2-Iodobenzoic Acid 邻碘苯甲酸
CAS 88-67-5 MFCD00002419
信息真实价格透明
资金保障
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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分类
- {SNA} Building Blocks, C7, Carbonyl Compounds, Carboxylic Acids, Chemical Synthesis, Organic Building Blocks
- Aromatics
- {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; carboxylic acid; 1fragment
产品应用
- 用于有机合成或用作分析试剂。
相关文献及参考
- Merck: 14,5030 Beilstein:9,363
- For related reactions, see 4,4-Dimethyl-2-pentyne, L10210, 2-Iodoaniline, A13059 and 2-Iodophenol, A13599.
- Merck: 14,5030
- Short: III/20c
- In the presence of Tetrakis(triphenylphosphine)palladium(0), 10548, and zinc chloride, undergoes cyclization with terminal acetylenes to give isocoumarins: J. Org. Chem., 60, 3711 (1995):
- Short: EINECS
- Short: III/5a
- Short: IV/8A
- Can be used to protect alcohols as their 2-iodobenzoates by DCC coupling. The group is removed by oxidation with chlorine under basic conditions: Tetrahedron Lett., 28, 5005 (1987).
安全信息
GHS Symbol
- S22 Do not breathe dust 不要吸入粉尘;
- S39 Wear eye/face protection 戴眼睛/面孔保护装置;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
- R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
- R22 Harmful if swallowed 吞咽有害
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P332+P313
- P301+P312+P330
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P302+P350
- P337+P313
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- H315 Causes skin irritation 会刺激皮肤
- H318 Causes serious eye damage 严重伤害眼睛
- H302 Harmful if swallowed 吞食有害
- H335 May cause respiratory irritation 可能导致呼吸道刺激
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 1500 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : PHARAT Pharmazie. (VEB Verlag Volk und Gesundheit, Neue Gruenstr. 18, Berlin DDR-1020, Ger. Dem. Rep.) V.1- 1946- Volume(issue)/page/year: 12,415,1957
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 200 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD277-689
其他信息
- 海关编码:29163900
- 图谱信息:2-碘苯甲酸(88-67-5)红外图谱(IR1) 2-碘苯甲酸(88-67-5)红外图谱(IR2) 2-碘苯甲酸(88-67-5)核磁图( 13 CNMR) 2-碘苯甲酸(88-67-5)质谱(MS)
- 用途二:用于有机合成或用作分析试剂。
- 方法一:由邻氨基苯甲酸经重氮化、置换而得。将邻氨基苯甲酸在硫酸存在下用亚硝酸钠重氮化,控制温度在10℃以下,重氮液过滤后,加入碘化钾与硫酸的混合液,加毕搅拌10min,煮沸。过滤,以硫代硫酸钠溶液洗涤,再用水重结晶即得成品。
- 用途一:用于有机合成或用作分析试剂。
- TSCA:T
- 检测方法:HPLC,NMR,T
- MSDS 信息:2-Iodobenzoic acid(88-67-5).msds
- 上游原料:邻氨基苯甲酸
- Acros Organics:2-碘苯甲酸 2-Iodobenzoic acid, 98%(88-67-5)
- Hazard Note:Irritant
- 存储注意事项:氮气保护
- 2-碘苯甲酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010286 邻碘苯甲酸 100g 350元 2011/04/16 I0053 2-碘苯甲酸 2-Iodobenzoic Acid 500G 2690元 2011/04/16 I0053 2-碘苯甲酸 2-Iodobenzoic Acid 25G 297元
- TCI Shanghai:2-碘苯甲酸 2-Iodobenzoic Acid,>;98.0%(GC)(T)(88-67-5)
- 溶于醇和醚,难溶于水。
- Alfa Aesar:2-碘苯甲酸,98+% 2-Iodobenzoic acid, 98+%(88-67-5)
- 下游产品:氟灭酸 --> 2-乙氧羰基苯硼酸频哪醇酯 --> 2-碘酰基苯甲酸 --> 戴斯-马丁氧化剂 --> 2-碘马尿酸 --> 邻碘苯甲酰氯
- Sigma Aldrich:88-67-5(sigmaaldrich)
- MOL 文件:88-67-5.mol
- 敏感性:Light Sensitive