Translation | 1,1'-双(二苯基膦)二茂铁 |
| LabNetwork Molecule ID | LN01358153 |
信息真实价格透明
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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现货库存
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分类
- Aromatics
- Catalyst
- {SNA} Analytical/Chromatography, Ion Sensor Materials, Ionophores Potentiometric for ISE
- {SNA} 12 Principles Alig
- {SNA} Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Development Quantities for Research, Phosphine Compounds, Polydentate Phosphine Ligands
- Chelating Agents & Ligands
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Polydentate Phosphine Ligands
- {SNA} 12 Principles Aligned Products, Related Palladacycles, Buchwald Ligands and Complexes, Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Development Quantities for Research, Greener Alternative Products, Phosphine Compounds, Polydentate Phosphine Ligands
产品应用
- 有机金属催化剂（配体）。通过钯-膦催化的 C-C 和 C-O 键顺序成键反应制备新型官能化呋喃衍生物。
相关文献及参考
- Short: III/35D5
- Nataro, C., et al.: J. Chem. Ed., 86, 1412 (2009),
- Short: ELINCS
- Hindered bidentate ligand used in, for example, the Ni-catalyzed Suzuki-type crossed coupling of arylboronic acids with aryl mesylates to give biaryls: J. Org. Chem., 60, 1060, 1066 (1995), and of thiophenolates with aryl mesylates to give unsymmetrical diaryl sulfides: J. Org. Chem., 60, 6895 (1995).
安全信息
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S37 Wear suitable gloves 戴适当手套；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
- R25 Toxic if swallowed 吞咽有毒
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352+P312+P362+P364
- P304+P340+P312
- P305+P351+P338
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P313 Get medical advice/attention. 获取医疗咨询/就医
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H302+H312+H332
其他信息
- 在空气中稳定。
