2-Amino-4-chloro-6-methylpyrimidine 4-chloro-6-methylpyrimidin-2-amine

CAS 5600-21-5 MFCD00006091

化学结构图

5600-21-5
SMILES: Cc1cc(Cl)nc(N)n1

化学属性

Mol. FormulaC5H6ClN3
Mol. Weight143.58
Melting Point182-186°C
TSCANo
Density1.349
Appearance 白色固体粉末，结晶（乙醇）。
Boiling Point326°C at 760 mmHg

别名和识别编码

Chemical Name2-Amino-4-chloro-6-methylpyrimidine
CAS Number5600-21-5
Alfabeta NameAMINOCHLOROMETHYLPYRIMIDINE 246-----
MDL NumberMFCD00006091
PubChem Substance ID21810
Beilstein Registry Number114297
EC Number227-018-3
Reaxys-RN114297
Synonym 4-Chloro-6-methylpyrimidin-2-amine {LY} 4-Chloro-6-methylpyrimidin-2-amine 4-amino-6-chloro-2-methylpyrimidine 4-chloro-6-methyl-2-pyridinamine {} {LY} 4-Chloro-6-methylpyrimidin-2-amine {} {} {LY} 4-Chloro-6-methylpyrimidin-2-amine {} {} {} {LY} 4-Chloro-6-methylpyrimidin-2-amine {} {} {} {} {LY} 4-Chloro-6-methylpyrimidin-2-amine {} {} {} {} {} {LY} 4-Chloro-6-methylpyrimidin-2-amine {} {} {} {} {} {} {LY} 4-Chloro-6-methylpyrimidin-2-amine {} {} {} {} {} {} {} {LY} 4-Chloro-6-methylpyrimidin-2-amine {} {} {} {} {} {} {} {} {LY} 4-Chloro-6-methylpyrimidin-2-amine {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} 4-Chloro-6-methylpyrimidin-2-amine {} {} {} {} {} {} {} {} {} {} {LY} 4-Chloro-6-methylpyrimidin-2-amine {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Chloro-6-methylpyrimidin-2-amine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Chloro-6-methylpyrimidin-2-amine {} {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation4-chloro-6-methylpyrimidin-2-amine
Wiswesser Line NotationT6N CNJ BZ DG F1
LabNetwork Molecule IDLN00161997
InChIInChI=1S/C5H6ClN3/c1-3-2-4(6)9-5(7)8-3/h2H,1H3,(H2,7,8,9)
Canonical SMILESNC1=NC(C)=CC(Cl)=N1
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分类

  • Building Blocks, C4 to C5, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Pyrimidines
  • {uni_hamburg} no charge; nitrogen heterocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Building Blocks, C4 to C5, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Pyrimidines

产品应用

  • 主要用于合成嘧啶类青霉素和嘧啶类头孢菌素。

相关文献及参考

  • Short: EINECS
  • Short: III/5a
  • Beilstein:25(3/4)2171

安全信息

Warnings IRRITANT, AVOID SKIN CONTACT
WGK Germany3
RTECSUV6329600
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S37 Wear suitable gloves 戴适当手套；
  • S22 Do not breathe dust 不要吸入粉尘；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
Hazard Codes Xi 
TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Microorganism - not otherwise specified
DOSE/DURATION           : 50 mg/L
REFERENCE :
   SOGEBZ Soviet Genetics.  English translation of GNKAA5.  (Plenum Pub. Corp.,
   233 Spring St., New York, NY 10013)  V.2-    1966- Volume(issue)/page/year:
   6,1623,1970

Storage condition -20°C, sealed storage, away from moisture and light {LY} -20°C, sealed storage, away from moisture and light {} {LY} -20°C, sealed storage, away from moisture and light {} {} {LY} -20°C, sealed storage, away from moisture and light {} {} {} {LY} -20°C, sealed storage, away from moisture and light {} {} {} {} {LY} -20°C, sealed storage, away from moisture and light {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture and light {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture and light {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture and light {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture and light {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture and light {} {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture and light {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture and light {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C

其他信息

  • Sigma Aldrich:5600-21-5(sigmaaldrich)
  • 海关编码:29335995
  • 用途二:主要用于合成嘧啶类青霉素和嘧啶类头孢菌素。
  • MSDS 信息:2-Amino-4-chloro-6-methylpyrimidine(5600-21-5).msds
  • MOL 文件:5600-21-5.mol
  • TCI Shanghai:2-氨基-4-氯-6-甲基嘧啶 2-Amino-4-chloro-6-methylpyrimidine,>;98.0%(T)(5600-21-5)
  • 检测方法:HPLC
  • 2-氨基-4-氯-6-甲基嘧啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A1088 2-氨基-4-氯-6-甲基嘧啶 2-Amino-4-chloro-6-methylpyrimidine 5G 364元 2014/06/02 A1088 2-氨基-4-氯-6-甲基嘧啶 2-Amino-4-chloro-6-methylpyrimidine 25G 999元 2010/06/21 153750250 2-氨基-4-氯-6-甲基嘧啶 2-Amino-4-chloro-6-methylpyrimidine 98% 25 GR 1650元
  • 用途一:安锥赛的中间体。
  • Acros Organics:2-氨基-4-氯-6-甲基嘧啶 2-Amino-4-chloro-6-methylpyrimidine, 98%(5600-21-5)
  • ,溶于甲醇,几乎不溶于水。
  • 上游原料:乙醚 --> 钠 --> 三氯氧磷 --> 乙酰乙酸乙酯 --> 盐酸胍
  • Alfa Aesar:2-氨基-4-氯-6-甲基嘧啶,98% 2-Amino-4-chloro-6-methylpyrimidine, 98%(5600-21-5)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyrimidines 嘧啶
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Halogenated Heterocycles 卤代杂环
  5. Pyrimidines - Halogenated Heterocycles
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Halogenated Heterocycles 卤代杂环
  5. Pyrimidines - Halogenated Heterocycles
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyrimidines 嘧啶
  5. C4 to C5 - Pyrimidines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Halogenated Heterocycles 卤代杂环
  5. Pyridines
  1. C9 to C46

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