1,1,2,2,3,3,4,4,4-Nonafluorobutane-1-sulfonyl fluoride 全氟丁基磺酰氟

CAS 375-72-4 MFCD00007422

化学结构图

375-72-4
SMILES: O=S(=O)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F

化学属性

Mol. FormulaC4F10O2S
Mol. Weight302.09
Density1.682
Boiling Point185.4°C at 760 mmHg
Refractive indexn20/D 1.3(lit.)
Flash Point77.9°C
TSCAYes
Melting Point-110 °C
Stability对湿度敏感
Appearance 无色透明液体。

别名和识别编码

Chemical Name1,1,2,2,3,3,4,4,4-Nonafluorobutane-1-sulfonyl fluoride
CAS Number375-72-4
EC Number206-792-6
Beilstein Registry Number1813589
MDL NumberMFCD00007422
PubChem Substance ID67814
Synonym Perfluorobutylsulfonyl fluoride {LY} Perfluorobutylsulfonyl fluoride {} {LY} Perfluorobutylsulfonyl fluoride {} {} {LY} Perfluorobutylsulfonyl fluoride {} {} {} {LY} Perfluorobutylsulfonyl fluoride {} {} {} {} {LY} Perfluorobutylsulfonyl fluoride {} {} {} {} {} {LY} Perfluorobutylsulfonyl fluoride {} {} {} {} {} {} {LY} Perfluorobutylsulfonyl fluoride {} {} {} {} {} {} {} {LY} Perfluorobutylsulfonyl fluoride {} {} {} {} {} {} {} {} {LY} Perfluorobutylsulfonyl fluoride {} {} {} {} {} {} {} {} {} {LY} Perfluorobutylsulfonyl fluoride {} {} {} {} {} {} {} {} {} {} {LY} Perfluorobutylsulfonyl fluoride {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluorobutylsulfonyl fluoride {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluorobutylsulfonyl fluoride {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluorobutylsulfonyl fluoride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Perfluorobutylsulfonyl fluoride {} {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation全氟丁基磺酰氟
Reaxys-RN1813589
InChIKeyLUYQYZLEHLTPBH-UHFFFAOYSA-N
LabNetwork Molecule IDLN00225116
InChIInChI=1S/C4F10O2S/c5-1(6,3(9,10)11)2(7,8)4(12,13)17(14,15)16
Canonical SMILESO=S(C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)(F)=O
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分类

  • {SNA} Building Blocks, Chemical Synthesis, F-Tagged, Fluorinated Building Blocks, Mono-Functionalized Sulfonyl Fluorides, Organic Building Blocks, Organic Fluorinated Building Blocks, SuFEx: The Next Click Reaction, Sulfonyl Halides, Sulfur Compounds
  • {SNA} Building Blocks, Chemical Synthesis, F-Tagged, Fluorinated Building Blocks, Organic Building Blocks, Organic Fluorinated Building Blocks, Sulfonyl Fluorides, Sulfonyl Halides, Sulfur Compounds
  • {SNA} Building Blocks, Building Blocks for SuFEx: The Next Click Reaction, Chemical Synthesis, F-Tagged, Fluorinated Building Blocks,
  • {SNA} Building Blocks, B

相关文献及参考

  • Nonaflates of phenols, which are stable to flash chromatography, are attractive precursors for coupling reactions, with alkyl- and arylzinc halides, arylboronic acids (Suzuki) and arylstannanes (Stille), catalyzed by Pd(0) under mild conditions: J. Org. Chem., 63, 203 (1998). Silyl enol ethers, with catalytic TBAF in the presence of molecular sieves, are converted to enol nonaflates which undergo Heck couplings, e.g with styrenes to give 1,3-dienes: Synlett, 1141 (1997).
  • Reagent for formation of nonafluorobutanesulfonates (nonaflates) of OH groups (compare Trifluoromethanesulfonic anhydride, A11767), e.g. with triethylamine in ether: Synthesis, 293 (1973); Liebigs Ann. Chem., 20 (1973).

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R34 Causes burns 会导致灼伤
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US)
Packing GroupII
UN Number 3265 UN 3265 8/PG 2 UN3265
Storage condition 2-8°C {LY} 2-8°C Moisture Sensitive {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Hazard Codes 8 C
Hazard Class8

其他信息

  • MSDS 信息:Nonafluorobutanesulfonyl fluoride(375-72-4).msds
  • 图谱信息:全氟丁基磺酰氟(375-72-4)质谱(MS) 全氟丁基磺酰氟(375-72-4)红外图谱(IR1)
  • Acros Organics:全氟丁烷磺酰氟 Perfluoro-1-butanesulfonyl fluoride, 92%(375-72-4)
  • 全氟丁基磺酰氟价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P1098 全氟丁烷磺酰氟 Perfluorobutanesulfonyl Fluoride 250G 4950元 2014/06/02 P1098 全氟丁烷磺酰氟 Perfluorobutanesulfonyl Fluoride 25G 826元 2010/06/21 312341000 全氟丁基磺酰氟 Perfluoro-1-butanesulfonyl fluoride 92% 100 GR 2202元
  • Alfa Aesar:九氟丁烷磺酰氟,90+% Nonafluorobutanesulfonyl fluoride, 90+%(375-72-4)
  • Sigma Aldrich:375-72-4(sigmaaldrich)
  • TCI Shanghai:全氟丁烷磺酰氟 Perfluorobutanesulfonyl Fluoride,>;90.0%(GC)(375-72-4)
  • MOL 文件:375-72-4.mol
  • 用途二:用于合成氟碳表面活性剂、含氟农药、染料、聚碳酸酯加工处理分散剂等
  • F:10-21
  • 用途一:用来合成多种含氟特种表面活性剂
  • Hazard Note:Corrosive
  • 敏感性:Moisture Sensitive

系列性分类