2-chloro-1,3-benzothiazole 2-氯苯并噻唑
CAS 615-20-3 MFCD00005776
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分类
- {Chemicalbook} 农药中间体: 除草剂中间体: 酰胺类除草剂
- {SNA} Building Blocks, C3 to C7, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Thiazoles
- {uni_hamburg} no charge; sulfur heterocycle; nitrogen heterocycle; carbocycle; aromatic; large ring; fused rings; 5ring; 6ring; 9ring; 1fragment
相关文献及参考
- Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
- Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
- Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
安全信息
GHS Symbol
- S36 Wear suitable protective clothing 穿戴适当的防护服;
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R22 Harmful if swallowed 吞咽有害
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312
- P301+P312+P330
- P302+P352
- P305+P351+P338
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H302 Harmful if swallowed 吞食有害
TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 250 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : NCNSA6 National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. (Washington, DC) Volume(issue)/page/year: 5,24,1953
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 200 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD277-689
其他信息
- MOL 文件:615-20-3.mol
- Acros Organics:2-氯苯并噻唑 2-Chlorobenzothiazole, 99%(615-20-3)
- 海关编码:29342080
- 类别:农药
- 毒性分级:高毒
- MSDS 信息:2-Chloro-1,3-benzothiazole(615-20-3).msds
- 上游原料:盐酸 --> 三氯氧磷 --> 氯 --> 五氯化磷 --> 2-巯基苯并噻唑
- 方法一:其制备方法是在反应釜中加入2-巯基苯并噻唑、甲苯和催化剂,升温,通入一定量的光气,反应至终点,用氢气赶走氯化氢及剩余光气等,然后脱溶得产品。 也可以用氯气进行氯化,在反应釜中投入2-巯基苯并噻唑、溶剂、催化剂,开动搅拌,升温至一定温度,开始通氯气,通氯气至一定量时取样分析,原料已消失,减压脱溶,再进行蒸馏得产品。
- 图谱信息:2-氯苯并噻唑(615-20-3)红外图谱(IR1) 2-氯苯并噻唑(615-20-3)核磁图( 13 CNMR) 2-氯苯并噻唑(615-20-3)质谱(MS) 2-氯苯并噻唑(615-20-3)核磁图( 1 HNMR)
- TCI Shanghai:2-氯化苯并噻唑 2-Chlorobenzothiazole,>;98.0%(GC)(615-20-3)
- 可燃性危险特性:遇热可燃; 热分解排出有毒氮氧化物, 硫氧化物, 氯化物烟雾
- 2-氯苯并噻唑价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 C0332 2-氯化苯并噻唑 2-Chlorobenzothiazole 250G 4740元 2011/04/16 C0332 2-氯化苯并噻唑 2-Chlorobenzothiazole 25G 948元 2010/06/21 173490050 2-氯苯并噻唑 2-Chlorobenzothiazole 99% 5 GR 305元
- 储运特性:库房低温通风干燥; 与食品原料分开存放
- 用途一:用于生产农药苯噻草胺稻田除草剂
- 急性毒性:口服-大鼠 LDL0: 250 毫克/公斤; 腹腔-小鼠 LD50: 200 毫克/公斤
- Sigma Aldrich:615-20-3(sigmaaldrich)
- 灭火剂:水,二氧化碳, 泡沫, 干粉
- 2-氯苯并噻唑价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C0332 2-氯化苯并噻唑 2-Chlorobenzothiazole 250G 3140元 2014/06/02 C0332 2-氯化苯并噻唑 2-Chlorobenzothiazole 25G 523元 2010/06/21 173490050 2-氯苯并噻唑 2-Chlorobenzothiazole 99% 5 GR 305元
- Hazard Note:Irritant
- Alfa Aesar:2-氯苯并噻唑,98+% 2-Chlorobenzothiazole, 98+%(615-20-3)
- 用途二:2-氯苯并噻唑是除草剂苯噻草胺的中间体。