3-Nitrophenylboronic acid 3-硝基苯硼酸
CAS 13331-27-6 MFCD00007193
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信息真实价格透明
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专业采购外包团队在线服务
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分类
- {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
- Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
产品应用
- 催化炔二羰基化合物的烯碳环化反应。
相关文献及参考
- Beil. 16 ,IV,1670
- Beilstein:16(3)1276
- Mild Lewis acid catayst, for example in the selective transesterific
- Mild Lewis acid catayst, for example in the selective transesterification of ß-keto esters: Synlett, 415 (2006). See also 3,4,5-Trifluorobenzeneboronic acid, L18519. For reactions of boronic acids, see Appendix 5.
- Oxidative conversion of arylboronic acids to phenols with potassium monopersulfate in buffered aqueous acetone (in situ dimethyldioxirane) is exemplified for this compound: Tetrahedron Lett., 36, 5117 (1995).
- Reagent for derivatization of diols and diamines for GC: Chromatographia, 11, 347 (1978).
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安全信息
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352+P332+P313+P362+P364
- P305+P351+P338+P337+P313
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S37 Wear suitable gloves 戴适当手套;
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 180 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#01859
其他信息
- 溶于热水,溶于甲醇。