4-Chloromercuribenzoic acid 对氯汞苯甲酸
CAS 59-85-8 MFCD00002526
化学结构图
SMILES: O=C(O)c1ccc([Hg]Cl)cc1
化学属性
| Mol. Formula | C7H4ClHgO2.H |
|---|---|
| Mol. Weight | 357.16 |
| Melting Point | ca 287° dec. |
| TSCA | Yes |
| Solubility | 不溶于水，溶于乙醇。 |
别名和识别编码
| Chemical Name | 4-Chloromercuribenzoic Acid |
|---|---|
| CAS Number | 59-85-8 |
| Synonym | 4-carboxyphenylmercuricchloride PCMB usafd-3 4-CHLOROMERCURIBENZOIC ACID P-CMBA p-chloro-mercuricbenzoicacid Mercurate(1-), (4-carboxylatophenyl)chloro-, hydrogen P-(CHLOROMERCURIO)BENZOIC ACID p-Chloro-mercuric benzoic acid 对氯化汞苯甲酸 4-氯苯甲酸汞 (p-carboxyphenyl)chloro-mercur 4-Carboxyphenylmercuric chloride 对氯高汞苯甲酸 Benzoic acid, p-(chloromercuri)- 4-(HYDROXYMERCURIO)BENZOIC ACID p-carboxyphenylmercuricchloride p-(chloromercuri)-benzoicaci 4-氯汞苯甲酸 4-(CHLOROMERCURIO)BENZOIC ACID 4-Carboxyphenylmercuric Chloride P-CHLOROMERCURIBENZOIC ACID (p-Carboxyphenyl)chloromercury 对氯汞苯甲酸 P-CHLOROMERCURIBENZOIC ACID, FREE ACID (4-carboxyphenyl)chloromercury 4-(Chloromercuric)benzoic acid (4-carboxylatophenyl)chloro-mercurate(1-hydrogen NSC 32866 (4-Carboxyphenyl)chloromercury 4-(CHLOROMERCURI)BENZOIC ACID 95% (& P-CMB 4-(HYDROXYMERCURI)BENZOIC ACID USAF D-3 p-Chloromercuribenzoic acid p-Carboxyphenylmercuric chloride |
| Beilstein Registry Number | 3662892 |
| PubChem Substance ID | 24278323 |
| EC Number | 200-442-6 |
| MDL Number | MFCD00002526 |
| Chemical Name Translation | 对氯汞苯甲酸 |
| Wiswesser Line Notation | QVR D-HG-G |
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分类
- A to C, Alcohol oxidase, Aldehyde dehydrogenase, Amino acid oxidase, D-, Apoptosis Enzymes, Application Index, Asparaginase, Biochemicals and Reagents, Calpain, Calpain II, Calpain II Inhibitors, Carboxypeptidase P, Cell Signaling Enzymes, Chemical Synthesis, Clostripain, Creatine Phosphokinase, D to K, Dihydrofolate reductase, Enzyme Inhibitors, Enzyme Inhibitors by Enzyme, Enzymes, Inhibitors, and Substrates, Folic Acid Metabolism, General Inhibitors, Glucosidase, beta-, Glycobiology,
- {SNA} A to C,
产品应用
- A useful sulfhydryl reagent that reacts with Histidine 225C, a residue of the NhaA-Na/H Antiporter of Escherichia Coli.
相关文献及参考
- Olami, Y. et al.: J. Biol. Chem., 272, 3, 1761 (1997).
- Kanauchi, M., et al., Purification and characteristics of feruloyl esterase from Aspergillus awamori G-2 strain. J. Food Sci. 73 , 458-63, (2008) 摘要
- Shpakov A.O., and Derkach, K.V., The role of sulfhydryl groups in functioning of components of adenylate cyclase signal system in smooth muscles of the mollusk Anodonta cygnea (effect of N-ethylmaleimide and p-chloromercuribenzoic acid) Tsitologia 41 , 499-505, (1999)
- Beil. 16 ,IV,1750
- Aldrich MSDS 1 , 411:C / Corp MSDS 1 (1), 794:C / FT-IR 1 (2), 1149:C / FT-IR 2 (3), 4509:A / IR-Spectra (2), 1335:E / IR-Spectra (3), 1562:H / NMR-Reference 2 (2), 982:C / RegBook 1 (2), 3071:C / Sax 6 , 729 / Sigma FT-IR 1 (2), 381:A / Structure Index 1 , 487:D:3
安全信息
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P273 Avoid release to the environment. 避免释放到环境中。
- P301+P310
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
GHS Symbol
- H330 Fatal if inhaled 吸入致命
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H310 Fatal in contact with skin 皮肤接触致命
- H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
- H300 Fatal if swallowed 吞食致命
- S13 Keep away from food, drink and animal foodstuffs 远离食品、饮料和动物饲料保存；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S27/28
- R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有剧毒
- R50/53
- R33 Danger of cumulative effects 有累积作用的危险
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 25 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD277-689
其他信息
- 职业标准:TWA 0.05 毫克 (汞)/ 立方米; STEL 0.15 毫克 (汞)/ 立方米
- 毒性分级:剧毒
- 储运特性:库房通风低温干燥; 与食品原料分开储运
- 灭火剂:二氧化碳、砂土、水、泡沫
- 图谱信息:对氯汞苯甲酸(59-85-8)红外图谱(IR2) 对氯汞苯甲酸(59-85-8)质谱(MS) 对氯汞苯甲酸(59-85-8)核磁图( 1 HNMR) 对氯汞苯甲酸(59-85-8)红外图谱(IR1)
- 对氯汞苯甲酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80034180 对氯汞苯甲酸 5g 136元
- 可燃性危险特性:高热分解有毒汞化物和氯化物气体
- MOL 文件:59-85-8.mol
- F:3-8-10
- Sigma Aldrich:59-85-8(sigmaaldrich)
- 急性毒性:腹腔-小鼠 LD50: 25 毫克/公斤
- 外观性质:白色结晶粉末。
- MSDS 信息:对氯化汞苯甲酸(59-85-8).msds
- 类别:有毒物品
