1-Naphthol 1-萘酚
CAS 90-15-3 MFCD00003930
信息真实价格透明
资金保障
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信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- {SNA} Analytical Standards, Physical Properties Standards,
- {SNA} Building Blocks, C9 to C20+, Chemical Synthesis, Detection, Organic Building Blocks, Oxygen Compounds, Phenols, 生化试剂, 荧光探针,标记,粒子和染色剂
- {SNA} APIs & Metabolites, APIs (Active Pharmaceutical Ingredients) & Metabolites,
产品应用
- 1、比色测定钛、铌、钨、锗、钒、亚硝酸盐和铜, 酪氨酸及蛋白质等的定性试剂,有机合成。
- 2、本品是染料、医药、农药、香料和橡胶防老剂的基本原料或中间体及彩色电影胶片之成色剂。
相关文献及参考
- Merck: 14,6383
- Merck: 14,6383 Beilstein: 6,IV,4208
- Short: II/2
- Short: II/27B
- [1]. Swain J, et al. 1-Naphthol as an ESPT fluorescent molecular probe for sensing thermotropic microenvironmental changes of pluronic F127 in aqueous media. Phys Chem Chem Phys. 2015 Jul 14;17(26):16752-9.
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H318 Causes serious eye damage 严重伤害眼睛
- H302 Harmful if swallowed 吞食有害
- H312 Harmful in contact with skin 皮肤接触有害
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
- H311 Toxic in contact with skin 皮肤接触中毒
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312+P330
- P302+P350
- P302+P352+P312+P361+P364
- P304+P340
- P304+P340+P312
- P305+P351+P338
- P305+P351+P338+P310
- P308+P311
- P332+P313
- P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S2 Keep out of the reach of children 避免儿童触及;
- S22 Do not breathe dust 不要吸入粉尘;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
- R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
- R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
- R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : >420 mg/m3/1H TOXIC EFFECTS : Sense Organs and Special Senses (Eye) - lacrimation Gastrointestinal - changes in structure or function of salivary glands REFERENCE : BIOFX* BIOFAX Industrial Bio-Test Laboratories, Inc., Data Sheets. (1810 Frontage Rd., Northbrook, IL 60062) Volume(issue)/page/year: 25-4/1973
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - guinea pig DOSE/DURATION : 2 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 30(9),22,1965
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Mammal - cat DOSE/DURATION : 134 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 30(9),22,1965
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 9 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 30(9),22,1965
TYPE OF TEST : LD50 - Lethal dose, 50 percen
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 500 ug/plate REFERENCE : BJCAAI British Journal of Cancer. (Macmillan Press Ltd., Houndmills, Basingstoke, Hants. RG21 2XS, UK) V.1- 1947- Volume(issue)/page/year: 37,873,1978
TYPE OF TEST : DNA repair TEST SYSTEM : Bacteria - Escherichia coli DOSE/DURATION : 2 mg/disc REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 97,1,1982
TYPE OF TEST : DNA repair TEST SYSTEM : Bacteria - Bacillus subtilis DOSE/DURATION : 5 gm/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 42,19,1977
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Subcutaneous SPECIES OBSERVED : Rodent - mouse DOSE : 90 mg/kg SEX/DURATION : female 6-14 day(s) after conception TOXIC EFFECTS : Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured before birth) Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) REFERENCE : NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: PB223-160
其他信息
- 外观性质:无色或黄色、有苯酚气味、晶体或粉末状。
- 用途四:1-萘酚又名α-萘酚、甲萘酚、α-羟基萘,是生产杀虫剂甲萘威的关键中间体。1-萘酚在染料工业中用于生产酸性黄1、酸性橙20、媒染黑3、媒染黑11、溶剂红3、溶剂橙5、油棕GB等,在医药工业中可用于制造防腐剂和抗腐蚀药物等,也是许多醛及矿物油和植物油的有效抗氧剂,广泛用于合成香料、橡胶防老化剂及彩色电影胶片的成色剂。
- 图谱信息:a-萘酚(90-15-3)核磁图( 1 HNMR) a-萘酚(90-15-3)红外图谱(IR2) a-萘酚(90-15-3)核磁图( 13 CNMR) a-萘酚(90-15-3)红外图谱(IR3) a-萘酚(90-15-3)质谱(MS) a-萘酚(90-15-3)Raman光谱 a-萘酚(90-15-3)红外图谱(IR1)
- 下游产品:萘丙胺 --> 1,4-萘醌 --> 铬黑 T --> 敌草胺 --> 2-乙氧基-1-萘甲酰氯 --> 17-乙炔基-17-羟基-18-甲基雌甾-5(10),9(11)-二烯-3-酮-3-乙二醇缩酮 --> 2-亚硝基-1-萘酚 --> 13-乙基-3Β-甲氧基甾烷-2,5(10)-二烯-17-酮-17-环亚乙基缩酮 --> 17Α-乙炔基-3Β,17Β-二羟基-18-甲基雌甾-2,5(10)-二烯-3-甲醚 --> 13-乙基-3-甲氧基甾烷-1,3,5(10)-三烯-17-酮-17-环亚乙基缩酮 --> 1-羟基-2-萘甲酸 --> CI 15630 --> 3-苯基-5,6-苯并香豆素 --> 13-乙基-17Β-羟基-18,19-二去甲孕甾-5(10)-烯-20-炔-3-酮 17Α-乙炔基-17Β-羟基-18-甲基雌甾-5(10)-烯-3-酮 --> N,N'-二(2-萘基)对苯二胺 --
- 海关编码:29071510
- F:8-23
- 在空气中逐渐变成玫瑰红色。常温下为带有萘兼酚的特征气味,对空气敏感,遇光变黑,常温下能升华,能随水蒸气挥发。易溶于醇、醚、苯、氯仿和碱溶液,微溶于水。最大吸收波长297、310、324nm。
- 用途六:1、比色测定钛、铌、钨、锗、钒、亚硝酸盐和铜, 酪氨酸及蛋白质等的定性试剂,有机合成。2、本品是染料、医药、农药、香料和橡胶防老剂的基本原料或中间体及彩色电影胶片之成色剂。
- 用途一:合成橡胶防老剂、杀虫剂、香料、染料等
- TCI Shanghai:1-萘酚 1-Naphthol,>;99.0%(GC)(90-15-3)
- MSDS 信息:α-萘酚(90-15-
- 蒸气压:1 mm Hg ( 94 °C)
- MSDS 信息:α-萘酚
- 方法一:1-萘酚有多种生产方法。 α-萘磺酸碱熔法 以萘为原料,用浓硫酸低温(40℃以下)磺化得到α-萘磺酸,再在310~320℃碱熔可制得1-萘酚。 该法总收率约40%,副产物2-萘酚较多,酸、碱消耗量大。用氯磺酸代替浓硫酸进行磺化,以邻硝基乙苯作溶剂,再经碱熔可得到1-萘酚,其收率约为72%,2-萘酚的生成量减少,但需耗用溶剂。 α-萘胺水解法 以α-萘胺为原料,在15%~20%的硫酸中加压水解。 反应温度为200℃,压力为1.2~1.5 MPa。水解产物分离,回收生成的硫酸氢铵,经中和、蒸馏得到含量96%~98%的1-萘酚,收率近90%。该法工艺较简单,但α-萘胺毒性高,设备防腐和废水处理问题较严重。 如果采用α-氯萘水解,温度和压力条件更高,反应压力约5MPa,反应温度为270℃左右,需采用铜催化剂。 四氢萘法 以萘为原料,经加氢得到四氢萘,再经氧化、脱氢得到1-萘酚。 萘加氢制四氢萘,采用工业加氢钼酸镍催化剂和“绝热”反应装置,压力约3MPa,平均反应温度300℃,加料空速0.8h -1 ,氢/萘比2500~6400(体积比),萘单程转化率可达85%,四氢萘选择达92%以上,精馏后四氢萘纯度达98%以上,加氢及精制总收率为85.5%。 四
- 用途二:用作分析试剂,也用于有机合成
- Alfa Aesar:1-萘酚,99% 1-Naphthol, 99%(90-15-3)
- Sigma Aldrich:90-15-3(sigmaaldrich)
- {C