CAS 100-16-3 MFCD00007579-4-Nitrophenylhydrazine 4-硝基苯肼 TAO{mole}

4-Nitrophenylhydrazine 4-硝基苯肼

CAS 100-16-3 MFCD00007579

化学结构图

SMILES: NNc1ccc([N+](=O)[O-])cc1

化学属性

Mol. Formula	C6H7N3O2
Mol. Weight	153
Melting Point	156
TSCA	Yes
Density	1.00
Solubility	微溶于水，溶于热乙醇、乙醚、苯、氯仿、乙酸乙酯。
Stability	对热、光及空气敏感
Boiling Point	100

别名和识别编码

Chemical Name	4-Nitrophenylhydrazine
CAS Number	100-16-3
PubChem Substance ID	3310889
EC Number	202-824-8
Beilstein Registry Number	608107
MDL Number	MFCD00007579
Reaxys-RN	608107
Merck Number	6624
Alfabeta Name	NITROPHENYLHYDRAZINE 4-
Chemical Name Translation	4-硝基苯肼
Synonym	4-硝基苯肼, 98% (DRY WT), >30%水作稳定剂 4-Nitrophenylhydrazine, 98% (dry wt), stab. with >30% water P-NitroPhneyl Hydrazine 4-NITROPHENYLHYDRAZINE CP 97% 4-NITROPHENYLHDYRAZINE P-NITROPHENYLHYDRAZINE,REAGENT Hydrazine, (4-nitrophenyl)- 4-Nitrophenylhydrazine (base and/or unspecified salts) 4-硝基苯基肼 Hydrazine, (p-nitrophenyl)- p-Nitrophenylhydrazine 4-硝基苯肼(禁止空运) 4-Nitrophenylhydrazine (p-nitrophenyl)-hydrazin (4-nitrophenyl)-hydrazin 1-(4-NITROPHENYL)HYDRAZINE Hydrazine,(4-nitrophenyl)- PARA-NITROPHENYLHYDRAZINE 4-硝基苯肼 4-NitrophenylHydrazineGr p-Hydrazinonitrobenzene 4-NITROPHENYLHYDRAZINE 对硝基苯肼 4-NITROPHENYLHYDRAZINE (DRY WT), STABILIZED WITH >30% WATER 4-NITROPHEYLHYDRAZINE 對硝苯肼 p-Nitrophenylhydrazide P-NITROPHENYLHYDRAZINE
Wiswesser Line Notation	ZMR DNW
LabNetwork Molecule ID	LN00222272
InChI	InChI=1S/C6H7N3O2/c7-8-5-1-3-6(4-2-5)9(10)11/h1-4,8H,7H2

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

产品应用

测定脂肪醛、酮和糖类。

安全信息

GHS Symbol

WGK Germany3

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H317 May cause an allergic skin reaction 可能导致皮肤过敏
H302 Harmful if swallowed 吞食有害
H312 Harmful in contact with skin 皮肤接触有害
H335 May cause respiratory irritation 可能导致呼吸道刺激
H319 Causes serious eye irritation 严重刺激眼睛
H228 Flammable solid 易燃固体
H242 Heating may cause a fire 加热可能会引起火灾

Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

Hazard Codes F,Xn

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P305+P351+P338
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P501 Dispose of contents/container to..… 处理内容物/容器.....
P332+P313
P301+P312+P330
P302+P350
P337+P313
P302+P352+P332+P313+P362+P364

Signal word

RTECSMV8225000

UN Number 3224

Safety Statements

S33 Take precautionary measures against static discharges 对静电采取预防措施；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S37 Wear suitable gloves 戴适当手套；
S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
S7 Keep container tightly closed 保存在严格密闭容器中；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
S36 Wear suitable protective clothing 穿戴适当的防护服；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；

Packing GroupI

Risk Statements

R11 Highly flammable 非常易燃
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R5 Heating may cause an explosion 加热会引起爆炸

Warnings 危化品目录(2015) IRRITANT

Storage condition Explosives area 密封避光保存。

Hazard Class4.1

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 250 mg/kg
TOXIC EFFECTS :
   Sense Organs and Special Senses (Olfaction) - effect, not otherwise
   specified
   Behavioral - altered sleep time (including change in righting reflex)
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 6,57,1954

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Microorganism - not otherwise specified
DOSE/DURATION           : 780 ug/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 173,233,1986

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 50 ug/plate
REFERENCE :
   SAIGBL Sangyo Igaku.  Japanese Journal of Industrial Health.  (Nippon Sangyo
   Eisei Igakkai, Kosu Eisei Bldg., 1-29-8, Shinjuku, Shinjuku-ku, Tokyo 160,
   Japan)  V.1-    1959-  Volume(issue)/page/year: 29,34,1987

Restrict 危险品

其他信息

图谱信息:4-硝基苯肼(100-16-3)红外图谱(IR2) 4-硝基苯肼(100-16-3)质谱(MS) 4-硝基苯肼(100-16-3)核磁图( 13 CNMR) 4-硝基苯肼(100-16-3)核磁图( 1 HNMR) 4-硝基苯肼(100-16-3)红外图谱(IR1)
溶于热水、热苯、乙醇、氯仿、乙醚和乙酸乙酯中，微溶于冷水。易燃。加热时爆炸。有毒。
Sigma Aldrich:100-16-3(sigmaaldrich)
Hazard Note:Flammable/Harmful
下游产品:5-硝基吲哚 --> 5-氨基-2-吲哚羧酸 --> 5-氨基-1H-吲哚-2-羧酸乙酯 --> 2,3,5-三甲基噻吩 --> 1-甲基-5-硝基-1H-吲哚 --> 5-硝基吲哚-2-羧酸乙酯 --> 5-氨基吲哚 --> 氯化硝基四氮唑兰 --> 4-(2-噻吩)苯胺,97%
急性毒性:腹腔-小鼠 LDL0: 250毫克/公斤
F:4.6
类别:有毒物品
4-硝基苯肼价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 80093914 4-硝基苯肼;对硝基苯肼 25g 120元 2011/04/16 N0230 4-硝基苯肼 4-Nitrophenylhydrazine 25G 600元 2010/06/21 383030050 4-硝基苯肼 4-Nitrophenylhydrazine 97%, moistened with >;30% water 5 GR 352元
Acros Organics:4-硝基苯肼 4-Nitrophenylhydrazine, 98%(100-16-3)
用途一:用作检验醛、酮糖类的试剂
Alfa Aesar:30%水作稳定剂 ##DISCONTINUED## 4-Nitrophenylhydrazine, 98% (dry wt), stab. with >30% water(100-16-3)" href="http://www.alfa.com/zh/GP100w.pgm?DSSTK=A12658&CAS;=100-16-3">4-硝基苯肼,98%(drywt),>30%水作稳定剂 ##DISCONTINUED## 4-Nitrophenylhydrazine, 98% (dry wt), stab. with >30% water(100-16-3)
储运特性:库房通风低温干燥; 与氧化剂、酸类、食品添加剂分开存放
MSDS 信息:4-硝基苯肼(100-16-3).msds
外观性质:橙黄色结晶粉末。
用途二:用作检验醛、酮和糖的试剂。
MOL 文件:100-16-3.mol
用途三:测定脂肪醛、酮和糖类。
灭火剂:二氧化碳、泡沫、砂土、雾状水。
可燃性危险特性:明火可燃;与氧化剂反应;高热分解有毒氮氧化物烟雾
上游原料:亚硫酸钠 --> 无水醋酸钠 --> 4-硝基苯胺 --> 盐酸苯肼
毒性分级:高毒
方法一:将对硝基苯胺溶于盐酸，冷至0℃，加入亚硝酸钠溶液进行重氮化，过滤。将滤液加到冷却的亚硫酸钠和氢氧化钠混合溶液中，再加浓盐酸使呈酸性，在25℃温热半小时，过滤得到对硝基苯肼盐酸。溶于水后加入乙酸钠深溶液，析出对硝基苯肼，收率63-72%。