4-Chloro-3-Methylphenol 4-氯-3-甲基苯酚
CAS 59-50-7 MFCD00002323
信息真实价格透明
资金保障
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信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- {SNA} 2000/60/EC, Alphabetical Index of Analytical Standards, Method and Regulation Specific, Alpha Sort, Analytical Standards, Analytical/Chromatography, C, CH, Chromatography, Environmental Standards, European Community: ISO, DIN and DL 152, Volatiles/ Semivolatiles
- {SNA} Building Blocks,
产品应用
- 用于有机合成,如染料、影片防腐剂等。
相关文献及参考
- Merck:14,2133 Beilstein: 6,IV,2064
- Short: III/35D2
- Short: III/20b
- Merck:14,2133
安全信息
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
- S7 Keep container tightly closed 保存在严格密闭容器中;
- R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
- R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
- R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
- R50 Very toxic to aquatic organisms 对水生生物极毒
GHS Symbol
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- H302+H312
- H318 Causes serious eye damage 严重伤害眼睛
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
- H302 Harmful if swallowed 吞食有害
- H312 Harmful in contact with skin 皮肤接触有害
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312+P330
- P301+P330+P331+P310
- P302+P350
- P305+P351+P338
- P305+P351+P338+P310
- P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 600 mg/kg TOXIC EFFECTS : Behavioral - somnolence (general depressed activity) REFERENCE : SRTCAC Science Reports of the Research Institutes, Tohoku University, Series C: Medicine. (Tohoku University, Research Institute for Tuberculosis and Cancer, 4-1 Seiryo-machi, Sendai, Japan) V.1- 1949- Volume(issue)/page/year: 36(1-4),10,1989
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Subcutaneous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 360 mg/kg TOXIC EFFECTS : Behavioral - general anesthetic Behavioral - tremor Lungs, Thorax, or Respiration - other changes REFERENCE : QJPPAL Quarterly Journal of Pharmacy & Pharmacology. (London, UK) V.2-21, 1929-48. For publisher information, see JPPMAB. Volume(issue)/page/year: 12,212,1939
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 1830 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : SchP## Personal Communication from P. Schmitz, Bayer AG, 5090 Leverkusen, Bayerwerk, Fed. Rep. Ger., April 4, 1986 Volume(issue)/page/year: 04APR1986
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Subcutaneous SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 400 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : QJPPAL Quarterly Journal of Pharmacy & Pharmacology. (London, UK) V.2-21, 1929-48. For publisher information, see JPPMAB. Volume(issue)/page/year: 12,212,1939
TYPE OF TEST :
TYPE OF TEST : Mutation test systems - not otherwise specified TEST SYSTEM : Bacteria - Escherichia coli DOSE/DURATION : 100 umol/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 307,141,1994
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 25 ug/plate REFERENCE : TECSDY Toxicological and Environmental Chemistry. (Gordon & Breach Science Pub. Inc., 1 Park Ave., New York, NY 10016) V.3(3/4)- 1981- Volume(issue)/page/year: 14,143,1987
其他信息
- 酚类单一化合物标准液
- Acros Organics:4-氯-3-甲基苯酚 4-Chloro-3-methylphenol, 99+%(59-50-7)
- Sigma Aldrich:59-50-7(sigmaaldrich)
- MSDS 信息:4-氯-3-甲酚(59-50-7).msds
- 20℃时1g能溶于250ml水,在热水中溶解更多,易溶于苯、乙醚、乙醇、丙酮、氯仿和石油醚。能随水蒸气挥发。
- 毒性分级:中毒
- Alfa Aesar:4-氯-3-甲基苯酚,99% 4-Chloro-3-methylphenol, 99%(59-50-7)
- 急性毒性:口服-大鼠 LD50: 1830 毫克/公斤; 口服-小鼠 LD50: 600 毫克/公斤
- 上游原料:磺酰氯 --> 间甲酚 --> 干燥剂
- 用途一:用于有机合成,如染料、影片防腐剂等。
- 储运特性:库房通风低温干燥; 与氢氧化钠分开储运
- 图谱信息:4-氯-3-甲酚(59-50-7)红外图谱(IR1)
- 外观性质:无色结晶,带有苯酚气味。
- 可燃性危险特性:受热放出有毒氯化物, 光气烟雾
- 灭火剂:二氧化碳、砂土、泡沫、干粉
- 海关编码:29081000
- TCI Shanghai:间甲基对氯苯酚(区域精制法精制,熔段数:26) 4-Chloro-m-cresol Zone Refined (number of passes:26)(59-50-7)
- MOL 文件:59-50-7.mol
- 4-氯-3-甲酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw090001 棕榈酸异丙酯 25ml 120元 2011/08/23 xw090004 棕榈酸异丙酯 100ml 150元 2011/04/16 C0628 4-氯间甲酚l(区域精制法精制,熔段数:26) 4-Chloro-m-cresol Zone Refined (number of passes:26) 1SAMPLE 966元
- 方法一:由间甲酚与二氯硫酰反应。在搅拌下,将间甲酚慢慢加入二氯硫酰,反应温度控制在30-50℃。加完后保温16h,用水洗,用碳酸钠溶液洗至碱性,再用热水洗至中性。分出油层用无水氯化钙干燥,滤去干燥剂后减压蒸馏,将蒸馏液倒入石油醚中,冷却,过滤,干燥得成品。
- 类别:有毒物品