2-Amino-3-sulfanyl-propanoic acid hydrochloride DL-半胱氨酸碱

CAS 3374-22-9 MFCD00004881

化学结构图

3374-22-9
SMILES: N[C@@H](CS)C(=O)O

化学属性

Mol. FormulaC3H7NO2S
Mol. Weight121.15
Melting Point225°C
TSCANo
Density1.334
Stability对光敏感
Appearance 无色结晶状物质；微臭，味酸；易溶于水、乙酸和氨水和乙醇，不溶于乙醚、苯、丙酮、乙酸乙酯、二硫化碳和四氯化碳；在中性或微碱性溶液中易氧化为胱氨酸，微量铁及重金属离子可促进氧化，在酸中能稳定存在。
Boiling Point293.883 °C at 760 mmHg

别名和识别编码

Chemical Name2-Amino-3-sulfanyl-propanoic acid hydrochloride
CAS Number3374-22-9
Synonym 2-Amino-3-mercaptopropanoic acid {LY} 2-Amino-3-mercaptopropanoic acid {} {LY} 2-Amino-3-mercaptopropanoic acid {} {} {LY} 2-Amino-3-mercaptopropanoic acid {} {} {} {LY} 2-Amino-3-mercaptopropanoic acid {} {} {} {} {LY} 2-Amino-3-mercaptopropanoic acid {} {} {} {} {} {LY} 2-Amino-3-mercaptopropanoic acid {} {} {} {} {} {} {LY} 2-Amino-3-mercaptopropanoic acid {} {} {} {} {} {} {} {LY} 2-Amino-3-mercaptopropanoic acid {} {} {} {} {} {} {} {} {LY} 2-Amino-3-mercaptopropanoic acid {} {} {} {} {} {} {} {} {} {LY} 2-Amino-3-mercaptopropanoic acid {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} 2-Amino-3-mercaptopropanoic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Amino-3-mercaptopropanoic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Amino-3-mercaptopropanoic acid {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Amino-3-mercaptopropanoic acid
MDL NumberMFCD00004881
PubChem Substance ID5862
Beilstein Registry Number1721406
EC Number222-160-2
Alfabeta NameCYSTEINE DL-
Chemical Name TranslationDL-半胱氨酸碱
Wiswesser Line NotationQVYZ1SH
LabNetwork Molecule IDLN00183188
InChIInChI=1S/C3H7NO2S/c4-2(1-7)3(5)6/h2,7H,1,4H2,(H,5,6)/t2-/m0/s1
Canonical SMILESO=C(O)C(N)CS
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分类

  • {Chemicalbook} 生物化学品: 生化试剂: 氨基酸及其衍生物
  • Amino Acids & Derivatives
  • Sulfur & Selenium Compounds
  • {SNA} Amino Acid Derivatives, Chemical Biology, Chemical Synthesis, Cysteine/Cystine, Peptide Chemistry
  • Pharmaceuticals
  • Intermediates & Fine Chemicals
  • {SNA} Amino Acids & Derivatives, Chemical Biology, Chemical Synthesis, Cysteine/Cystine, Peptide Chemistry
  • {uni_hamburg} no charge; carboxylic acid; thiol; racemate; 1fragment

产品应用

  • 生化研究。NMDA受体激动剂

相关文献及参考

  • Hui, N. et al.: Meat Sci. Appl., 74 (2001); Kiviharju, K. et al.: J. Biotechnol., 117, 299 (2005); Pecivova, P. et al.: J. Sci. Food Agric., 90, 1681 (2010);
  • Short: III/35B Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Fluorine-19 and Nitrogen-15 Author: Balasubramanian, M.; Gupta, R.R.; Jain, M.; Perumal, S. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35B Year: 1998 ISBN: 3-540-63275-1 ISBN: 978-3-540-63275-7 Internet Resource: DOI:10.1007/b55685 RefComment: VII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.
  • Short: IV/8A Title: Enthalpies of Fusion and Transition of Organic Compounds Author: Zhang, Z.-Y.; Frenkel, M.; March, K.N.; Wilhoit, R.C. Editor: Marsh, K.N. Source: Landolt-Börnstein, New Series Volume: IV/8A Year: 1995 Keyword: organic compounds; enthaly of fusion; melting point; phase transition ISBN: 3-540-58854-X ISBN: 978-3-540-58854-2 Internet Resource: DOI:10.1007/b55145 RefComment: VIII, 588 pages.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P312+P330
  • P301+P317
  • P302+P352
  • P303+P361+P353
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P317
  • P337+P317
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
WGK Germany1
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word
Warnings IRRITANT
RTECSHA1595000
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Packing GroupIII
Safety Statements
Risk Statements
UN Number
Hazard Codes C 
TYPE OF TEST            : Phage inhibition capacity
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 5 mg/L
REFERENCE :
   APMBAY Applied Microbiology.  (Washington, DC)  V.1-30, 1953-75.  For
   publisher information, see AEMIDF.  Volume(issue)/page/year: 12,234,1964

其他信息

  • DL-半胱氨酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 62007460 DL-半胱氨酸;DL-2-氨基-3-巯基丙酸; DL-半膀胱氨基酸; DL-β-巯基丙氨酸; DL-脬氨基酸 25g 60元 2011/08/23 62007434 DL-半胱氨酸;DL-2-氨基-3-巯基丙酸; DL-半膀胱氨基酸; DL-β-巯基丙氨酸; DL-脬氨基酸 25g 60元
  • MSDS 信息:2-Amino-3-mercaptopropionic acid(3374-22-9).msds
  • 上游原料:DL-半胱氨酸盐酸盐
  • 方法一:以DL-半胱氨酸盐酸盐为原料，用碱中和后过滤、干燥，精制而得。
  • 用途一:用于生化研究。
  • MOL 文件:3374-22-9.mol
  • 参考质量标准:含量不少于98%；纸层析、盐酸溶解试验、灼烧残渣、干燥失重、氯化物、重金属、铁等项均合格。
  • Sigma Aldrich:3374-22-9(sigmaaldrich)
  • F:8-10-23
  • 在空气中极易氧化。在中性或微碱性溶液中能被空气氧化成胱氨酸，在酸性溶液中较稳定。溶于水、乙醇、乙酸和氨水，不溶于乙醚、丙酮、乙酸乙酯、苯、二硫化碳和四氯化碳。

系列性分类

  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Amino Acids 氨基酸
  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Amino Acid Derivatives 氨基酸及其衍生物
  5. Cysteine/Cystine - Amino Acid Derivatives
  1. Functional Group 官能团索引
  2. alkylthiol

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