Nitroethane 硝基乙烷(易制爆)

CAS 79-24-3 MFCD00007404

化学结构图

79-24-3
SMILES: CC[N+](=O)[O-]

化学属性

Mol. FormulaC2H5NO2
Mol. Weight75.08
Density1.045
Refractive index1.391
Flash Point30°(86°F)
TSCAYes
Boiling Point114.0°C
Melting Point-90°C
Autoignition Point778 °F
Vapor Density2.58 (vs air)
Vapor Pressure15.6 mmHg ( 20 °C)
Solubility4.6 G/100 ML (20 ºC)

别名和识别编码

Chemical NameNitroethane
Synonym NITROETHANE ethane, nitro- Nitroethane, 98+% 硝基乙烷 Ethane,nitro- Nitro-ethane nitroethane Nitroparaffin Nitroethane, reagent grade, >=98.0% nitro-ethan C2H5NO2 Nitroäthan 硝乙烷 Nitroetan NITROETHANE, REAGENTPLUS, 99.5% nitroetan(polish) 2-Nitroethane NITROETHANE,REAGENT 1-Nitroethane Nitroethane,99% Nitroethane Nitroethane,95%
CAS Number79-24-3
EC Number201-188-9
Beilstein Registry Number1209324
MDL NumberMFCD00007404
Merck Number14,6597
Chemical Name Translation硝基乙烷(易制爆)
Wiswesser Line NotationWN2
PubChem Substance ID6587
InChIInChI=1S/C2H5NO2/c1-2-3(4)5/h2H2,1H3
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分类

  • {uni_hamburg} no charge; 1fragment

产品应用

  • 用于有机合成,用作硝化纤维素及其它树脂、蜡、脂肪、染料等的溶剂。

相关文献及参考

  • Short: II/25B Title: Structure Data Of Free Polyatomic Molecules: Molecules containing One or Two Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25B Year: 1999 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-63645-5 ISBN: 978-3-540-63645-8 Internet Resource: DOI:10.1007/b68834 RefComment: IX, 512 pages. Hardcover Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.
  • Short: II/27B Title: Diamagnetic Susceptibility of Organic Compounds, Oils, Paraffins and Polyethylenes Author: Kumar, M.; Gupta, R. Editor: Gupta, Radha Raman Source: Landolt-Börnstein, New Series Volume: II/27B Year: 2008 Keyword: diamagnetic susceptibility; organic compounds ISBN: 978-3-540-44359-9 (print) ISBN: 978-3-540-45860-9 (online) Internet Resource: doi:10.1007/978-3-540-45860-9 RefComment: VIII, 503 p. With CD-ROM., Hardcover RefComment: Written for: Scientists and researchers in the fields of physics, chemistry, materials science RefComment: Supplement and Revised Editon to II/16 Abstract: The volume II/27 has been divided into three subvolumes according to the classes of compounds: Subvolume A: Diamagnetic susceptibility and magnetic anisotropy of inorganic and organometallic compounds; Subvolume B: Diamagnetic susceptibility of organic compounds, oil

安全信息

Signal word Warning
GHS Symbol
WGK Germany2
Safety Statements
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S25 Avoid contact with eyes 避免眼睛接触;
  • S41 In case of fire and/or explosion do not breathe fumes 着火和/或爆炸时,不要吸入烟雾;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
Risk Statements
  • R45 May cause cancer 可能致癌
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
RTECSKI5600000
Packing GroupIII
UN Number UN 2842 3/PG 3 UN2842 2842
Hazard Codes Xn T,Xn
Hazard Class3
Storage condition Flammables area
Restrict 易制爆 {} 易制爆危险化学品
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Behavioral - ataxia
   Lungs, Thorax, or Respiration - respiratory stimulation
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 22,315,1940

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human - child
DOSE/DURATION           : 1478 uL/kg
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - respiratory obstruction
   Lungs, Thorax, or Respiration - cyanosis
   Blood - methemoglobinemia-carboxyhemoglobin
REFERENCE :
   JTCTDW Journal of Toxicology, Clinical Toxicology.  (Marcel Dekker, 270
   Madison Ave., New York, NY 10016)  V.19-    1982-  Volume(issue)/page/year:
   32,321,1994

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 310 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   KHFZAN Khimiko-Farmatsevticheskii Zhurnal.  Chemical Pharmaceutical Journal.
    For English translation, see PCJOAU.  (V/O Mezhdunarodnaya Kniga, 113095
   Moscow, USSR)  V.1-    19

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 5000 ppm/2H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/

其他信息

  • 急救:此化学品如进入眼中,立即用水冲洗; 如接触皮肤,迅速用肥皂和水清洗;如大量吸入,立即移离现场至新鲜空气处,必要时,进行人工呼吸; 如误被吞服,催吐,洗胃,给予医学注视,对症处理; 严重者不进行催吐,立即送
  • {Chemica
  • 上游原料:硝基甲烷 --> 2-硝基丙烷 --
  • Acros Organ
  • 急性毒性:口服- 大鼠 LD50: 1100 毫克/ 公斤; 口服- 小鼠 LD50: 860 毫克/ 公斤
  • 有害影响和中毒症状:接触皮肤可引起接
  • 毒性分级:中毒
  • 职业标准:TWA 310 毫克/ 立方米
  • 急救:此化学品如进入眼中,立即用水冲洗; 如接触皮肤,迅速用肥皂和水清洗;如大量吸入,立即移离现场至新鲜空气处,必要时,进行人工呼吸; 如误被吞服,催吐,洗胃,给予医学注视,对症处理; 严重者不进行催吐,立即送医院救治。
  • 概述:无色油状液体,有令人不愉快的气味。分子量75.07。熔点-50℃。沸点114~114.8℃。相对密度1.0528。折射率1.3917。闪点30℃。能与甲醇、乙醇、醚、氯仿及碱溶液相混溶,极微溶于水,在水中的溶解度为4.5mL/100mL(20℃),而水在本品中的溶解度为0.9mL/100mL(20℃)。蒸气与空气形成爆炸性混合物,爆炸极限3.0%~5.0% (体积)。有毒! 由于硝基乙烷化学性质较稳定,可用作硝化纤维素和纤维素乙酯、乙烯基和醇酸树脂、蜡、油脂、脂肪及染料等的溶剂,也用作火箭推进剂和燃料助剂以及制造药物和有机合成中间体。可由乙烷直接气相硝化制得或由α-氯丙酸和亚硝酸钠作用而制得。
  • TCI Shanghai:硝基乙烷 Nitroethane,>;95.0%(GC)(79-24-3)
  • 硝基乙烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80092328 硝基乙烷(易制爆) 500ml 149元 2010/06/21 157020025 硝基乙烷 Nitroethane 98+% 2.5 LT 2342元 2010/06/21 157020010 硝基乙烷 Nitroethane 98+% 1
  • 硝基甲烷:硝基甲烷是最简单的有机硝基化合物,常温下为无色油状有微弱芳香气味的透明液体,有较大的极性,可燃,有毒,具爆炸性。可作燃料。它可以和乙醇、丙酮、乙醚混溶,是一种良好的溶剂和萃取剂。同时由于硝基α-氢具有较强的活性,故硝基甲烷也是化工和有机合成中的常见原料,用于制取药物、杀虫剂、炸药、染料和纤维等。 硝基甲烷在有机合成中为一碳合成子。受硝基吸电子效应的影响,碳上的氢具有酸性,可以与碱作用去质子化。生成的碳负离子可以与醛发生1,2-加
  • 图谱信息:硝基乙烷(79-24-3)Raman光谱 硝基乙烷(79-24-3)核磁图( 13 CNMR) 硝基乙烷(79-24-3)核磁图( 1 HNMR) 硝基乙烷(79-24-3)红外图谱(IR1) 硝基乙烷(79-24-3)质谱(MS) 硝基乙烷(79-24-3)红外图谱(IR2)
  • 危险情况:(1) 本品有毒,吸入和摄入会引起中毒; 受高热时会分解,分解产物有剧毒。 (2) 易燃,有中等燃烧危险,燃点415℃。蒸气能与空气形成爆炸性混合物,爆炸极限低限为3.4%,高限不明。快速加热至高温时可引起爆炸; 在坚实密闭条件下,受到强爆炸作用时亦可发生爆炸。空气中的容许浓度美国为100ppm (310mg/m3)。
  • Alfa Aesar:硝基乙烷,99% Nitroethane, 99%(79-24-3)
  • Acros Organics:硝基乙烷 Nitroethane, 98+%(79-24-3)
  • 不溶于水,水中溶解度:4.6 g/100 mL (20°C),溶于碱性溶液,和甲醇、乙醇和乙醚混溶,溶于氯仿。
  • 硝基乙烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80092328 硝基乙烷(易制爆) 500ml 149元 2010/06/21 157020025 硝基乙烷 Nitroethane 98+% 2.5 LT 2342元 2010/06/2

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