2-Bromobenzoic Acid 2-溴苯甲酸
CAS 88-65-3 MFCD00002402
信息真实价格透明
资金保障
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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分类
- {SNA} Building Blocks, C7, Carbonyl Compounds, Carboxylic Acids, Chemical Synthesis, Organic Building Blocks
- {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; carboxylic acid; 1fragment
产品应用
- 有机合成。
相关文献及参考
- Short: II/27B
- Beilstein:9,347
- Forms a dimetallated derivative with n-BuLi, which reacts with electrophiles preferentially at the ortho-carbon: J. Org. Chem., 39, 2051, 2053 (1974); e.g. with aroyl halides leads to 2-carboxybenzophenones which can be cyclized by acid to substituted anthraquinones: J. Org. Chem., 46, 1057 (1981).
- Short: II/27C
- The Br can be displaced by malonate-type carbanions, in the presence of Cu catalysts: Angew. Chem. Int. Ed., 13, 340 (1974). For coupling with Na 2,4-pentanedionate, see: Org. Synth. Coll., 6, 36 (1988).
安全信息
GHS Symbol
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
- S36 Wear suitable protective clothing 穿戴适当的防护服;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
- S37 Wear suitable gloves 戴适当手套;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R36 Irritating to eyes 刺激眼睛
- R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352+P332+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- H302 Harmful if swallowed 吞食有害
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
TYPE OF TEST : LD - Lethal dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : >500 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : NCNSA6 National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. (Washington, DC) Volume(issue)/page/year: 5,7,1953
其他信息
- 毒性分级:中毒
- 溶于乙醇、乙醚、丙酮、氯仿和热水,微溶于冷水。沸点升华。
- 上游原料:氧 --> 2-溴甲苯
- MSDS 信息:2-Bromobenzoic acid(88-65-3).msds
- 2-溴苯甲酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010238 邻溴苯甲酸 100g 360元 2011/04/16 B0552 2-溴苯甲酸 2-Bromobenzoic Acid 500G 2630元 2011/04/16 B0552 2-溴苯甲酸 2-Bromobenzoic Acid 25G 312元
- Sigma Aldrich:88-65-3(sigmaaldrich)
- Hazard Note:Irritant
- 检测方法:GC,NMR
- 可燃性危险特性:热分解排出有毒溴化物气体
- 储运特性:库房通风,低温,干燥
- MOL 文件:88-65-3.mol
- TCI Shanghai:2-溴苯甲酸 2-Bromobenzoic Acid,>;98.0%(GC)(T)(88-65-3)
- 图谱信息:2-溴苯甲酸(88-65-3)红外图谱(IR1) 2-溴苯甲酸(88-65-3)红外图谱(IR2) 2-溴苯甲酸(88-65-3)核磁图( 13 CNMR) 2-溴苯甲酸(88-65-3)核磁图( 1 HNMR) 2-溴苯甲酸(88-65-3)质谱(MS)
- Acros Organics:2-溴苯甲酸 2-Bromobenzoic acid, 97%(88-65-3)
- 海关编码:29163900
- 类别:有毒物质
- 蒸气压:>;1 mm Hg ( 20 °C)
- 灭火剂:水, 沙土, 二氧化碳, 干粉和泡沫
- 急性毒性:口服-大鼠 LD: >; 500 毫克/公斤
- 用途一:用于有机合成
- 下游产品:2-溴-5-硝基苯甲酸 --> 4-氯-2-苯基喹唑啉 --> 2-苯基-4-[3H]喹唑啉酮
- Alfa Aesar:2-溴苯甲酸,98% 2-Bromobenzoic acid, 98%(88-65-3)