2-Methyl-2-Propanethiol 叔丁基硫醇
CAS 75-66-1 MFCD00004857
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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分类
- {SNA} Alkyl Thiols, Building Blocks, Chemical Synthesis, Micro/NanoElectronics, Organic Building Blocks, Self Assembly & Contact Printing, Self-Assembly Materials, Sulfur Compounds, Thiols, Thiols/Mercaptans, 材料科学
- Alkyl Thiols, Building Blocks, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Organic Building Blocks, Self Assembly & Contact Printing, Self-Assembly Materials, Sulfur Compounds, Thiols, Thiols/Mercaptans
- {SNA} Alkyl Thiols, Building Blocks, Chemical Synthesis, Materials Science,
相关文献及参考
- Merck: 14,1579
- Merck: 14,1579 Beilstein:1,383
- Short: II/14a
- Short: II/2
- Short: III/38B
安全信息
GHS Symbol
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- H318 Causes serious eye damage 严重伤害眼睛
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241+P242+P243
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P310
- P302+P352+P332+P313+P362+P364
- P303+P361+P353
- P305+P351+P338
- P305+P351+P338+P337+P313
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
- P331 Do NOT induce vomiting.. 不要催吐。
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P370+P378
- P403+P235
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
- S38 In case of insufficient ventilation wear suitable respiratory equipment 通风不良时,佩带适当的呼吸器;
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
- R11 Highly flammable 非常易燃
- R36 Irritating to eyes 刺激眼睛
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
- R51/53
- R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 22200 ppm/4H TOXIC EFFECTS : Behavioral - muscle weakness Behavioral - ataxia Lungs, Thorax, or Respiration - cyanosis REFERENCE : AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 19,171,1958
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 590 mg/kg TOXIC EFFECTS : Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - respiratory depression Behavioral - coma REFERENCE : AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 19,171,1958
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 4729 mg/kg TOXIC EFFECTS : Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - respiratory depression Behavioral - coma REFERENCE : AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 19,171,1958
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 16500 ppm/4H TOXIC EFFECTS : Behavioral - muscle weakness Behavioral - ataxia Lungs, Thorax, or Respiration - cyanosis REFERENCE : AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron,
其他信息
- 灭火剂:雾状水、泡沫、砂土、二氧化碳、1211灭火剂
- 用途一:特丁硫醇是有机磷杀虫剂特丁硫磷的中间体。
- 急性毒性:口服- 大鼠 LD50: 4729 毫克/ 公斤
- 刺激数据:眼- 兔子 84 毫克
- 毒性分级:中毒
- 蒸气密度:3.1 (vs air)
- 类别:易燃液体
- TCI Shanghai:叔丁基硫醇 tert-Butyl Mercaptan,>;98.0%(GC)(75-66-1)
- 上游原料:氢 --> 异丁烯 --> 氢硫酸 --> 特丁硫醇
- 外观性质:无色液体,有不愉快气味。
- F:13
- 蒸气压:303.5 mm Hg ( 37.7 °C)
- MOL 文件:75-66-1.mol
- 方法一:其制备方法是由异丁烯和硫化氢进行催化反应得到特丁硫醇。(CH 3 ) 2 C=CH 2 +H 2 S[催化剂]→(CH 3 ) 3 CSH 将装有催化剂的合成塔预热到70℃,按一定配比将异丁烯气体和干燥的硫化氢气体通入混合器,混合气体进入预热器预热。控制一定温度再进入合成塔,保持稳定的流速使反应气体从塔顶进入冷凝器,经分离器将未反应的混合气体送回混合器,分离出的液体即为特丁硫醇。
- Acros Organics:2-甲基-2-丙硫醇 2-Methyl-2-propanethiol, 99%(75-66-1)
- 微溶于水,溶于液体硫化氢,极溶于醇和醚。
- 图谱信息:叔丁基硫醇(75-66-1)红外图谱(IR1) 叔丁基硫醇(75-66-1)核磁图( 1 HNMR) 叔丁基硫醇(75-66-1)质谱(MS) 叔丁基硫醇(75-66-1)核磁图( 13 CNMR)
- 储运特性:库房通风低温干燥; 轻装轻卸、与氧化剂和酸类分开存放
- 下游产品:
- Sigma Aldrich:75-66-1(sigmaaldrich)
- 叔丁基硫醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0405 叔丁硫醇 tert-Butyl Mercaptan 25ML 168元 2014/06/02 M0405 叔丁硫醇 tert-Butyl Mercaptan 500ML 329元 2010/06/21 149020500 叔丁基硫醇 2-Methyl-2-propanethiol 99% 50 ML 178元
- 可燃性危险特性:明火、受热、氧化剂可燃; 遇酸、受热放出有毒氧化硫气体
- MSDS 信息:叔丁硫醇(75-66-1).msds