CAS 3034-19-3 MFCD00007577-2-Nitrophenylhydrazine 2-硝基苯肼 TAO{mole}

2-Nitrophenylhydrazine 2-硝基苯肼

CAS 3034-19-3 MFCD00007577

化学结构图

SMILES: NNc1ccccc1[N+](=O)[O-]

化学属性

Mol. Formula	C6H7N3O2
Mol. Weight	153.14
Melting Point	91-93 °C (lit.)
TSCA	No
Density	1.419
Stability	对光敏感
Solubility	微溶于水，溶于乙醇、乙醚。

别名和识别编码

Chemical Name	2-Nitrophenylhydrazine
Beilstein Registry Number	512797
PubChem Substance ID	3314739
CAS Number	3034-19-3
EC Number	221-222-6
MDL Number	MFCD00007577
Reaxys-RN	512797
Synonym	(2'-nitrophenyl)hydrazine (2-Nitro-phenyl)-hydrazine (2-Nitrophenyl)-hydrazin (2-Nitrophenyl)hydrazine (Contains ~30-40% water as stabilizer) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} o-Nitrophenythydrazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} O-NITROPHENYLHYDRAZINE {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {uni_hamburg} Hydrazine, (2-nitrophenyl)- {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {uni_hamburg} o-Nitrophenylhydrazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {SNA} 2-硝基苯肼 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} 2-硝基苯基肼
Alfabeta Name	NITROPHENYLHYDRAZINE 2()-
Chemical Name Translation	2-硝基苯肼
Wiswesser Line Notation	ZMR BNW
InChIKey	FRBUNLLUASHNDJ-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00183531
InChI	InChI=1S/C6H7N3O2/c7-8-5-3-1-2-4-6(5)9(10)11/h1-4,8H,7H2

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产品应用

有机合成。

安全信息

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P501 Dispose of contents/container to..… 处理内容物/容器.....
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P332+P313
P301+P312+P330
P302+P350
P337+P313
P302+P352+P332+P313+P362+P364
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P403+P235
P273 Avoid release to the environment. 避免释放到环境中。
P420 Store away from other materials. 远离其他材料。
P305+P351+P338+P337+P313
P234 Keep only in original container. 只保留在原来的容器中。

WGK Germany3

Signal word Danger

Hazard statements

H228 Flammable solid 易燃固体
H315 Causes skin irritation 会刺激皮肤
H335 May cause respiratory irritation 可能导致呼吸道刺激
H302 Harmful if swallowed 吞食有害
H319 Causes serious eye irritation 严重刺激眼睛
H242 Heating may cause a fire 加热可能会引起火灾

Hazard Codes Xi F,Xn 4.1

GHS Symbol

RTECSMV8210000

UN Number 3224 UN1325 UN 1325 4.1/PG 2

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36 Wear suitable protective clothing 穿戴适当的防护服；
S7 Keep container tightly closed 保存在严格密闭容器中；

Packing GroupII

Risk Statements

R11 Highly flammable 非常易燃
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R5 Heating may cause an explosion 加热会引起爆炸
R22 Harmful if swallowed 吞咽有害

Storage condition +4°C 2-8°C Light Sensitive 避光保存。

Warnings IRRITANT 危化品目录(2015) 危险化学品

Hazard Class4.1

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 178 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#00632

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 4 mmol/L
REFERENCE :
   AEMIDF Applied and Environmental Microbiology.  (American Soc. for
   Microbiology, 1913 I St., NW, Washington, DC 20006)  V.31-    1976-
   Volume(issue)/page/year: 44,801,1982

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Microorganism - not otherwise specified
DOSE/DURATION           : 7 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 173,233,1986

其他信息

溶于热水，微溶于乙醇、乙醚、苯和石油英。易燃。加热时爆炸。有刺激性。
Alfa Aesar:15% water(3034-19-3)" href="http://www.alfa.com/zh/GP100w.pgm?DSSTK=L02203&CAS;=3034-19-3">2-硝基苯基肼,97% 2-Nitrophenylhydrazine, 97% (dry wt.), stab. with >15% water(3034-19-3)
可燃性危险特性:遇明火可燃;燃烧产生有毒氮氧化物烟雾；与氧化剂反应
毒性分级:中毒
类别:有毒物品
2-硝基苯肼价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 N0413 2-硝基苯肼 2-Nitrophenylhydrazine 25G 1640元 2014/06/02 N0413 2-硝基苯肼 2-Nitrophenylhydrazine 5G 497元 2010/06/21 128830100 2-硝基苯肼 2-Nitrophenylhydrazine 97%, moistened with ca 30% water 10 GR 638元
外观性质:桔红色粉末。
MSDS 信息:2-硝基苯肼(3034-19-3).msds
Sigma Aldrich:3034-19-3(sigmaaldrich)
急性毒性:静脉-小鼠LD50： 178 毫克/公斤
F:4.6-8
灭火剂:二氧化碳、泡沫、砂土、雾状水、干粉
Acros Organics:2-硝基苯肼 2-Nitrophenylhydrazine, moistened with ca 30% water, 97%(3034-19-3)
图谱信息:2-硝基苯肼(3034-19-3)红外图谱(IR1) 2-硝基苯肼(3034-19-3)质谱(MS) 2-硝基苯肼(3034-19-3)核磁图( 13 CNMR) 2-硝基苯肼(3034-19-3)核磁图( 1 HNMR)
储运特性:库房通风低温干燥; 与氧化剂、酸类、食品添加剂分开存放
敏感性:Light Sensitive
MOL 文件:3034-19-3.mol