Fumaronitrile 反丁烯二腈
CAS 764-42-1 MFCD00001928
信息真实价格透明
资金保障
专业采购外包团队在线服务
信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- Building Blocks, C1 to C5, Chemical Synthesis, Cyanides/Nitriles, Nitrogen Compounds, Organic Building Blocks
- {SNA} Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Building Blocks, C1 to C5, Chemical Synthesis, Cyanides/Nitriles, F, FM - FZ, Nitrogen Compounds, Organic Building Blocks
- {uni_hamburg} no charge; 1fragment
- {SNA} Alphabetic, Analytical Standards, Analytical/Chromatography, Building Blocks, C1 to C5, Chemical Synthesis, Cyanides/Nitriles, F, FM -
相关文献及参考
- Beil. 2 ,IV,2219
- Aldrich MSDS 1 , 981:B / Corp MSDS 1 (1), 1750:A / FT-IR 1 (1), 844:A / FT-IR 2 (1), 1432:A / FT-NMR 1 (1), 1360:B / IR-Spectra (3), 504:C / NMR-Reference 2 (1), 702:B / RegBook 1 (1), 993:A / Sax 6 , 1460 / Sigma FT-IR 1 (2), 586:B / Structure Index 1 , 154:D:9 / Vapor Phase 3 , 803:D
- Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
- Short: IV/20C Title: Vapor Pressure and Antoine Coefficients for Nitrogen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20C Year: 2001 Keyword: organic compounds; vapor pressure ISBN: 3-540-41060-0 ISBN: 978-3-540-41060-7 Internet Resource: DOI:10.1007/b88812 RefComment: VII, 197 pages
- Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
安全信息
GHS Symbol
- H301+H311+H331
- H301+H331
- H331 Toxic if inhaled 吸入中毒
- H301 Toxic if swallowed 吞食有毒
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P310+P330
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
- P332+P313
- P302+P352+P312+P361+P364
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P405 Store locked up. 上锁保管。
- P305+P351+P338+P337+P313
- P304+P340+P311
- P305+
- P403+P233
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S36 Wear suitable protective clothing 穿戴适当的防护服;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 38 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : ZAARAM Zentralblatt fuer Arbeitsmedizin und Arbeitsschutz. (Darmstadt, Fed. Rep. Ger.) V.1-25, 1951-75. Volume(issue)/page/year: 19,225,1969
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 132 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : TOLED5 Toxicology Letters. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1977- Volume(issue)/page/year: 12,157,1982
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 56 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#05718
TYPE OF TEST : Sex chromosome loss and nondisjunction TEST SYSTEM : Yeast - Saccharomyces cerevisiae DOSE/DURATION : 17 mg/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 241,255,1990
其他信息
- 上游原料:马来酸酐 --> 马来酸 --> 富马酸 --> 富马酰胺
- 用途一:用于有机合成。
- MOL 文件:764-42-1.mol
- Alfa Aesar:富马酸腈,98+% Fumaronitrile, 98+%(764-42-1)
- 图谱信息:反丁烯二腈 (764-42-1)红外图谱(IR1) 反丁烯二腈 (764-42-1)核磁图( 1 HNMR) 反丁烯二腈 (764-42-1)Raman光谱 反丁烯二腈 (764-42-1)核磁图( 13 CNMR) 反丁烯二腈 (764-42-1)质谱(MS) 反丁烯二腈 (764-42-1)红外图谱(IR2)
- TCI Shanghai:反丁烯二腈 Fumaronitrile,>;98.0%(GC)(764-42-1)
- 方法一:由反丁烯二酸制得,反丁烯二酸的化学性质与顺丁烯二酸相似,反丁烯二酸加热至250-300℃转变顺丁烯二酸酐,反丁烯二酸也能生成一元及二元酯或酰胺,但不能生成一元酰氯而可生成二元酰氯。反丁烯二酸酯化生成反丁烯二酸二乙酯,再经酰胺化,脱水即得反丁烯二腈。1.酰胺化将反丁烯二酸二乙酯冷至0℃,搅拌下慢慢加入氨水,加完后再搅拌4h,过滤,用少量水洗一次,晾干,得反丁烯酰胺[627-64-5]。2.脱水将上述反丁烯酰胺与五氧化二磷混匀后,加热,减压蒸馏至无馏出物为止,得反丁烯二腈粗品。将粗品溶于苯中,摇动下倒入石油醚中,过滤,凉干即得成品。
- Acros Organics:富马二腈/丁烯二腈 Fumaronitrile, 98%(764-42-1)
- Sigma Aldrich:764-42-1(sigmaaldrich)