gamma-Terpinene gamma-松油烯

CAS 99-85-4 MFCD00001537

化学结构图

99-85-4
SMILES: CC1=CCC(C(C)C)=CC1

化学属性

Mol. FormulaC10H16
Mol. Weight136.24
Refractive index1.4720 to 1.4750
Vapor Density4.7 (vs air)
Boiling Point182
Vapor Pressure~0.7 mmHg ( 20 °C)
Density0.85
Flash Point56°C(lit.)
Appearance 天然品存在于芫荽子油、柠檬油、枯茗油和香旱芹油等中。 无色液体。具有柑橘和柠檬香气。沸点182℃。溶于乙醇和大多数非挥发性油,不溶于水。遇空气易氧化。

别名和识别编码

Chemical Nameγ-Terpinene
MDL NumberMFCD00001537
CAS Number99-85-4
Synonym γ-松油烯 1,4-p-menthadiene 1,4-Cyclohexadiene, 1-methyl-4-(1-methylethyl)- 1,4-P-MENTHADIENE 1,4-p-menthadiene 1-ISOPROPYL-4-METHYL-1,4-CYCLOHEXADIENE 1-ISOPROPYL-4-METHYL-1,4-CYCLOHEXADIENE P-MENTHA-1,4-DIENE 1-Isopropyl-4-methyl-cyclohexa-1,4-diene 1-Methyl-4-(1-methylethyl)-1,4-cyclohexadiene 1-Methyl-4-(1-methylethyl)-1,4-cyclohexadiene 1-异丙基-4-甲基-1,4-环己二烯 对薄荷-1,4-二烯 1-Methyl-4-isopropyl-1,4-cyclohexadiene 1-Methyl-4-isopropylcyclohexadiene-1,4 1-isopropyl-4-methyl-1,4-cyclohexadiene 1-isopropyl-4-methyl-1,4-cyclohexadiene (gamma-terpinene) 1-isopropyl-4-methyl-cyclohexa-1,4-diene 1-methyl-4-(1-methylethyl)-1,4-cyclohexadiene 1-methyl-4-(1-methylethyl)-4-cyclohexadiene 1-methyl-4-isopropyl-1,4-cyclohexadiene alp
PubChem Substance ID7461
EC Number202-794-6
Beilstein Registry Number2038347
Reaxys-RN2038347
Merck Number9170
Chemical Name Translationgamma-松油烯
Wiswesser Line NotationL6U CUTJ AY1&1 D1
LabNetwork Molecule IDLN00193807
InChIInChI=1S/C10H16/c1-8(2)10-6-4-9(3)5-7-10/h4,7-8H,5-6H2,1-3H3
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分类

  • {Chemicalbook} 食品添加剂: 食用香料(增香剂): 天然等同香料和人造香
  • {SNA} Alphabetical Listings, Certified Food Grade Products, Certified Natural Products, E-H, Flavors and Fragrances, Kosher Certified Products, Q-Z, R-Z
  • {SNA} Alphabetical Listings, Certified Food Grade Products, Certified Natural Products, E-H, Flavors and Fragrances, Follows IFRA Guidelines, Hal
  • {uni_hamburg} no charge; carbocycle; alicycle; 6RingOnly; 6ring; 1fragment
  • {SNA} Alphabetical Listings, Certified Food Grade Products, E-H, Flavors and Fragrances, Halal Certified Products, Kosher Certified Products, O - Z, Q-Z, R-Z

相关文献及参考

  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: IV/6 Title: Static Dielectric Constants of Pure Liquids and Binary Liquid Mixtures Author: Wohlfarth, Ch. Editor: Madelung, O. Source: Landolt-Börnstein, New Series Volume: IV/6 Year: 1991 Keyword: organic compounds; dielectric constant; liquids; mixtures ISBN: 3-540-54417-8 ISBN: 978-3-540-54417-3 Internet Resource: DOI:10.1007/b44266 RefComment: VIII, 521 pages.
  • Short: IV/8D Title: Densities of Monocyclic Hydrocarbons Author: Wilhoit, R.C.; Hong, X.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R.; Marsh, K.N. Source: Landolt-Börnstein, New Series Volume: IV/8D Year: 1997 Keyword: organic compounds; density; liquids ISBN: 3-540-62509-7 ISBN: 978-3-540-62509-4 Internet Resource: DOI:10.1007/b62066 RefComment: 117 figs., XIV, 466 pages, with CD-ROM, Hardcover
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSOS8070000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P316
  • P303+P361+P353
  • P305+P351+P338
  • P331 Do NOT induce vomiting.. 不要催吐。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P370+P378
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Hazard Codes
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
UN Number 3295
Packing GroupIII
Hazard Class3
Storage condition 2-8°C
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3650 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher information, see FCTOD7.  Volume(issue)/page/year: 14,875,1976

其他信息

  • 蒸气密度:4.7 (vs air)
  • Sigma Aldrich:99-85-4(sigmaaldrich)
  • 方法一:由马缨丹(Lantana camara)精油分离而得。 由对异丙基甲苯在液氨中用乙醇和钠反应(Birch反应)而得。
  • 含量分析:按GT-10-4中用极性杜进行气相色谱法测定。
  • 图谱信息:GAMMA-萜品烯,松油烯(99-85-4)核磁图( 13 CNMR) GAMMA-萜品烯,松油烯(99-85-4)红外图谱(IR1) GAMMA-萜品烯,松油烯(99-85-4)核磁图( 1 HNMR) GAMMA-萜品烯,松油烯(99-85-4)质谱(MS)
  • 蒸气压:~0.7 mm Hg ( 20 °C)
  • 参考质量标准:FCC,1996 含量 ≥95.0% 折射率(n D 20 ) 1.473~1.477 相对密度(d 25 25 ) 0.841~0.845
  • TCI Shanghai:γ-萜品烯 gamma-Terpinene,>;95.0%(GC)(99-85-4)
  • F:10-23
  • 上游原料:氨 --> 4-异丙基甲苯
  • 使用限量:FEMA(mg/kg):焙烤食品13.6;冻乳品8.6;肉制品20.0;糖果10.3;布丁类8.6;软饮料8.5;酒类10.0;硬糖50.0;胶姆糖25.0。 适度为限(FDA§172.515,2000)。
  • FEMA:3559
  • 毒性:GRAS(FEMA)。 LD 50 3650mg/kg(大鼠,经口)。
  • Acros Organics:gamma-松油烯 gamma-Terpinene, stabilized, 98+%(99-85-4)
  • GAMMA-萜品烯,松油烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0318 γ-萜品烯 gamma-Terpinene 500ML 1930元 2014/06/02 M0318 γ-萜品烯 gamma-Terpinene 25ML 220元 2010/06/21 207505000 GAMMA-萜品烯,松油烯 gamma-Terpinene 98+%, stabilized 500 ML 2198元
  • 用途一:香料。主要用以配制人造柠檬和薄荷精油。
  • MOL 文件:99-85-4.mol

系列性分类


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