2-Nitrobenzyl Bromide 2-硝基苄溴
CAS 3958-60-9 MFCD00007184
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资金保障
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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分类
- {SNA} Building Blocks, Chemical Synthesis, Nitro Compounds, Nitrogen Compounds, Organic Building Blocks
相关文献及参考
- Photosensitive protecting reagent for alcohols, acids, phenols etc: J. Am. Chem. Soc., 91, 5694 (1969); J. Org. Chem., 37, 2281, 2285 (1972); Compare 4,5-Dimethoxy-2-nitrobenzyl alcohol, L00719. Has also been recommended for the protection of the imidazole function in histidine containing peptides: J. Am. Chem. Soc., 97, 440 (1975). See Appendix 6. It has been investigated as a photocleavable protecting group for various N-heterocycles: Tetrahedron Lett., 39, 359 (1998). For reviews of photoremovable groups in organic synthesis, see: Synthesis, 1 (1980); Org. Photochem., 9, 225 (1987).
- Beilstein:5(1)164
安全信息
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- R34 Causes burns 会导致灼伤
- R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
- R5 Heating may cause an explosion 加热会引起爆炸
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P303+P361+P353
- P305+P351+P338
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H290 May be corrosive to metals 可能腐蚀金属。
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
其他信息
- 方法一:将四氯化碳、邻硝基甲苯及偶氮二异丁腈的水溶液加入反应罐内,搅拌加热,滴加溴的四氯化碳溶液,保持回流至滴加完毕,继续回流5-6h,溴化生成邻硝基苄基溴。
- 下游产品:
- 检测方法:GC
- MSDS 信息:2-Nitrobenzyl bromide(3958-60-9).msds
- 存储注意事项:湿度敏感
- 上游原料:四氯化碳 --> 偶氮二异丁腈 --> 2-硝基甲苯
- TCI Shanghai:2-硝基苄溴 2-Nitrobenzyl Bromide,>;98.0%(GC)(3958-60-9)
- Sigma Aldrich:3958-60-9(sigmaaldrich)
- 海关编码:29049085
- Alfa Aesar:2-硝基苯甲基溴,98+% 2-Nitrobenzyl bromide, 98+%(3958-60-9)
- F:4.8-19-21
- Acros Organics:2-硝基苄溴 2-Nitrobenzyl bromide, 97%(3958-60-9)
- MOL 文件:3958-60-9.mol
- 2-硝基苄溴价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0404 2-硝基苄溴 2-Nitrobenzyl Bromide 5G 260元 2014/06/02 N0404 2-硝基苄溴 2-Nitrobenzyl Bromide 25G 850元 2010/06/21 148310050 2-硝基苄溴 2-Nitrobenzyl bromide 97% 5 GR 530元
- 用途一:有机合成中间体。用于生产祛痰剂溴已胺盐酸盐。