6-Amino-4-Hydroxy-2-Naphthalenesulfonic Acid 6-氨基-4-羟基萘-2-磺酸

CAS 90-51-7 MFCD00003973

化学结构图

90-51-7
SMILES: Nc1ccc2cc(S(=O)(=O)O)cc(O)c2c1

化学属性

Mol. FormulaC10H9NO4S
Mol. Weight239.25
Appearance 纯品为白色针状结晶或结晶粉末。 溶于乙醇和乙醚,难溶于水。
Solubility溶于乙醇和乙醚,难溶于水。
Density1.627
Boiling Point458 °C at 760 mmHg

别名和识别编码

Chemical Name6-Amino-4-Hydroxy-2-Naphthalenesulfonic Acid
Synonym 6-Amino-4-hydroxynaphthalene-2-sulfonic acid {LY} 6-Amino-4-hydroxynaphthalene-2-sulfonic acid {} {LY} 6-Amino-4-hydroxynaphthalene-2-sulfonic acid {} {} {LY} 6-Amino-4-hydroxynaphthalene-2-sulfonic acid {} {} {} {LY} 6-Amino-4-hydroxynaphthalene-2-sulfonic acid {} {} {} {} {LY} 6-Amino-4-hydroxynaphthalene-2-sulfonic acid {} {} {} {} {} {LY} 6-Amino-4-hydroxynaphthalene-2-sulfonic acid {} {} {} {} {} {} {LY} 6-Amino-4-hydroxynaphthalene-2-sulfonic acid {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {LY} 6-Amino-4-hydroxynaphthalene-2-sulfonic acid {} {} {} {} {} {} {} {} {LY} 6-Amino-4-hydroxynaphthalene-2-sulfonic acid {} {} {} {} {} {} {} {} {} {LY} 6-Amino-4-hydroxynaphthalene-2-sulfonic acid {} {} {} {} {} {} {} {} {} {} {LY} 6-Amino-4-hydroxynaphthalene-2-sulfonic acid {} {} {} {} {} {} {} {} {} {} {} {LY} 6-Amino-4-hydroxynaphthalene-2-sulfonic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} 6-Amino-4-hydroxynaphthalene-2-sulfonic acid {} {} {} {} {} {} {} {} {}
CAS Number90-51-7
PubChem Substance ID87562016
EC Number202-000-8
Beilstein Registry Number1821283
MDL NumberMFCD00003973
Reaxys-RN1821283
Chemical Name Translation6-氨基-4-羟基萘-2-磺酸
LabNetwork Molecule IDLN00238308
InChIInChI=1S/C10H9NO4S/c11-7-2-1-6-3-8(16(13,14)15)5-10(12)9(6)4-7/h1-5,12H,11H2,(H,13,14,15)
Canonical SMILESOC1=CC(S(=O)(O)=O)=CC2=CC=C(N)C=C12
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfonic/Sulfinic Acids, Sulfur Compounds
  • {SA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfonic/Sulfinic Acids, Sulfur Compounds

产品应用

  • 本品用作偶氮染料的中间体,作为黑色系列的直接染料、酸性染料的中间体而被广泛应用。其衍生物钠盐易溶于水;O,N-二乙酰化物的对甲苯胺盐,熔点230~231℃。

相关文献及参考

  • Beilstein: 14,IV,2823

安全信息

GHS Symbol
WGK Germany1
Hazard Codes C
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSQK1295250
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Signal word Danger
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R34 Causes burns 会导致灼伤
UN Number UN 2585 8/PG 3 2585
TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 6,59,1954

Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr

其他信息

  • 上游原料:氢氧化钠 --> 二氧化硫 --> 2-羟基萘 --> 2-萘胺 --> 色膏 --> 2-萘酚-6,8-二磺酸双钾盐
  • 储运特性:库房通风低温干燥
  • 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
  • 用途三:本品用作偶氮染料的中间体,作为黑色系列的直接染料、酸性染料的中间体而被广泛应用。其衍生物钠盐易溶于水;O,N-二乙酰化物的对甲苯胺盐,熔点230~231℃。
  • 毒性分级:中毒
  • 急性毒性:腹腔-小鼠 LD: >;500 毫克/公斤
  • 方法一:以前生产γ酸用β-萘胺为原料,同时副产J酸。但由于β-萘胺的致癌作用如今不再采用。目前用G盐(2-萘酚-6,8-二磺酸双钾盐)为原料,经氨化、碱熔、酸化而得。产品规格:HG2-205-80。外观为浅灰色膏状物,γ酸含量(以偶合值计)大于55%。原料消耗定额:G盐(折100%)1520kg/t、硫酸(99%)1850kg/t、烧碱(折100%)1200kg/t、二氧化硫(工业品)330kg/t、氨(99%)485kg/t。
  • 用途一:主要用作偶氮染料的中间体,用于制造活性及直接染料
  • 图谱信息:2-氨基-8-萘酚-6-磺酸(90-51-7)红外图谱(IR1) 2-氨基-8-萘酚-6-磺酸(90-51-7)红外图谱(IR2)
  • 溶于乙醇和乙醚,难溶于水。遇三氯化铁呈现暗红紫色。与亚硝酸作用,生成黄色难溶性重氮化合物。在酸性及碱性条件偶合分别生成两种偶氮化合物。
  • 下游产品:酸性红37 --> 直接灰D
  • TCI Shanghai:6-氨基-4-羟基-2-萘磺酸 6-Amino-4-hydroxy-2-naphthalenesulfonic Acid,>;97.0%(LC)(T)(90-51-7)
  • 可燃性危险特性:可燃;燃烧产生有毒氮氧化物和硫氧化物烟雾
  • Sigma Aldrich:90-51-7(sigmaaldrich)
  • 用途二:用作活性染料和直接染料的中间体。用于直接重氮黑BH、直接深棕M、直接枣红GB、直接红F、直接灰D、直接N和直接耐晒灰等。
  • 类别:有毒物品
  • MOL 文件:90-51-7.mol
  • 2-氨基-8-萘酚-6-磺酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0371 6-氨基-4-羟基-2-萘磺酸 6-Amino-4-hydroxy-2-naphthalenesulfonic Acid 500G 1530元 2014/06/02 A0371 6-氨基-4-羟基-2-萘磺酸 6-Amino-4-hydroxy-2-naphthalenesulfonic Acid 25G 306元

系列性分类


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