Methyldiphenylphosphine oxide 甲基二苯基氧化膦

CAS 2129-89-7 MFCD00002081

化学结构图

2129-89-7
SMILES: CP(=O)(c1ccccc1)c1ccccc1

化学属性

Mol. FormulaC13H13OP
Mol. Weight216.22
Melting Point111-115°C
TSCANo
Boiling Point180 °C at 1 mmHg

别名和识别编码

Chemical NameMethyldiphenylphosphine oxide
Synonym Methyldiphenylphosphine oxide {LY} Methyldiphenylphosphine oxide {} {LY} Methyldiphenylphosphine oxide {} {} {LY} Methyldiphenylphosphine oxide {} {} {} {LY} Methyldiphenylphosphine oxide {} {} {} {} {LY} Methyldiphenylphosphine oxide {} {} {} {} {} {LY} Methyldiphenylphosphine oxide {} {} {} {} {} {} {LY} Methyldiphenylphosphine oxide {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine oxide {} {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine oxide {} {} {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine oxide {} {} {} {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine oxide {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00002081
CAS Number2129-89-7
PubChem Substance ID75041
EC Number218-346-8
Beilstein Registry Number957291
Reaxys-RN957291
Chemical Name Translation甲基二苯基氧化膦
InChIKeyPEGCITODQASXKH-UHFFFAOYSA-N
InChIInChI=1S/C13H13OP/c1-15(14,12-8-4-2-5-9-12)13-10-6-3-7-11-13/h2-11H,1H3
LabNetwork Molecule IDLN00198535
Canonical SMILESCP(C1=CC=CC=C1)(C2=CC=CC=C2)=O
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

相关文献及参考

  • Short: EINECS
  • Short: III/35D2
  • The lithiated derivative undergoes Horner olefination reactions with carbonyl compounds to give, after dehydration, vinyl or allyl phosphine oxides: Synthesis, 64 (1988). The reaction has been use in a useful synthesis of (3Z,6E)-ɑ-farnesene: J. Org. Chem., 60, 6211 (1995); for reaction scheme see Geranyl­ bromide, A14093. Epoxides give -hydroxy propylphosphine oxides: J. Chem. Soc., Perkin 1, 2971 (1988); see also: J. Chem. Soc., Perkin 1, 1963 (1999).

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P312+P330
  • P301+P317
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337 If eye irritation persists: 如果眼睛刺激持续
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
RTECSSZ0199480
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Codes Xn
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 840 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   KHFZAN Khimiko-Farmatsevticheskii Zhurnal.  Chemical Pharmaceutical Journal.
    For English translation, see PCJOAU.  (V/O Mezhdunarodnaya Kniga, 113095
   Moscow, USSR)  V.1-    1967-  Volume(issue)/page/year: 24(4),22,1990

其他信息

  • MOL 文件:2129-89-7.mol
  • Sigma Aldrich:2129-89-7(sigmaaldrich)
  • Alfa Aesar:甲基二苯基氧膦,98+% Methyldiphenylphosphine oxide, 98+%(2129-89-7)
  • TCI Shanghai:甲基二苯基氧化膦 Methyl(diphenyl)phosphine Oxide,>;98.0%(GC)(2129-89-7)
  • 图谱信息:甲基二苯基氧化膦(2129-89-7)核磁图( 1 HNMR) 甲基二苯基氧化膦(2129-89-7)质谱(MS) 甲基二苯基氧化膦(2129-89-7)红外图谱(IR2) 甲基二苯基氧化膦(2129-89-7)核磁图( 13 CNMR) 甲基二苯基氧化膦(2129-89-7)红外图谱(IR1)
  • 敏感性:Moisture Sensitive
  • 甲基二苯基氧化膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 D2445 甲基(二苯基)氧化膦 Methyl(diphenyl)phosphine Oxide 10G 691元 2010/05/25 A11484 甲基二苯基氧膦, 98+% Methyldiphenylphosphine oxide, 98+% 5g 288元 2010/05/25 A11484 甲基二苯基氧膦, 98+% Methyldiphenylphosphine oxide, 98+% 25g 1064元
  • 甲基二苯基氧化膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D2445 甲基(二苯基)氧化膦 Methyl(diphenyl)phosphine Oxide 10G 636元 2010/05/25 A11484 甲基二苯基氧膦, 98+% Methyldiphenylphosphine oxide, 98+% 5g 288元 2010/05/25 A11484 甲基二苯基氧膦, 98+% Methyldiphenylphosphine oxide, 98+% 25g 1064元

系列性分类