CAS 103-85-5 MFCD00004933-1-Phenylthiourea 苯基硫脲 TAO{mole}

1-Phenylthiourea 苯基硫脲

CAS 103-85-5 MFCD00004933

化学结构图

SMILES: NC(=S)NC1CCCCC1

化学属性

Mol. Formula	C7H8N2S
Mol. Weight	152.22
Melting Point	145-150°C
TSCA	Yes
Density	1.294
Stability	对湿度敏感
Appearance	苯基硫脲(103-85-5)为白色针状结晶。熔点154℃。易溶于乙醇，能溶于400份冷水，17份热水中。微具苦味。
Boiling Point	266.7°C at 760 mmHg
Flash Point	115.1°C

别名和识别编码

Chemical Name	1-Phenylthiourea
MDL Number	MFCD00004933
CAS Number	103-85-5
Synonym	Phenylthiourea {LY} Phenylthiourea {} {LY} Phenylthiourea {} {} {LY} Phenylthiourea {} {} {} {LY} Phenylthiourea {} {} {} {} {LY} Phenylthiourea {} {} {} {} {} {LY} Phenylthiourea {} {} {} {} {} {} {LY} Phenylthiourea {} {} {} {} {} {} {} {LY} Phenylthiourea {} {} {} {} {} {} {} {} {LY} Phenylthiourea {} {} {} {} {} {} {} {} {} {LY} Phenylthiourea {} {} {} {} {} {} {} {} {} {} {LY} Phenylthiourea {} {} {} {} {} {} {} {} {} {} {} {LY} Phenylthiourea {} {} {} {} {} {} {} {} {} {} {} {} {LY} Phenylthiourea {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Phenylthiourea {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Phenylthiourea {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Phenylthiourea {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Phenylthiourea {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Phenylthiourea
PubChem Substance ID	87574480
Beilstein Registry Number	907309
EC Number	203-151-2
Merck Number	7315
Reaxys-RN	907309
Chemical Name Translation	苯基硫脲
Wiswesser Line Notation	SUYZMR
LabNetwork Molecule ID	LN00116464
InChI	InChI=1S/C7H8N2S/c8-7(10)9-6-4-2-1-3-5-6/h1-5H,(H3,8,9,10)
Canonical SMILES	S=C(NC1=CC=CC=C1)N

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产品应用

检定铜、金、汞、钯、铂和银。有机微量分析测定氮和硫的标准物质。用于生产2-氨基苯并噻唑、3-甲基苯并噻唑腙等染料中间体。也用作分析试剂。

安全信息

WGK Germany3

GHS Symbol

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P310
P301+P310+P330
P302+P350
P302+P352+P333+P313+P362+P364
P333+P313
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H317 May cause an allergic skin reaction 可能导致皮肤过敏
H300 Fatal if swallowed 吞食致命

RTECSYU1400000

Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

Signal word Danger

Safety Statements

S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；

Packing GroupI

UN Number 2811 UN 2811 6.1/PG 1

Risk Statements

R28 Very toxic if swallowed 吞咽极毒
R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应

Hazard Codes 6.1 T+

Storage condition 2-8°C {LY} 2-8°C Poison room Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

Hazard Class6.1

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5 mg/kg
TOXIC EFFECTS :
   Endocrine - hyperglycemia
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 89,186,1947

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 40 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JMPCAS Journal of Medicinal and Pharmaceutical Chemistry.  (Washington, DC)
   V.1-5, 1959-62.  For publisher information, see JMCMAR.
   Volume(issue)/page/year: 4,109,1961

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 25 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 10 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCILB* Progress Report for Contract No. NIH-NCI-E-C-72-3252, Submitted to
   the National Cancer Institute by Litton Bionetics, Inc.  (Bethesda, MD)
   Volume(issue)/page/year: NCI-E-C-72-3252,1973

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral

TYPE OF TEST            : DNA damage
TEST SYSTEM             : Rodent - rat Liver
DOSE/DURATION           : 8 mmol/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   24,181,1994

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 168 mg/kg
SEX/DURATION            : female 1-21 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - cytological changes (including
   somatic cell genetic material)
   Reproductive - Effects on Embryo or Fetus - other effects to embryo
REFERENCE :
   EXPEAM Experientia.  (Birkhaeuser Verlag, POB 133, CH-4010 Basel,
   Switzerland)  V.1-    1945-  Volume(issue)/page/year: 34,1319,1978

其他信息

图谱信息:苯基硫脲(103-85-5)红外图谱(IR2) 苯基硫脲(103-85-5)质谱(MS) 苯基硫脲(103-85-5)红外图谱(IR1) 苯基硫脲(103-85-5)核磁图( 1 HNMR)
MOL 文件:103-85-5.mol
Acros Organics:1-苯基-2-硫脲 C7 H8 N2 S 1-Phenyl-2-thiourea, 97%(103-85-5)
用途二:检定铜、金、汞、钯、铂和银。有机微量分析测定氮和硫的标准物质。用于生产2-氨基苯并噻唑、3-甲基苯并噻唑腙等染料中间体。也用作分析试剂。
上游原料:硫氰酸钠
Sigma Aldrich:103-85-5(sigmaaldrich)
苯基硫脲价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 P0237 1-苯基-2-硫脲 1-Phenyl-2-thiourea 25G 455元 2014/06/02 P0237 1-苯基-2-硫脲 1-Phenyl-2-thiourea 500G 3790元 2010/06/21 207250050 苯基硫脲 1-Phenyl-2-thiourea 97% 5 GR 245元
下游产品:2-氨基苯并噻唑 --> 4-苯氧基-2,6-二异丙基苯硫代异氰酸酯
TCI Shanghai:1-苯基-2-硫脲 1-Phenyl-2-thiourea,>;98.0%(N)(103-85-5)
Alfa Aesar:苯硫脲,97% N-Phenylthiourea, 97%(103-85-5)
用途一:用于生产2-氨基苯并噻唑、3-甲基苯并噻唑腙等染料中间体。也用作分析试剂。
方法一:由苯胺先与硫酸成盐，再与硫氰化钠进行加成反应而得。
苦味或无味(根据试味者的遗传特征)。水中溶解度: 1 G/L (20°C)，溶于400份冷水、17份沸水，溶于乙醇、AQ、乙醚和氢氧化钠碱液。剧毒，半数致死量(大鼠，经口)3mg/kg。