Ethyl cyanoglyoxylate-2-oxime 2-肟氰乙酸乙酯

CAS 3849-21-6 MFCD00002112

化学结构图

3849-21-6
SMILES: CCOC(=O)C(C#N)=NO

化学属性

Mol. FormulaC5H6N2O3
Mol. Weight142.11
Melting Point130-132°C
Boiling Point248.9°C at 760 mmHg

别名和识别编码

Chemical NameEthyl 2-cyano-2-(hydroxyimino)acetate
Synonym Ethyl 2-cyano-2-(hydroxyimino)acetate {LY} Ethyl 2-cyano-2-(hydroxyimino)acetate {} {LY} Ethyl 2-cyano-2-(hydroxyimino)acetate {} {} {LY} Ethyl 2-cyano-2-(hydroxyimino)acetate {} {} {} {LY} Ethyl 2-cyano-2-(hydroxyimino)acetate {} {} {} {} {LY} Ethyl 2-cyano-2-(hydroxyimino)acetate {} {} {} {} {} {LY} Ethyl 2-cyano-2-(hydroxyimino)acetate {} {} {} {} {} {} {LY} Ethyl 2-cyano-2-(hydroxyimino)acetate {} {} {} {} {} {} {} {LY} Ethyl 2-cyano-2-(hydroxyimino)acetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl 2-cyano-2-(hydroxyimino)acetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl 2-cyano-2-(hydroxyimino)acetate {} {} {} {} {} {} {} {} {} {} {LY} Ethyl 2-cyano-2-(hydroxyimino)acetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl 2-cyano-2-(hydroxyimino)acetate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl 2-cyano-2-(hydroxyimino)acetate
Beilstein Registry Number774783
PubChem Substance ID6400537
CAS Number3849-21-6
EC Number223-351-3
MDL NumberMFCD00002112
Reaxys-RN774783
Alfabeta NameETHYLCYANOHYDROXYIMINOACETATE E2(())-
Chemical Name Translation2-肟氰乙酸乙酯
InChIKeyLCFXLZAXGXOXAP-QPJJXVBHSA-N
LabNetwork Molecule IDLN00182333
InChIInChI=1S/C5H6N2O3/c1-2-10-5(8)4(3-6)7-9/h9H,2H2,1H3/b7-4+
Canonical SMILESO=C(OCC)/C(C#N)=N/O
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分类

  • Active Esters/Additives, Building Blocks, Chemical Biology, Chemical Synthesis, Coupling, Nitrogen Compounds, Organic Building Blocks, Oximes, Peptide Chemistry, Peptide Coupling, Synthetic Reagents
  • {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Oximes

相关文献及参考

  • Beil. 3 ,IV,1805
  • Corp MSDS 1 (1), 1592:C / FT-IR 2 (3), 4005:B / FT-IR 1 (2), 922:C / NMR-Reference 2 (2), 968:B / RegBook 1 (2), 2687:I / Structure Index 1 , 423:B:3

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H302+H312+H332
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P312+P330
  • P301+P317
  • P302+P352
  • P302+P352+P312+P362+P364
  • P304+P312
  • P304+P340
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard Codes Xn Xn,Xi
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Warnings IRRITANT
Packing GroupIII
Hazard Class6.1
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
UN Number 3276
GHS Symbol

其他信息

  • MOL 文件:3849-21-6.mol
  • Acros Organics:氰基乙醛酸乙酯-2-肟 Ethyl cyanoglyoxylate-2-oxime, 97%(3849-21-6)
  • Hazard Note:Irritant
  • Sigma Aldrich:3849-21-6(sigmaaldrich)
  • 用途一:敏喘宁的中间体。
  • 2-肟氰乙酸乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 A12691 2-肟氰乙酸乙酯, 97% Ethyl isonitrosocyanoacetate, 97% 5g 378元 2010/05/25 A12691 2-肟氰乙酸乙酯, 97% Ethyl isonitrosocyanoacetate, 97% 25g 1085元 2010/05/25 A12691 2-肟氰乙酸乙酯, 97% Ethyl isonitrosocyanoacetate, 97% 100g 3388元
  • F:10
  • MSDS 信息:Ethyl cyanoglyoxylate-2-oxime(3849-21-6).msds
  • Alfa Aesar:2-肟氰乙酸乙酯,97% Ethyl isonitrosocyanoacetate, 97%(3849-21-6)

系列性分类


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