Trifluoroacetamide 三氟乙酰胺
CAS 354-38-1 MFCD00008008
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资金保障
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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分类
- {SNA} Amides, Building Blocks, C2 to C7, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks
- {uni_hamburg} no charge; amide; 1fragment
产品应用
- 有机合成。从卤化物或甲基磺酸类化合物合成伯胺。
相关文献及参考
- Short: IV/20A
- Beilstein:2(2)186
- Short: IV/20C
- Short: IV/20B
- Short: II/2
- Has been used in a convenient alternative to the Gabriel synthesis of primary amines from halides by N-alkylation followed by cleavage of the readily-hydrolyzed trifluoroacetyl group: Synthesis, 941 (1984). For improved N-alkylation under phase-transfer conditions allowing successive alkylation with different alkyl groups, see: Synth. Commun., 18, 791 (1988). The method has been further extended by the use of ɑ-bromo esters to provide a high yielding route to ɑ-amino acids: J. Org. Chem., 56, 420 (1991):
安全信息
GHS Symbol

- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S37 Wear suitable gloves 戴适当手套;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
- S36 Wear suitable protective clothing 穿戴适当的防护服;
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P350
- P302+P352+P332+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P337+P313
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
其他信息
- 外观性质:白色结晶。易溶于水。有毒。有刺激性。熔点:75℃沸点:162.5℃
- Acros Organics:2,2,2-三氟乙酰胺 2,2,2-Trifluoroacetamide, 99+%(354-38-1)
- 下游产品:2-(三氟甲基)噻唑-5-甲酸乙酯 --> 2,2,2-三氟乙基胺
- 检测方法:GC
- TCI Shanghai:三氟乙酰胺 Trifluoroacetamide,>;98.0%(N)(354-38-1)
- TSCA:T
- MOL 文件:354-38-1.mol
- 2,2,2-三氟乙酰胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010156 三氟乙酰胺;2,2,2-三氟乙酰胺 100g 600元 2011/04/16 T0598 三氟乙酰胺 Trifluoroacetamide 25G 395元 2011/04/16 T0598 三氟乙酰胺 Trifluoroacetamide 500G 3110元
- MSDS 信息:2,2,2-Trifluoroacetamide(354-38-1).msds
- Hazard Note:Harmful/Irritant
- Sigma Aldrich:354-38-1(sigmaaldrich)
- 易溶于水。有毒。有刺激性。
- Alfa Aesar:2,2,2-三氟乙酰胺,97% 2,2,2-Trifluoroacetamide, 97%(354-38-1)
- 图谱信息:2,2,2-三氟乙酰胺(354-38-1)红外图谱(IR2) 2,2,2-三氟乙酰胺(354-38-1)Raman光谱 2,2,2-三氟乙酰胺(354-38-1)质谱(MS) 2,2,2-三氟乙酰胺(354-38-1)红外图谱(IR1)
- 用途一:有机合成。从卤化物或甲基磺酸类化合物合成伯胺。
- 海关编码:29241900