Dimethylamine 二甲胺
CAS 124-40-3 MFCD00008288
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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分类
- {SA} Alphabetic, Analytical Standards, Analytical/Chromatography, Chemical Synthesis, D, DID - DIN, Organic Bases, Synthetic Reagents
- {uni_hamburg} no charge; 1fragment
- {SNA} Chemical Synthesis, Organic Bases, Synthetic Reagents
- {SNA} 25mL Sure/Seal Reagents, Acids & Bases, Amines, Bases, Building Blocks, C2 to C5, Chemical Synthesis, Nitrogen Compounds, Organic Bases, Organic Building Blocks, Organometallic Reagents, Synthetic Reagents
- {SNA} Acids & Bases, Bases, Chemical Synthesis, Organic Bases,
产品应用
- ⑴. 二甲胺在室温下是无色气体。高浓度的带有氨味,低浓度的有烂鱼味。易溶于水,溶于乙醇和乙醚。易燃烧。
- ⑵. 有弱碱性,与无机酸生成易溶于水的盐类。其蒸气能与空气形成爆炸性混合物,爆炸极限2.8%-14.4%。闪点低,避免日光直射,远离火源。对铜、铜合金、铝、锡、锌等有腐蚀性。
- ⑶. 化学性质具有仲胺的典型性质。
- ① 水溶液呈碱性,与无机酸、有机酸、酸性芳香族硝基化合物生成具有一定熔点的盐。与重金属化合物形成络盐。
- ② 与酰氯、酸酐等发生酰基化反应,生成N-取代酰胺。与脂肪族羧酸生成的盐,经脱水后也生成
- 测定镁和锌。氢氧化锌、氢氧化锰的沉淀。酸性气体吸收剂。溶剂。检验氯化苦及空气中二氧化碳。有机合成中间体,二甲基二硫代氨基甲酸盐等制备。
相关文献及参考
- Short: II/4
- Merck: 14,3228
- Short: II/6
- Short: II/25B
- Merck: 14,3228 Beilstein: 4,IV,128
安全信息
GHS Symbol
- H220 Extremely flammable gas 极易燃气体。
- H224 Extremely flammable liquid and vapour 极端易燃液体和蒸气
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H280 Contains gas under pressure; may explode if heated 内含高压气体,遇热可能爆炸。
- H302 Harmful if swallowed 吞食有害
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H315 Causes skin irritation 会刺激皮肤
- H318 Causes serious eye damage 严重伤害眼睛
- H332 Harmful if inhaled 吸入有害
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
- H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P242 Use only non-sparking tools. 只能使用无火花工具。
- P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P310
- P301+P312
- P301+P330+P331
- P302+P352
- P303+P361+P353
- P304+P312
- P304+P340
- P305+P351+P338
- P307+P311
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
- P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
- P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
- P330 Rinse mouth. 漱口
- P332+P313
- P333+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P370+P378
- P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely. 漏气着火:切勿灭火,除非漏气能够被安全地制止。
- P381 Eliminate all ignition sources if safe to do so. 如果安全的话,消除所有点火源。
- P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
- P403 Store in a well-ventilated place. 储存在通风良好的地方。
- P403+P233
- P403+P235
- P405 Store locked up. 上锁保管。
- P410+P403
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- R12 Extremely flammable 极端易燃
- R11 Highly flammable 非常易燃
- R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
- R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性:吸入,皮肤接触和吞食都会产生十分严重的不可逆危险
- R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
- R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
- R34 Causes burns 会导致灼伤
- R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
- R20 Harmful by inhalation 吸入有害
- R19 May form explosive peroxides 可能生成易爆的过氧化物质
- R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
- S29 Do not empty into drains 不要排入下水道;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 4725 ppm/2H TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 43,411,1982
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 240 mg/kg TOXIC EFFECTS : Behavioral - excitement Behavioral - muscle weakness Gastrointestinal - ulceration or bleeding from stomach REFERENCE : HYSAAV Hygiene and Sanitation (USSR). English translation of GISAAA. (Springfield, VA) 1964-71. Discontinued. Volume(issue)/page/year: 32(6),329,1967
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 4540 ppm/6H TOXIC EFFECTS : Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Sense Organs and Special Senses (Eye) - effect, not otherwise specified Lungs, Thorax, or Respiration - dyspnea REFERENCE : AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 4
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 736 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : YKKZAJ Yakugaku Zasshi. Journal of Pharmacy. (Nippon Yakugakkai, 2-12-15 Shibuya, Shibuya-ku, Tokyo 150, Japan) No.1- 1881- Volume(issue)/page/year: 97,1117,1977
TYPE OF TEST : Sister chromatid exchange TEST SYSTEM : Rodent - hamster Ovary DOSE/DURATION : 500 umol/L REFERENCE : MOTOEX Molecular Toxicology. (Taylor & Francis, Inc., 242 Cherry St., Philadelphia, PA USA 19106) V.1- 1987- Volume(issue)/page/year: 1,217,1987
TYPE OF TEST : Cytogenetic analysis ROUTE OF EXPOSURE : Inhalation TEST SYSTEM : Rodent - rat DOSE/DURATION : 50 ug/m3 REFERENCE : GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 36(11),9,1971
TYPE OF TEST : Cytogenetic analysis TEST SYSTEM : Rodent - hamster Ovary DOSE/DURATION : 10 mmol/L REFERENCE : MOTOEX Molecular Toxicology. (Taylor & Francis, Inc., 242 Cherry St., Philadelphia, PA USA 19106) V.1- 1987- Volume(issue)/page/year: 1,217,1987
其他信息
- ⑴. 储存于阴凉、通风的库房。远离火种、热源。库温不宜超过30℃。保持容器密封。应与氧化剂、酸类、卤素单质分开存放,切忌混储。采用防爆型照明、通风设施。禁止使用易产生火花的机械设备和工具。储区应备有泄漏应急处理设备。 ⑵. 密闭操作,加强通风。操作人员必须经过专门培训,严格遵守操作规程。建议操作人员佩戴自吸过滤式防毒面具(全面罩),穿防静电工作服,戴橡胶手套。远离火种、热源,工作场所严禁吸烟。使用防爆型的通风系统和设备。防止气体泄漏到工作场所空气中。 ⑶. 在传送过程中,钢瓶和容器必须接地和跨接,防止产