2-Bromophenol 2-溴苯酚

CAS 95-56-7 MFCD00002146

化学结构图

95-56-7
SMILES: Oc1ccccc1Br

化学属性

Mol. FormulaC6H5BrO
Mol. Weight173.01
Refractive index1.5840 to 1.5920
Boiling Point195
Density1.492
Melting Point3-7
Flash Point42.22°C
TSCAYes
Solubility可溶
Stability对空气敏感

别名和识别编码

Chemical Name2-Bromophenol
CAS Number95-56-7
PubChem Substance ID7244
EC Number202-432-7
Beilstein Registry Number1905115
MDL NumberMFCD00002146
Reaxys-RN1905115
Merck Number1428
Synonym 2-Bromophenol {LY} 2-Bromophenol 2-Bromophenol, 98+% 2-Bromphenol 2-Hydroxybrombenzol 2-bromo-pheno 2-bromo-phenol 2-溴苯酚 2-溴苯酚,98+% 2-溴苯酚; 邻溴苯酚 2-溴酚 2-溴酚;邻溴苯酚;邻溴酚 o-Bromophenol o-Bromphenol ortho-bromophenol O-BROMOPHENOL ORTHO-BROMOPHENOL Phenol, 2-bromo- Phenol, o-bromo- Phenol, o-bromo- o-BROMO PHENOL (2-BROMO PHENOL) o-Bromophenol o-bromo-pheno o-bromophenic acid o-bromophenol (2 isomer) {} {LY} 2-Bromophenol {} {} {LY} 2-Bromophenol {} {} {} {LY} 2-Bromophenol {} {} {} {} {LY} 2-Bromophenol {} {} {} {} {} {LY} 2-Bromophenol {} {} {} {} {} {} {LY} 2-Bromophenol {} {} {} {} {} {} {} {LY} 2-Bromophenol {} {} {} {} {} {
Alfabeta NameBROMOPHENOL 2-
Chemical Name Translation2-溴苯酚
Wiswesser Line NotationQR BE
LabNetwork Molecule IDLN00182018
InChIInChI=1S/C6H5BrO/c7-5-3-1-2-4-6(5)8/h1-4,8H
Canonical SMILESOC1=CC=CC=C1Br
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分类

  • {SNA} B, Building Blocks, C6 to C8, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols, 生物活性小分子, 细胞生物学
  • {SNA} Building Blocks, C6 to C8, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols
  • {SNA} B, Bioactive Small Molecule Alphabetical Index, Building Blocks, C6 to C8, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols, 生物活性小分子, 细胞生物学
  • {SNA} Analytical Standards, Organic Pollutant Standards,

产品应用

  • Usually used in the preparation of anti-benzofurobenzofuran diimides. And also used to study the photodegradation of 2-bromophenol using UV-Vis spectroscopy and HPLC.

相关文献及参考

  • Merck: 14,1428
  • Short: II/27B
  • Reacts with n-BuLi to give a dilithio derivative, which reacts with electrophiles at carbon in a useful synthesis of ortho-substituted phenols: J. Org. Chem., 49, 5267 (1984).
  • Merck: 14,1428 Beilstein:6,197

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H302 Harmful if swallowed 吞食有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 3 Xn,F,Xi
RTECSSJ7875000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P211 Do not spray on an open flame or other ignition source.? 不要喷洒在明火或其他点火源。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P312+P330
  • P302+P352+P332+P313+P362+P364
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S29 Do not empty into drains 不要排入下水道;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Risk Statements
  • R10 Flammable 易燃
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R50 Very toxic to aquatic organisms 对水生生物极毒
UN Number 1993 2929 UN3082
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Packing GroupIII
Warnings 危化品目录(2015) IRRITANT
Hazard Class6.1/3
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 652 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 44(12),19,1979

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 1500 mg/kg
TOXIC EFFECTS :
   Behavioral - tremor
   Behavioral - convulsions or effect on seizure threshold
   Behavioral - muscle weakness
REFERENCE :
   RMSRA6 Revue Medicale de la Suisse Romande.  (Societe Medicale de La Suisse
   Romande, 2 rue Bellefontaine, 1003 Lausanne, Switzerland)  V.1-    1881-
   Volume(issue)/page/year: 16,449,1896

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 1 gm/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 1 gm/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 3

Restrict 危险品

其他信息

  • MSDS 信息:2-溴苯酚(95-56-7).msds
  • 毒性分级:中毒
  • Hazard Note:Irritant
  • 2-溴苯酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0630 2-溴苯酚 2-Bromophenol 500G 1960元 2014/06/02 B0630 2-溴苯酚 2-Bromophenol 25G 180元 2010/06/21 157360100 2-溴苯酚 2-Bromophenol 98% 10 ML 881元
  • 检测方法:GC,NMR
  • 类别:有毒物品
  • 职业标准:STEL 0.3 毫克/ 立方米
  • 储运特性:库房通风低温干燥; 与氧化剂、食品添加剂分开存放
  • 溶于水。和氯仿和醚混溶
  • 下游产品:2-异丙氧基苯硼酸 --> 2,3-二氢苯并呋喃-5-甲醛 --> 2-苄氧基苯硼酸
  • 急性毒性:口服- 小鼠 LD50: 652 毫克/ 公斤; 腹腔-小鼠 LD50: 633 毫克/公斤
  • TCI Shanghai:2-溴苯酚 2-Bromophenol,>;98.0%(GC)(T)(95-56-7)
  • Alfa Aesar:2-溴苯酚,98+% 2-Bromophenol, 98%(95-56-7)
  • F:8-10-23
  • 用途一:用于有机合成
  • Sigma Aldrich:95-56-7(sigmaaldrich)
  • 外观性质:黄色到红色油状液体,具有不愉快的气味。
  • 灭火剂:雾状水、泡沫、二氧化碳、砂土
  • MOL 文件:95-56-7.mol
  • Acros Organics:2-溴苯酚 2-Bromophenol, 98%(95-56-7)
  • 可燃性危险特性:明火可燃; 高热放出有毒溴化物气体
  • 图谱信息:2-溴苯酚(95-56-7)核磁图( 13 CNMR) 2-溴苯酚(95-56-7)红外图谱(IR1) 2-溴苯酚(95-56-7)质谱(MS)

系列性分类


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