Bromoacetonitrile 溴乙腈
CAS 590-17-0 MFCD00001884
信息真实价格透明
资金保障
专业采购外包团队在线服务
信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- Building Blocks, C1 to C5, Chemical Synthesis, Cyanides/Nitriles, Nitrogen Compounds, Organic Building Blocks
- {uni_hamburg} no charge; 1fragment
- {SNA} Building Blocks, C1 to C5, Chemical Synthesis, Cyanides/Nitriles, Nitrogen Compounds, Organic Building Blocks
产品应用
- 有机合成。
相关文献及参考
- Short: II/14a
- Phenols can be protected (K2CO3, acetone) as their cyanomethyl ethers which can be cleaved by hydrogenation of the nitrile: Tetrahedron Lett., 34, 7567 (1993).
- The Reformatsky-type reaction with cyclohexanone is more successful in the presence of a Zn/Ag couple than with the conventional Zn-Cu couple: Synth. Commun., 19, 2355 (1989). Good yields of ß-hydroxy nitriles have also been achieved from aldehydes and ketones using Zn and TMS chloride: Tetrahedron Lett., 31, 2205 (1990). The condensation with aldehydes can also be mediated by active Ni: Tetrahedron Lett., 26, 155 (1985). The reaction with aldehydes in the presence of Zn and tri-n-butylphosphine gives ɑß-unsaturated nitriles directly: Synth. Commun., 20, 3277 (1990).
- Short: II/24B
- Beilstein:2,216
安全信息
GHS Symbol
- H301 Toxic if swallowed 吞食有毒
- H301+H311+H331
- H311 Toxic in contact with skin 皮肤接触中毒
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H330 Fatal if inhaled 吸入致命
- H331 Toxic if inhaled 吸入中毒
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P301+P310
- P301+P310+P330
- P301+P330+P331
- P302+P352
- P302+P352+P312+P361+P364
- P303+P361+P353
- P304+P340
- P304+P340+P311
- P305+P351+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
- P320 Specific treatment is urgent (see … on this label). 紧急具体治疗(见本标签上的)。
- P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
- P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
- P330 Rinse mouth. 漱口
- P332+P313
- P337+P313
- P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36 Wear suitable protective clothing 穿戴适当的防护服;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 6 mg/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 341,289,1995
TYPE OF TEST : Unscheduled DNA synthesis ROUTE OF EXPOSURE : Oral TEST SYSTEM : Rodent - rat DOSE/DURATION : 19350 ug/kg REFERENCE : TOXID9 Toxicologist. (Soc. of Toxicology, Inc., 475 Wolf Ledge Parkway, Akron, OH 44311) V.1- 1981- Volume(issue)/page/year: 13,220,1993
TYPE OF TEST : Micronucleus test ROUTE OF EXPOSURE : Multiple routes TEST SYSTEM : Non-mammalian species DOSE/DURATION : 125 ug/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 341,289,1995
其他信息
- F:19
- 用途一:用于有机合成
- 储运特性:库房通风低温干燥
- 图谱信息:溴乙腈(590-17-0)质谱(MS) 溴乙腈(590-17-0)红外图谱(IR1)
- 方法一:乙腈与N-溴代琥珀酰亚胺反应而得。反应在溶剂加氯化碳中进行,在反应混合物中加入少量硫,回流反应14h。将反应物蒸馏,收集60-62℃(3.19kPa)馏分即得溴乙腈。
- MOL 文件:590-17-0.mol
- TCI Shanghai:溴乙腈 Bromoacetonitrile,>;97.0%(GC)(590-17-0)
- 用途二:有机合成中间体。
- Alfa Aesar:溴乙腈,96% Bromoacetonitrile, 96%(590-17-0)
- 可燃性危险特性:热分解排出有毒氮氧化物和溴化物蒸汽
- 灭火剂:水,泡沫,沙土,二氧化碳,干粉
- Acros Organics:溴乙腈 Bromoacetonitrile, 97%(590-17-0)
- 溴乙腈价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1058 溴乙腈 Bromoacetonitrile 25G 612元 2014/06/02 B1058 溴乙腈 Bromoacetonitrile 500G 5090元 2010/06/21 221860250 溴乙腈 Bromoacetonitrile 97% 25 GR 936元
- 类别:有毒物质
- 上游原料:N-溴代丁二酰亚胺
- 溶于乙醚,微溶于乙醇。有毒。有催泪性。
- Sigma Aldrich:590-17-0(sigmaaldrich)
- 下游产品:DL-氮杂环丁烷-2-羧酸 --> (S)-(-)-2-羧基环丁胺 --> 2-(丁-3-炔氧基)乙胺
- MSDS 信息:Bromoacetonitrile(590-17-0).msds