CAS 6628-77-9 MFCD00006264-5-Amino-2-methoxypyridine 5-氨基-2-甲氧基吡啶 TAO{mole}

5-Amino-2-methoxypyridine 5-氨基-2-甲氧基吡啶

CAS 6628-77-9 MFCD00006264

化学结构图

SMILES: COc1ccc(N)cn1

化学属性

Mol. Formula	C6H8N2O
Mol. Weight	124.14
Melting Point	29-31°C
Density	1.575
Refractive index	n20/D 1.575(lit.)
Boiling Point	264.8°C at 760 mmHg
Flash Point	>110°(230°F)
TSCA	No
Solubility	Slightly soluble

别名和识别编码

Chemical Name	5-Amino-2-methoxypyridine
CAS Number	6628-77-9
Alfabeta Name	AMINOMETHOXYPYRIDINE 52---
MDL Number	MFCD00006264
EC Number	229-612-8
Beilstein Registry Number	22(5)11,408
PubChem Substance ID	81121
Synonym	5-Amino-2-methoxypyridine {LY} 5-Amino-2-methoxypyridine {} {LY} 5-Amino-2-methoxypyridine {} {} {LY} 5-Amino-2-methoxypyridine {} {} {} {LY} 5-Amino-2-methoxypyridine {} {} {} {} {LY} 5-Amino-2-methoxypyridine {} {} {} {} {} {LY} 5-Amino-2-methoxypyridine {} {} {} {} {} {} {LY} 5-Amino-2-methoxypyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Amino-2-methoxypyridine {} {} {} {} {} {} {} {} {LY} 5-Amino-2-methoxypyridine {} {} {} {} {} {} {} {} {} {LY} 5-Amino-2-methoxypyridine {} {} {} {} {} {} {} {} {} {} {LY} 5-Amino-2-methoxypyridine {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Amino-2-methoxypyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Amino-2-methoxypyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Amino-2-methoxypyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Amino-2-methoxypyridine {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation	5-氨基-2-甲氧基吡啶
Reaxys-RN	115155
InChIKey	UUVDJIWRSIJEBS-UHFFFAOYSA-N
Wiswesser Line Notation	T6NJ BO1 EZ
LabNetwork Molecule ID	LN00140549
InChI	InChI=1S/C6H8N2O/c1-9-6-3-2-5(7)4-8-6/h2-4H,7H2,1H3
Canonical SMILES	COC(C=C1)=NC=C1N

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品牌质保精细包装现货库存一流品牌服务

安全信息

Warnings IRRITANT

Signal word Warning

GHS Symbol

WGK Germany3

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；

Risk Statements

R22 Harmful if swallowed 吞咽有害
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P312+P330
P305+P351+P338
P305+P351+P338+P337+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H335 May cause respiratory irritation 可能导致呼吸道刺激
H302 Harmful if swallowed 吞食有害
H319 Causes serious eye irritation 严重刺激眼睛

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSUS1836000

Hazard Codes Xn Xn,Xi

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 89,153,1947

其他信息

用途三:医药中间体,用于生产咯萘啶磷酸盐
Sigma Aldrich:6628-77-9(sigmaaldrich)
上游原料:乙醇 --> 甲醇 --> 氢化钠 --> 铁粉 --> 亚硫酸钠 --> 连二亚硫酸钠 --> 2-氯-5-硝基吡啶 --> 5-硝基-2-甲氧基吡啶
用途二:医药中间体。用于生产咯萘啶磷酸盐。
Acros Organics:5-氨基-2-甲氧基吡啶 5-Amino-2-methoxypyridine, tech., 90%(6628-77-9)
用途一:用作药物中间体
Hazard Note:Irritant
MOL 文件:6628-77-9.mol
方法一:由2-甲氧基-5-硝基吡啶还原而得。将50%甲醇、铁粉及乙酸加热至回流，分次加入2-甲氧基-5-硝基吡啶，回流4h。用20%氢氧化钠液碱化，过滤，滤液减压蒸馏，收集140-142℃（3.33-3.60kPa）馏分，得5-氨基-5-甲氧基吡啶。收率70%。
TCI Shanghai:5-氨基-2-甲氧基吡啶 5-Amino-2-methoxypyridine,>;98.0%(GC)(6628-77-9)
Alfa Aesar:5-氨基-2-甲氧基吡啶,98% 5-Amino-2-methoxypyridine, 98%(6628-77-9)
检测方法:HPLC,NMR
MSDS 信息:6-Methoxy-3-pyridylamine(6628-77-9).msds
下游产品:5-氨基-2-甲氧基吡啶-4-羧酸 --> 3-氨基-6-甲氧基-2-氯吡啶 --> 5-氟-2-甲氧基吡啶-4-硼酸
5-氨基-2-甲氧基吡啶价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 A1956 5-氨基-2-甲氧基吡啶 5-Amino-2-methoxypyridine 25G 1380元 2014/06/02 A1956 5-氨基-2-甲氧基吡啶 5-Amino-2-methoxypyridine 5G 449元 2010/06/21 103951000 5-氨基-2-甲氧基吡啶 5-Amino-2-methoxypyridine 90%, tech. 100 GR 6039元