Cyclopentene oxide 氧化环戊烯

CAS 285-67-6 MFCD00005161

化学结构图

285-67-6
SMILES: C1CC2OC2C1

化学属性

Mol. FormulaC5H8O
Mol. Weight84.12
Refractive index1.4330 to 1.4360
Boiling Point102°C at 760 mmHg
Density0.964
Flash Point10°C
TSCAYes
Appearance 无色液体性,密度 0.964,沸点 102℃,折射率 1.433-1.435,闪点 10℃
Melting Point136-137 °C

别名和识别编码

Chemical NameCyclopentene oxide
CAS Number285-67-6
Alfabeta NameEPOXYCYCLOPENTANE 12-,
MDL NumberMFCD00005161
Synonym 1,2-Epoxycyclopentane {LY} 1,2-Epoxycyclopentane {} {LY} 1,2-Epoxycyclopentane {} {} {LY} 1,2-Epoxycyclopentane {} {} {} {LY} 1,2-Epoxycyclopentane {} {} {} {} {LY} 1,2-Epoxycyclopentane {} {} {} {} {} {LY} 1,2-Epoxycyclopentane {} {} {} {} {} {} {LY} 1,2-Epoxycyclopentane {} {} {} {} {} {} {} {LY} 1,2-Epoxycyclopentane {} {} {} {} {} {} {} {} {LY} 1,2-Epoxycyclopentane {} {} {} {} {} {} {} {} {} {LY} 1,2-Epoxycyclopentane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Epoxycyclopentane {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Epoxycyclopentane {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Epoxycyclopentane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Epoxycyclopentane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Epoxycyclopentane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,2-Epoxycyclopentane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID9244
EC Number206-005-6
Beilstein Registry Number17(5)1,190
Reaxys-RN102495
Chemical Name Translation氧化环戊烯
Wiswesser Line NotationT35 BOTJ
LabNetwork Molecule IDLN00008958
InChIInChI=1S/C5H8O/c1-2-4-5(3-1)6-4/h4-5H,1-3H2
Canonical SMILESC12CCCC1O2
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Epoxides, Organic Building Blocks, Oxygen Compounds
  • {SNA} Epoxide Monomers, Monomers, Polymer Science, 材料科学
  • {SNA} Epoxide Monomers, Materials Science, Monomers, Polymer Science
  • {uni_hamburg} no charge; oxygen heterocycle; carbocycle; alicycle; fused rings; 3ring; 5ring; 6ring; ether; racemate; 1fragment

相关文献及参考

  • Base-induced isomerization can give 2-cyclopentenol or cyclopentanone depending on the conditions. For discussion of the mechanism, see: J. Org. Chem., 61, 820 (1996), and references therein. Review of the rearrangement of epoxides to allylic alcohols: Org. React., 29, 345 (1983).
  • Beilstein:17(5)1,190
  • Short: II/25D

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard Codes F;Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSRN8935000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P332+P313
  • P370+P378
  • P305+P351+P338+P337+P313
  • P233 Keep container tightly closed. ?保持容器密闭。
Signal word
UN Number UN 1993 3/PG 2 1993
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R11 Highly flammable 非常易燃
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
Packing GroupII
Hazard Class3
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 15 umol/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 90,67,1981

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 40 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 249,55,1991

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Klebsiella pneumoniae
DOSE/DURATION           : 2 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 89,269,1981

其他信息

  • Sigma Aldrich:285-67-6(sigmaaldrich)
  • 1,2-环氧环戊烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 E0513 1,2-环氧环戊烯 1,2-Epoxycyclopentane 5G 588元 2014/06/02 E0513 1,2-环氧环戊烯 1,2-Epoxycyclopentane 25G 2040元 2010/06/21 348520250 1,2-环氧环戊烷 Cyclopentene oxide 98% 25 GR 2375元
  • Alfa Aesar:氧化环戊烯,97% Cyclopentene oxide, 97%(285-67-6)
  • TCI Shanghai:1,2-环氧环戊烯 1,2-Epoxycyclopentane,>;97.0%(GC)(285-67-6)
  • MSDS 信息:Cyclopentene oxide(285-67-6).msds
  • Acros Organics:氧化环戊烯 Cyclopentene oxide, 98%(285-67-6)
  • MOL 文件:285-67-6.mol
  • 上游原料:二氯甲烷 --> 间氯过氧苯甲酸 --> 环戊烯

系列性分类


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