CAS 101-80-4 MFCD00007863-4,4'-Oxydianiline 4,4'-二氨基二苯醚 TAO{mole}

4,4'-Oxydianiline 4,4'-二氨基二苯醚

CAS 101-80-4 MFCD00007863

化学结构图

SMILES: Nc1ccc(Oc2ccc(N)cc2)cc1

化学属性

Mol. Formula	C12H12N2O
Mol. Weight	200.24
Density	1.216
Vapor Pressure	10 mmHg ( 240 °C)
Melting Point	188-192°C
Flash Point	218.9°C
TSCA	Yes
Boiling Point	389.4±27.0 °C at 760 mmHg
Solubility	易溶于盐酸，不溶于水。
Stability	对湿度敏感

别名和识别编码

Chemical Name	4,4'-Oxydianiline
MDL Number	MFCD00007863
CAS Number	101-80-4
EC Number	202-977-0
Beilstein Registry Number	475735
Synonym	4,4'-Oxydianiline {LY} 4,4'-Oxydianiline {} {LY} 4,4'-Oxydianiline {} {} {LY} 4,4'-Oxydianiline {} {} {} {LY} 4,4'-Oxydianiline {} {} {} {} {LY} 4,4'-Oxydianiline {} {} {} {} {} {LY} 4,4'-Oxydianiline {} {} {} {} {} {} {LY} 4,4'-Oxydianiline {} {} {} {} {} {} {} {LY} 4,4'-Oxydianiline {} {} {} {} {} {} {} {} {LY} 4,4'-Oxydianiline {} {} {} {} {} {} {} {} {} {LY} 4,4'-Oxydianiline {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Oxydianiline {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Oxydianiline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Oxydianiline {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Oxydianiline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Oxydianiline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-Oxydianiline {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID	87574099
Reaxys-RN	475735
Chemical Name Translation	4,4'-二氨基二苯醚
Wiswesser Line Notation	ZR DOR DZ
LabNetwork Molecule ID	LN00224964
InChI	InChI=1S/C12H12N2O/c13-9-1-5-11(6-2-9)15-12-7-3-10(14)4-8-12/h1-8H,13-14H2
Canonical SMILES	NC1=CC=C(OC2=CC=C(C=C2)N)C=C1

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产品应用

1. 它是新型特种工程塑料聚酰亚胺、聚醚酰亚胺、聚酯酰亚胺、聚马来酰亚胺、聚芳酰胺等耐高温树脂的重要原料之一;
2. 它还是合成 3,3'， 4,4'-四氨基二苯醚的原料，后者是制备一系列芳杂环耐热高分子材料的主要单体。
3. 它还用作高性能耐热性环氧树脂、聚氨酯等合成高分子的原料及交联剂。
4. 同时还用于替代具有致癌作用的联苯胺生产偶氮染料、活性染料和香料等领域。目前用二氨基二苯醚作原料已经研制出了大红、艳红、沙红、黄棕、绿、灰、兰、艳橙、黑等不同色阶的直接染料，可用于丝、毛、棉、麻等织物的染色，其色泽牢度和竭染率等方面均优于联苯胺染料。

安全信息

Signal word Danger

GHS Symbol

WGK Germany3

Safety Statements

S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

Risk Statements

R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
R45 May cause cancer 可能致癌
R46 May cause inheritable genetic damage 可能引起遗传基因损害
R50/53
R51/53
R62 Possible risk of impaired fertility 有削弱生殖能力的危险

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P310
P301+P312+P330
P302+P350
P302+P352+P333+P313+P362+P364
P304+P340
P308+P313
P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H302 Harmful if swallowed 吞食有害
H331 Toxic if inhaled 吸入中毒
H311 Toxic in contact with skin 皮肤接触中毒
H301 Toxic if swallowed 吞食有毒
H350 May cause cancer 可能致癌
H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
H340 May cause genetic defects 可能导致遗传性缺陷
H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
H317 May cause an allergic skin reaction 可能导致皮肤过敏
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
H301+H311+H331

Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

RTECSBY7900000

Packing GroupIII

UN Number 3077 UN 3077 9/PG 3 UN3077

Hazard Codes 9 T,N

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

Hazard Class9

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 19 gm/kg/77W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Kidney, Ureter, Bladder - Kidney tumors
   Blood - tumors
REFERENCE :
   VOONAW Voprosy Onkologii.  Problems of Oncology.  For English translation,
   see PONCAU. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-10,
   1928-37; V.1-    1955-  Volume(issue)/page/year: 21(3),69,1975

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 12978 mg/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Sense Organs and Special Senses (Eye) - tumors
REFERENCE :
   JJIND8 JNCI, Journal of the National Cancer Institute.  (Washington, DC)
   V.61-79, 1978-87. For publisher information, see JNCIEQ.
   Volume(issue)/page/year: 72,1457,1984

TYPE OF TEST            : TD - Toxic dose (other than lowest)

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 13 gm/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Sense Organs and Special Senses (Eye) - tumors
   Liver - tumors
REFERENCE :
   NC

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 69216 mg/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
   Endocrine - thyroid tumors
REFERENCE :
   JJIND8 JNCI, Journal of the National Cancer Institute.  (Washington, DC)
   V.61-79, 1978-87. For publisher information, see JNCIEQ.
   Volume(issue)/page/year: 72,1457,1984

{hazar

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 650 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Lungs, Thorax, or Respiration - dyspnea
   Nutritional and Gross Metabolic - body temperature decrease
REFERENCE :
   HYSAAV Hygiene and Sanitation (USSR).  English translation of GISAAA.
   (Springfield, VA)  1964-71. Discontinued.  Volume(issue)/page/year:
   33(10-12),137,1968

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 650 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Lungs, Thorax, or Respiration - dyspnea
   Nutritional and Gross Metabolic - body temperature decrease
REFERENCE :
   HYSAAV Hygiene and Sanitation (USSR).  English translation of GISAAA.
   (Springfield, VA)  196

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 300 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Lungs, Thorax, or Respiration - dyspnea
   Nutritional and Gross Metabolic - body temperature decrease
REFERENCE :
   HYSAAV Hygiene and Sanitation (USSR).  English translation of GISAAA.
   (Springfield, VA)  1964-71. Discontinued.  Volume(issue)/page/year:
   33(10-12),137,1968

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 365 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Lungs, Thorax, or Respiration - dyspnea
   Nutritional and Gross Metabolic - body temperature decrease
REFERENCE :
   HYSAAV Hygiene and Sanitation (USSR).  English translation of GISAAA.
   (Springf

TYPE OF TEST            : DNA damage
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 3640 umol/kg
REFERENCE :
   CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House,
   Southfield Road, Eynsham, Oxford OX8 1JJ, UK)  V.1-    1980-
   Volume(issue)/page/year: 2,1317,1981

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 14

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 160 mg/L
REFERENCE :
   SCIEAS Science.  (American Assoc. for the Advancement of Science, 1333 H
   St., NW, Washington, DC 20005)  V.1-    1895-  Volume(issue)/page/year:
   236,933,1987

TYPE OF TEST            : Micronucleus test
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 225 mg/kg/3D (Continuous)
REFERENCE :
   EMMUEG Environmental and Mole

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 333 ug/plate
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   11(Suppl 12),1,1988

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 50 mg/L
REFERENCE :
   SCIEAS Science.  (American Assoc. for the Advancement of Science, 1333 H
   St., NW, Washington, DC 20005)  V.1-    1895-  Volume(issue)/page/year:
   236,933,1987

TYPE OF TEST            :

其他信息

外观:白色或浅黄色晶体，无味。
海关编码:29222900
上游原料:盐酸 --> 碳酸钠 --> 亚硝酸钠 --> 氢氧化铵 --> 氯化铵 --> 铁粉 --> 活性炭 --> 氯化钾 --> 乳化剂 --> 柠檬酸 --> 硝基苯 --> 甲酸钠 --> 4-硝基苯酚
4,4'-二氨基二苯醚价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 30049926 4，4-二氨基二苯醚 100g 36.7元 2011/04/16 O0088 4,4'-二氨基二苯醚 4,4'-Diaminodiphenyl Ether 25G 260元 2011/04/16 O0088 4,4'-二氨基二苯醚 4,4'-Diaminodiphenyl Ether 500G 1850元
用途二:用作染料中间体，也用于树脂的合成
MOL 文件:101-80-4.mol
TCI Shanghai:4,4'-二氨基二苯醚 4,4'-Diaminodiphenyl Ether,>;98.0%(GC)(T)(101-80-4)
微溶于水，稍溶于乙醇。低毒，半数致死量(大鼠，经口)725mg/kg。有致癌可能性。有刺激性。
MSDS 信息:4,4'-氧二苯胺(101-80-4).msds
蒸气压:10 mm Hg ( 240 °C)
用途三:用作耐热性塑料聚酰亚胺树脂,聚马来酰亚胺树脂、聚酰胺-酰亚胺树脂，聚酯-酰亚胺树脂，聚酰亚胺薄膜等的原料,其中聚酰亚胺薄膜是电子和电力工业中最常用的特种绝缘材料.
下游产品:均苯聚酰亚胺薄膜
Acros Organics:对氨基二苯醚 4-Aminophenyl ether, 98%(101-80-4)
用途一:用作耐高温聚合材料聚酰亚胺的单体，也用于塑料工业
用途五:香料。染料中间体。树脂合成。
Alfa Aesar:双(4-氨基苯基)醚,98% Bis(4-aminophenyl) ether, 98%(101-80-4)
用途四:用于各类特种电缆、胶鞋、橡胶地板、海绵、三角带、同步带、密封带、胶辊等制品中。
图谱信息:4,4'-二氨基二苯醚(101-80-4)红外图谱(IR1) 4,4'-二氨基二苯醚(101-80-4)质谱(MS) 4,4'-二氨基二苯醚(101-80-4)红外图谱(IR2)
Sigma Aldrich:101-80-4(sigmaaldrich)
包装:纸板桶或纸板箱