2-Chlorocyclohexanone 2-氯环己酮
CAS 822-87-7 MFCD00001626
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分类
- {uni_hamburg} no charge; carbocycle; alicycle; 6RingOnly; 6ring; ketone; racemate; 1fragment
- {SNA} Building Blocks, C3 to C6, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
相关文献及参考
- Short: II/25D
- Beilstein:7,10
- Short: III/38B
安全信息
GHS Symbol
- S24 Avoid contact with skin 避免皮肤接触;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S37 Wear suitable gloves 戴适当手套;
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P350
- P302+P352+P333+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P337+P313
- P337+P313
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H315 Causes skin irritation 会刺激皮肤
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H227 Combustible liquid 可燃液体
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 830 mg/kg TOXIC EFFECTS : Behavioral - convulsions or effect on seizure threshold Behavioral - coma Behavioral - analgesia REFERENCE : COREAF Comptes Rendus Hebdomadaires des Seances, Academie des Sciences. (Paris, France) V.1-261, 1835-1965. For publisher information, see CRASEV. Volume(issue)/page/year: 254,2683,1962
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 370 nmol/plate REFERENCE : CBINA8 Chemico-Biological Interactions. (Elsevier Scientific Pub. Ireland Ltd., POB 85, Limerick, Ireland) V.1- 1969- Volume(issue)/page/year: 45,305,1983
其他信息
- 图谱信息:2-氯环己酮(822-87-7)核磁图( 13 CNMR) 2-氯环己酮(822-87-7)质谱(MS) 2-氯环己酮(822-87-7)红外图谱(IR1)
- TCI Shanghai:2-氯环己酮(含稳定剂氢醌) 2-Chlorocyclohexanone (stabilized with HQ),>;95.0%(GC)(822-87-7)
- 可燃性危险特性:可燃; 热分解排出有毒氯化物烟雾
- 类别:有毒物质
- Acros Organics:2-氯环己酮 2-Chlorocyclohexanone, stabilized, 95%(822-87-7)
- 毒性分级:中毒
- 储运特性:库房低温通风干燥
- 2-氯环己酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C0965 2-氯环己酮(含稳定剂HQ) 2-Chlorocyclohexanone (stabilized with HQ) 25G 714元 2010/06/21 108960050 2-氯环己酮 2-Chlorocyclohexanone 95%, stabilized 5 GR 278元 2010/06/21 108961000 2-氯环己酮 2-Chlorocyclohexanone 95%, stabilized 100 GR 2294元
- color:colorless to very deep brown
- 用途一:有机合成中间体。
- Alfa Aesar:2-氯环己酮,97%,stab.withcalciumcarbonate/magnesiumoxide 2-Chlorocyclohexanone, 97%, stab. with calcium carbonate/magnesium oxide(822-87-7)
- F:10-19
- 上游原料:环己酮
- Sigma Aldrich:822-87-7(sigmaaldrich)
- MSDS 信息:2-Chlorocyclohexanone(822-87-7).msds
- 灭火剂:雾水,二氧化碳, 泡沫, 干粉
- 方法一:由环己酮经氯化而得。将氯气通入环己酮水溶液进行氯化,反应结束后分出2-氯环己酮液层,水层用乙醚提取。提取液与氯环己酮液层合并,先用水洗,再用氯化钠饱和溶液洗,以无水硫酸钠干燥。过滤后蒸去乙醚,再进行减压蒸馏,收集2-氯环己酮馏分。
- 急性毒性:腹腔-小鼠 LD50: 830 毫克/公斤
- MOL 文件:822-87-7.mol