CAS 139-66-2 MFCD00003064-Diphenyl sulfide 二苯硫醚 TAO{mole}

Diphenyl sulfide 二苯硫醚

CAS 139-66-2 MFCD00003064

化学结构图

SMILES: C1CCC(SC2CCCCC2)CC1

化学属性

Mol. Formula	C12H10S
Mol. Weight	186.27
Density	1.113
Refractive index	1.6310 to 1.6360
Boiling Point	296 °C at 760 mmHg
Melting Point	-40 °C
Flash Point	126°C(lit.)
TSCA	Yes
Solubility	不溶
Appearance	无色液体。熔点约40℃，沸点295-297℃，相对密度（15/15℃）1.1185，折光率（nD18）1.6350。能与苯、醚、二硫化碳混碳，溶于热醇，不溶于水。

别名和识别编码

Chemical Name	Diphenyl sulfide
Synonym	Diphenylsulfane {LY} Diphenylsulfane {} {LY} Diphenylsulfane {} {} {LY} Diphenylsulfane {} {} {} {LY} Diphenylsulfane {} {} {} {} {LY} Diphenylsulfane {} {} {} {} {} {LY} Diphenylsulfane {} {} {} {} {} {} {LY} Diphenylsulfane {} {} {} {} {} {} {} {LY} Diphenylsulfane {} {} {} {} {} {} {} {} {LY} Diphenylsulfane {} {} {} {} {} {} {} {} {} {LY} Diphenylsulfane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenylsulfane {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenylsulfane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenylsulfane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenylsulfane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenylsulfane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenylsulfane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenylsulfane
CAS Number	139-66-2
EC Number	205-371-4
Beilstein Registry Number	1907932
MDL Number	MFCD00003064
PubChem Substance ID	8766
Merck Number	7314
Reaxys-RN	1907932
Chemical Name Translation	二苯硫醚
Wiswesser Line Notation	RSR
LabNetwork Molecule ID	LN00226444
InChI	InChI=1S/C12H10S/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h1-10H
Canonical SMILES	C1(SC2=CC=CC=C2)=CC=CC=C1

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

产品应用

用于有机合成。

安全信息

Signal word Warning

GHS Symbol

WGK Germany3

Safety Statements

S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

Risk Statements

R22 Harmful if swallowed 吞咽有害
R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
R38 Irritating to skin 刺激皮肤
R50/53

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P312+P330
P302+P350
P302+P352+P332+P313+P362+P364
P305+P351+P338
P332+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H302 Harmful if swallowed 吞食有害
H315 Causes skin irritation 会刺激皮肤
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSSX2275000

Hazard Codes 9

UN Number 3082

Packing GroupIII

Hazard Class9

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 490 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   23,95,1962

Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitro

其他信息

方法一:将858g无水苯和464g三氯化铝混合，冷却到10℃，搅拌下加入405.1g氯化硫和390g苯配成的溶液。反应立即开始，逸出氯化氢，析出黄色粘稠的三氯化铝络合物。反应毕，将反应混合物冰析。分出苯层，蒸除苯后的深色油状物冷至0℃，滤除析出的硫。再将油状物溶于甲醇，冷却至0℃，再滤除析出硫。甲醇溶液在回收甲醇后继续蒸除少量低沸点馏分。然后收集155-170℃（2.39kPa）馏分，即为粗品。粗品用锌粉、氢氧化钠加热处理，水洗，干燥，最后进行减压蒸馏，得450-464g二苯硫醚。
方法二:氯苯法---以氯苯为起始原料，有与硫反应的方法和与硫化氢反应的方法。
Acros Organics:苯硫醚 Phenyl sulfide, 99%(139-66-2)
用途三:用于合成2，4-二氯苯酚，除草醚、2，4-滴、EPBP、毒克散、格螨酯等农药；医药方面用于合成硫双二氯酚等。
图谱信息:二苯硫醚(139-66-2)Raman光谱二苯硫醚(139-66-2)核磁图( 13 CNMR) 二苯硫醚(139-66-2)核磁图( 1 HNMR) 二苯硫醚(139-66-2)红外图谱(IR1) 二苯硫醚(139-66-2)质谱(MS)
用途二:用于有机合成。
下游产品:2,4-二氯酚 --> 2-氯噻吨酮 --> 2-氯-9-[3-(二甲基氨基)丙基]噻吨-9-醇 --> 4-羟基硫代香豆素 --> 硝酸芬替康唑
二苯硫醚价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 P0230 二苯硫醚 Phenyl Sulfide 500G 785元 2014/06/02 P0230 二苯硫醚 Phenyl Sulfide 25G 185元 2010/06/21 130951000 二苯硫醚 Phenyl sulfide 99% 100 ML 1262元
MOL 文件:139-66-2.mol
能与苯、醚、二硫化碳混碳，溶于热醇，不溶于水。
Sigma Aldrich:139-66-2(sigmaaldrich)
上游原料:锌粉 --> 甲醇溶液 --> 二氯化二硫 --> 无水苯
敏感性:Stench
TCI Shanghai:二苯硫醚 Phenyl Sulfide,>;98.0%(GC)(139-66-2)
用途一:用作农药、医药、染料中间体
Alfa Aesar:二苯硫醚,98% Diphenyl sulfide, 98%(139-66-2)
Hazard Note:Harmful/Stench
F:13